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We present a method for performing path integral molecular dynamics (PIMD) simulations for fermions and address its sign problem. PIMD simulations are widely used for studying many-body quantum systems at thermal equilibrium. However, they…

Chemical Physics · Physics 2020-05-07 Barak Hirshberg , Michele Invernizzi , Michele Parrinello

Recently, fictitious identical particles have provided a promising way to overcome the fermion sign problem and have been used in path integral Monte Carlo (PIMC) to accurately simulate warm dense matter with up to 1000 electrons (T.…

Quantum Gases · Physics 2025-08-14 Yunuo Xiong , Shujuan Liu , Hongwei Xiong

The \emph{ab initio} path integral Monte Carlo (PIMC) method is one of the most successful methods in statistical physics, quantum chemistry and related fields, but its application to quantum degenerate Fermi systems is severely hampered by…

Computational Physics · Physics 2023-08-14 Tobias Dornheim , Panagiotis Tolias , Simon Groth , Zhandos Moldabekov , Jan Vorberger , Barak Hirshberg

The ab initio thermodynamic simulation of correlated Fermi systems is of central importance for many applications, such as warm dense matter, electrons in quantum dots, and ultracold atoms. Unfortunately, path integral Monte Carlo (PIMC)…

Computational Physics · Physics 2019-08-28 Tobias Dornheim

The zero-temperature and finite-temperature thermodynamics of two-component Fermi gases with finite-range attractive interaction suffer from fermion sign problem, which seems like an insurmountable problem in exact numerical simulations. In…

Quantum Gases · Physics 2022-12-02 Yunuo Xiong , Hongwei Xiong

By generalizing the recently developed path integral molecular dynamics for identical bosons and fermions, we consider the finite-temperature thermodynamic properties of fictitious identical particles with a real parameter $\xi$…

Statistical Mechanics · Physics 2022-09-21 Yunuo Xiong , Hongwei Xiong

We combine the recent $\eta-$ensemble path integral Monte Carlo (PIMC) approach to the free energy [T.~Dornheim \textit{et al.}, \textit{Phys.~Rev.~B} \textbf{111}, L041114 (2025)] with a recent fictitious partition function technique based…

Accurate thermodynamic simulations of correlated fermions using path integral Monte Carlo (PIMC) methods are of paramount importance for many applications such as the description of ultracold atoms, electrons in quantum dots, and warm-dense…

Computational Physics · Physics 2021-02-03 Tobias Dornheim , Michele Invernizzi , Jan Vorberger , Barak Hirshberg

The fermion sign problem constitutes one of the most fundamental obstacles in quantum many-body theory. Recently, it has been suggested to circumvent the sign problem by carrying out path integral simulations with a fictitious quantum…

Mean-field molecular dynamics based on path integrals is used to approximate canonical quantum observables for particle systems consisting of nuclei and electrons. A computational bottleneck is the sampling from the Gibbs density of the…

Numerical Analysis · Mathematics 2023-11-30 Xin Huang , Petr Plechac , Mattias Sandberg , Anders Szepessy

For strongly quantum-degenerate systems at finite temperatures, the fermion sign problem remains the major obstacle to first-principles simulations. In this work, we apply the recently proposed pseudo-fermion method - designed to overcome…

Computational Physics · Physics 2026-03-31 Yunuo Xiong , Tommaso Morresi , Hongwei Xiong

The fermion sign problem constitutes a fundamental computational bottleneck across a plethora of research fields in physics, quantum chemistry and related disciplines. Recently, it has been suggested to alleviate the sign problem in…

Correlated fermions are of high interest in condensed matter (Fermi liquids, Wigner molecules), cold atomic gases and dense plasmas. Here we propose a novel approach to path integral Monte Carlo (PIMC) simulations of strongly degenerate…

Quantum Gases · Physics 2016-01-15 Tobias Dornheim , Simon Groth , Alexey Filinov , Michael Bonitz

Path integral molecular dynamics (PIMD) has been successfully applied to perform simulations of large bosonic systems in a recent work (Hirshberg et al., PNAS, 116, 21445 (2019)). In this work we extend PIMD techniques to study Green's…

Quantum Physics · Physics 2022-04-22 Xiong Yunuo , Xiong Hongwei

We investigate the energy per particle, static structure factor, and momentum distribution of the uniform electron gas for different conditions defined by the dimensionless temperature $\Theta = 0.25 - 1.0$ and average interparticle…

Materials Science · Physics 2025-06-13 Tommaso Morresi , Giovanni Garberoglio , Hongwei Xiong , Yunuo Xiong

Ab initio path integral Monte Carlo (PIMC) simulations constitute the gold standard for the estimation of a broad range of equilibrium properties of a host of interacting quantum many-body systems spanning conditions from ultracold atoms to…

Chemical Physics · Physics 2025-08-27 Paul Hamann , Jan Vorberger , Tobias Dornheim

The main difficulty for path integral Monte Carlo studies of Fermi systems results from the requirement of antisymmetrization of the density matrix and is known in literature as the 'sign problem'. To overcome this issue the new numerical…

Plasma Physics · Physics 2017-05-09 Alexander Larkin , Vladimir Filinov , Vladimir Fortov

In this work we study the recently developed parametrized partition function formulation and show how we can infer the thermodynamic properties of fermions based on numerical simulation of bosons and distinguishable particles at various…

Quantum Gases · Physics 2023-06-07 Yunuo Xiong , Hongwei Xiong

Most recently, path integral molecular dynamics (PIMD) has been successfully applied to perform simulations of identical bosons and fermions by B. Hirshberg et al.. In this work, we demonstrate that PIMD can be developed to calculate…

Quantum Gases · Physics 2022-05-30 Xiong Yunu , Xiong Hongwei

We present a practical analysis of the fermion sign problem in fermionic path integral Monte Carlo (PIMC) simulations in the grand-canonical ensemble (GCE). As a representative model system, we consider electrons in a $2D$ harmonic trap. We…

Computational Physics · Physics 2021-09-01 Tobias Dornheim
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