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The physical impossibility of heat transfer under isothermal conditions implies that the classical expression for the entropy of the ideal gas may not be compatible with the internal energy of the gas itself. A corrected expression of the…

Statistical Mechanics · Physics 2023-09-01 A. Paglietti

We review the inherent structure thermodynamical formalism and the formulation of an equation of state for liquids in equilibrium based on the (volume) derivatives of the statistical properties of the potential energy surface. We also show…

Soft Condensed Matter · Physics 2009-11-07 S. Mossa , E. La Nave , P. Tartaglia , F. Sciortino

We derive a Thermodynamic Uncertainty Relation bounding the mean squared displacement of a Gaussian process with memory, driven out of equilibrium by unbalanced thermal baths and/or by external forces. Our bound is tighter with respect to…

Statistical Mechanics · Physics 2023-05-23 Andrea Plati , Andrea Puglisi , Alessandro Sarracino

We examine the dependence of a thermodynamic potential of a fluid on the geometry of its container. If motion invariance, continuity, and additivity of the potential are fulfilled, only four morphometric measures are needed to describe…

Soft Condensed Matter · Physics 2016-08-31 P. -M. König , R. Roth , K. R. Mecke

The thermodynamic approach to non-equilibrium dynamics describes the state of macroscopic systems by means of a collection of intensities or intensive variables. The latter are by definition the differentials of the entropy with respect to…

chao-dyn · Physics 2008-02-03 Z. Hens , X. de Hemptinne

The thermodynamic uncertainty relation expresses a universal trade-off between precision and entropy production, which applies in its original formulation to current observables in steady-state systems. We generalize this relation to…

Statistical Mechanics · Physics 2018-12-06 Timur Koyuk , Udo Seifert , Patrick Pietzonka

Environmental science almost invariably proposes problems of extreme complexity, typically characterized by strongly nonlinear evolution dynamics. The systems under investigation have many degrees of freedom - which makes them complicated -…

Atmospheric and Oceanic Physics · Physics 2007-05-23 A. Speranza , V. Lucarini

We investigate a solvable model for energy conserving non-equilibrium steady states. The time-reversal asymmetry of the dynamics leads to the violation of detailed balance and to ergodicity breaking, as manifested by the presence of…

Statistical Mechanics · Physics 2011-11-09 Yair Shokef , Gal Shulkind , Dov Levine

The fact that a temperature and an entropy may be associated with horizons in semi-classical general relativity has led many to suspect that spacetime has microstructure. If this is indeed the case then its description via Riemannian…

Statistical Mechanics · Physics 2011-10-28 Cenalo Vaz

To the student of thermodynamics the most difficult subject is entropy. In this paper we examine the actual, practical application of entropy to two simple systems, the homogeneous slab with fixed boundary values of the temperature, and an…

Statistical Mechanics · Physics 2015-05-28 Christian Frønsdal , Abhishek Pathak

All current formulations of nonequilibrium thermodynamics of open chemical reaction networks rely on the assumption of non-interacting species. We develop a general theory which accounts for interactions between chemical species within a…

Statistical Mechanics · Physics 2021-03-09 Francesco Avanzini , Emanuele Penocchio , Gianmaria Falasco , Massimiliano Esposito

The thermodynamics with medium effects expressed by the dispersion relation of the temperature and density dependent particle mass is studied. Many previous treatments have been reviewed. A new thermodynamical treatment based on the…

Nuclear Theory · Physics 2007-05-23 Shaoyu Yin , Ru-Keng Su

Completely open systems can exchange heat, work, and matter with the environment. While energy, volume, and number of particles fluctuate under completely open conditions, the equilibrium states of the system, if they exist, can be…

Statistical Mechanics · Physics 2017-01-25 Ivan Latella , Agustín Pérez-Madrid , Alessandro Campa , Lapo Casetti , Stefano Ruffo

We analyze, from the thermodynamical point of view, mechanical systems in which there is production of mechanical energy due to an internal source of energy, and compare that analysis with the similar one for the "symmetric" motion which…

Classical Physics · Physics 2014-03-17 Julio Güémez , Manuel Fiolhais

In this paper we develop a generalized formalism for equilibrium thermodynamic systems when an information is shared between the system and the reservoir. The information results in a correction to the entropy of the system. This extension…

Statistical Mechanics · Physics 2013-05-10 Alessio Gagliardi , Aldo Di Carlo

The postulational basis of classical thermodynamics has been expanded to incorporate equilibrium fluctuations. The main additional elements of the proposed thermodynamic theory are the concept of quasi-equilibrium states, a definition of…

Statistical Mechanics · Physics 2019-06-11 Y. Mishin

A central endeavor of thermodynamics is the measurement of free energy changes. Regrettably, although we can measure the free energy of a system in thermodynamic equilibrium, typically all we can say about the free energy of a…

Statistical Mechanics · Physics 2012-04-10 David A. Sivak , Gavin E. Crooks

Axion electrodynamics is based upon the Lagrangian of the electromagnetic (EM) field plus its interaction with the axions, and is accordingly a physically open system. It means that the four-divergence of the EM energy-momentum tensor is…

High Energy Physics - Phenomenology · Physics 2022-11-01 Iver H. Brevik , Moshe M. Chaichian

The temperature of a physical system is operationally defined in physics as "that quantity which is measured by a thermometer" weakly coupled to, and at equilibrium with the system. This definition is unique only at global equilibrium in…

Statistical Mechanics · Physics 2020-01-08 Daochi Zhang , Xiao Zheng , Massimiliano Di Ventra

Extended Thermodynamics is a very important theory: for example, it predicts hyperbolicity, finite speeds of propagation waves as well as continuous dependence on initial data. Therefore, it constitutes a significative improvement of…

Mathematical Physics · Physics 2007-05-23 Sebastiano Pennisi , Maria Cristina Carrisi , Antonio Scanu