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Quantum spectroscopy seeks to probe chemical systems using nonclassical light, which has properties that are qualitatively and quantitatively different than conventional light sources. One promising technique uses intensity-correlated twin…

We introduce a toluene-filled fiber platform for two-photon absorption measurements. By confining both the light and molecular sample inside the 5 $\mu$m hollow core of the fiber, we increase the distance over which the nonlinear…

We numerically analyze the use of intense entangled twin beams for ultra-sensitive spectroscopic measurements in chemical and biological systems. The examined scheme makes use of intense frequency-modulated (chirped) entangled beams to…

Quantum Physics · Physics 2018-05-16 Jiří Svozilík , Jan Peřina , Roberto de J. León-Montiel

Entangled photons can be used to make measurements with an accuracy beyond that possible with classical light. While most implementations of quantum metrology have used states made up of a single colour of photons, we show that entangled…

Multi-photon entangled states play a crucial role in quantum information applications such as secure quantum communication, scalable computation, and high-precision quantum metrology. Quantum memory for entangled states is a key component…

Quantum Physics · Physics 2018-12-19 Wei Zhang , Ming-Xin Dong , Dong-Sheng Ding , Shuai Shi , Kai-Wang , Zhi-Yuan Zhou , Guang-Can Guo , Bao-Sen Shi

We examine the possibility of storing and retrieving a single photon using electromagnetically induced transparency (EIT). We consider the theory of a proof of principle two-photon interference experiment, in which an atomic vapor cell is…

Quantum Physics · Physics 2007-05-23 Jianming Wen , Morton H. Rubin

Entangled two-photon absorption (ETPA) has recently become a topic of lively debate, mainly due to the apparent inconsistencies in the experimentally-reported ETPA cross sections of organic molecules. In this work, we provide a thorough…

Traditionally, spectroscopy is performed by examining the position of absorption lines. However, at frequencies near the transition frequency, additional information can be obtained from the phase shift. In this work we consider the…

Quantum Physics · Physics 2016-06-14 Hossein T. Dinani , Manish K. Gupta , Jonathan P. Dowling , Dominic W. Berry

Entangled photon pairs are predicted to linearize and increase the efficiency of two-photon absorption, allowing continuous wave laser diodes to drive ultrafast time-resolved spectroscopy and nonlinear processes. Despite a range of…

Quantum Physics · Physics 2022-05-31 Bryce P. Hickam , Manni He , Nathan Harper , Szilard Szoke , Scott Cushing

In this contribution we analyze virtual-state spectroscopy --- a unique tool for extracting information about the virtual states that contribute to the two-photon excitation of an absorbing medium --- as implemented by means of intense…

Quantum Physics · Physics 2018-03-14 Jiří Svozilík , Jan Peřina , Roberto de J. León-Montiel

Sub-picosecond coincidence timing from nonlocal intensity interference of entangled photons allows quantum interferometry for plasmas. Using a warm plasma dispersion relation, we correlate phase measurement sensitivity with different plasma…

Quantum Physics · Physics 2021-07-08 Zhehui Wang , Yanhua Shih

We present an analytical quantum theoretic model for non-resonant molecular two-photon absorption (TPA) of broadband, spectrally multi-mode squeezed vacuum, including low-gain (isolated entangled photon pairs or EPP) and high-gain (bright…

Quantum Physics · Physics 2022-08-10 Michael G. Raymer , Tiemo Landes

It is well known that energy-time entanglement can enhance two photon absorption (TPA) by simultaneously optimizing the two photon resonance and the coincidence rate of photons at the absorber. However, the precise relation between…

Quantum Physics · Physics 2021-08-31 Baihong Li , Holger F. Hofmann

Magnetic- and electric-dipole two-photon absorption (MED-TPA), recently introduced as a new spectroscopic technique for studying transitions between states of opposite parities, is investigated from a theoretical point of view. A new…

atom-ph · Physics 2009-10-28 M. Daoud , M. Kibler

Quantum light is a key resource for promoting quantum technology. One such class of technology aims to improve the precision of optical measurements using engineered quantum states of light. In this study, we investigate transmission…

Quantum Physics · Physics 2020-08-10 Akihito Ishizaki

Most experimental demonstrations of entanglement require nonclassical states and correlated measurements of single-photon detection events. It is shown here that entanglement can produce a large decrease in the rate of two-photon absorption…

Quantum Physics · Physics 2009-11-11 J. D. Franson

Recent theoretical studies in quantum spectroscopy have emphasized the potential of non-classical correlations in entangled photon pairs for selectively targeting specific nonlinear optical processes in nonlinear optical responses. However,…

Chemical Physics · Physics 2026-04-21 Yuta Fujihashi , Ozora Iso , Ryosuke Shimizu , Akihito Ishizaki

Single-photon entangled states, i.e. states describing two optical paths sharing a single photon, constitute the simplest form of entanglement. Yet they provide a valuable resource in quantum information science. Specifically, they lie at…

Quantum light spectroscopy, providing novel molecular information non-accessible by classical light, necessitates new computational tools when applied for complex molecular systems. We introduce two computational protocols for the molecular…

Chemical Physics · Physics 2021-09-14 Bing Gu , Daniel Keefer , Shaul Mukamel

We calculate the rate of two-photon absorption for frequency entangled photons in a tapered optical fiber whose diameter is comparable to the wavelength of the light. The confinement of the electric field in the transverse direction…

Quantum Physics · Physics 2010-04-12 Hao You , S. M. Hendrickson , J. D. Franson