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We present an equation of motion coupled cluster approach for calculating and understanding intrinsic inelastic losses in core level x-ray absorption spectra (XAS). The method is based on a factorization of the transition amplitude in the…

Chemical Physics · Physics 2020-05-20 John J. Rehr , Fernando D. Vila , Joshua J. Kas , Nitzan Y. Hirshberg , Karol Kowalski , Bo Peng

The combination of Maxwell and X-ray Bloch equations forms an appropriate framework to describe ultrafast time-resolved X-ray experiments on attosecond time scale in crystalline solids. However, broadband experiments such as X-ray…

Materials Science · Physics 2025-04-16 Joris Sturm , Ivan Maliyov , Dominik Christiansen , Malte Selig , Marco Bernardi , Andreas Knorr

The development of medium-energy inelastic X-ray scattering (IXS) optics with meV and sub-meV resolution has attracted considerable efforts in recent years. Meanwhile, there are also concerns or debates about the fundamental and feasibility…

Optics · Physics 2011-09-12 Xian-Rong Huang

Recent seminal experiments have utilized time-resolved X-ray absorption spectroscopy (XAS) to investigate the ultrafast photo-induced renormalization of the electron interaction (''Hubbard $U$'') in Mott and charge transfer insulators. In…

Strongly Correlated Electrons · Physics 2025-08-19 Denis Golez , Eva Paprotzki , Philipp Werner , Martin Eckstein

In this study, we utilize the many-body expansion (MBE) framework to decompose electronic structures into fragments by incrementing the virtual orbitals. Our work aims to accurately solve the ground and excited state energies of each…

Chemical Physics · Physics 2023-10-09 Enhua Xu , Yuma Shimomoto , Seiichiro L. Ten-no , Takashi Tsuchimochi

Many remarkable properties of quantum materials emerge from states with intricate coupling between the charge, spin and orbital degrees of freedom. Ultrafast photo-excitations of these materials hold great promise for understanding and…

Strongly Correlated Electrons · Physics 2019-04-02 Y. Cao , D. G. Mazzone , D. Meyers , J. P. Hill , X. Liu , S. Wall , M. P. M. Dean

Accurate decomposition of the mixed Mn oxidation states is highly important for characterizing the electronic structures, charge transfer, and redox centers for electronic, electrocatalytic, and energy storage materials that contain Mn.…

Materials Science · Physics 2022-10-24 Huolin L. Xin , Mike Hu

Phase transitions driven by ultrashort laser pulses have attracted interest both for understanding the fundamental physics of phase transitions and for potential new data storage or device applications. In many cases these transitions…

X-ray cavity quantum optics with inner-shell transitions has been hindered by the overlap between resonant and continuum states. Here, we report the first experimental demonstration of cavity-controlled co-to-core resonant inelastic x-ray…

Development of materials for electrochemical energy conversion requires a deep understanding of the factors governing chemical and physical rates at submicron length scales. Many workers have sought to develop chemically sensitive in situ…

Chemical Physics · Physics 2022-03-23 Brian Gerwe , Keita Mizuno , Oki Sekizawa , Kiyofumi Nitta , Koji Amezawa , Stuart B Adler

Resonant inelastic x-ray scattering (RIXS) is a well-established tool for studying electronic, nuclear and collective dynamics of excited atoms, molecules and solids. An extension of this powerful method to a time-resolved probe technique…

Chemical Physics · Physics 2015-11-03 Victor Kimberg , Nina Rohringer

We present a hybrid approach for GW/Bethe-Salpeter Equation (BSE) calculations of core excitation spectra, including x-ray absorption (XAS), electron energy loss spectra (EELS), and non-resonant inelastic x-ray scattering (NRIXS). The…

Materials Science · Physics 2015-05-20 J. Vinson , E. L. Shirley , J. J. Rehr , J. J. Kas

X-ray absorption fine structure (XAFS) and x-ray emission spectroscopy (XES) are advanced x-ray spectroscopies that impact a wide range of disciplines. However, unlike the majority of other spectroscopic methods, XAFS and XES are…

Multiexcitons (MXs) in quantum dots (QDs) manifest many body interactions under quantum confinement. Beyond this fundamental interest, MXs are of importance in numerous optoelectronic applications including QD lasing, light emitting diodes…

Mesoscale and Nanoscale Physics · Physics 2025-08-08 Einav Scharf , Rotem Liran , Adar Levi , Omer Alon , Nadav Chefetz , Dan Oron , Uri Banin

Using a recently developed impurity solver we exemplify how dynamical mean field theory captures band excitations, resonances, edge singularities and excitons in core level x-ray absorption (XAS) and core level photo electron spectroscopy…

Strongly Correlated Electrons · Physics 2015-06-23 M. W. Haverkort , G. Sangiovanni , P. Hansmann , A. Toschi , Y. Lu , S. Macke

This paper explores an integrated sensing and communication (ISAC) network empowered by multiple active simultaneously transmitting and reflecting reconfigurable intelligent surfaces (STAR-RISs). A base station (BS) furnishes downlink…

Signal Processing · Electrical Eng. & Systems 2025-07-25 Hyeonho Noh , Hyeonsu Lyu , Hyun Jong Yang

To fully capitalize on the potential and versatility of resonant inelastic x-ray scattering (RIXS), it is essential to develop the capability to interpret different RIXS contributions through calculations, including the dependence on…

X-ray absorption spectroscopy (XAS) has gained popularity in recent years as it probes matter with high spatial and elemental sensitivity. However, the theoretical modelling of XAS is a challenging task since XAS spectra feature a fine…

Chemical Physics · Physics 2023-02-03 Lukas Konecny , Stanislav Komorovsky , Jan Vicha , Kenneth Ruud , Michal Repisky

Wide-angle x-ray scattering (WAXS) is emerging as a powerful tool for increasing the resolution of solution structure measurements of biomolecules. Compared to its better known complement, small angle x-ray scattering (SAXS), WAXS targets…

Transient X-ray spectroscopies have become ubiquitous in studying photoexcited dynamics in solar energy materials due to their sensitivity to carrier occupations and local chemical or structural dynamics. The interpretation of solid-state…

Materials Science · Physics 2022-09-15 Isabel M. Klein , Alex Krotz , Jonathan M. Michelsen , Scott K. Cushing