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We present the results of a computational study of ZnO in the presence of Co and Mn substitutional impurities. The goal of our work is to identify potential ferromagnetic ground states within the (Zn,Co)O or (Zn,Mn)O material systems that…

Materials Science · Physics 2021-03-09 Nicola A. Spaldin

Surface alloying can alter surface electronic and magnetic properties, which are key parameters when developing new materials tailored for specific applications. A magnetic surface alloy was formed by depositing Sb on Ni(111) at elevated…

Motivated by the recent experimental observation of a large pressure effect on $T_c$ in Pr$_{1-x}$Sr$_x$NiO$_2$, we study the electronic properties of this compound as a function of pressure for $x=0$ and $0.2$ doping using self-consistent…

Strongly Correlated Electrons · Physics 2026-01-09 Viktor Christiansson , Francesco Petocchi , Philipp Werner

Mn is used as a dopant to improve the electromechanical properties of perovskite oxides. We elucidate the role of Mn defects and associated vacancies on the electronic, atomic and ferroelectric properties of BaTiO$_3$. Using density…

Materials Science · Physics 2014-12-24 J. F. Nossa , Ivan I. Naumov , R. E. Cohen

The Mn-terminated (001) surface of the stable anti-ferromagnetic insulating phase of cubic perovskite CaMnO$_3$ is found to undergo a magnetic reconstruction consisting on a spin-flip process at surface: each Mn spin at the surface flips to…

Materials Science · Physics 2009-10-31 Alessio Filippetti , Warren E. Pickett

Atomic and electronic structures of TiO_2(110) surface with possible adsorptional, substitutional and interstitial Au or Pt elemental impurities at full and one-sixth monolayer concentrations were investigated by density functional theory…

Strongly Correlated Electrons · Physics 2012-11-19 Ersen Mete , Oğuz Gülseren , Şinasi Ellialtıoğlu

We use a combination of density functional theory and Monte Carlo calculations to calculate the surface magnetization in magnetoelectric $\mathrm{Cr_2O_3}$ at finite temperatures. Such antiferromagnets, lacking both inversion and…

Materials Science · Physics 2023-04-19 Sophie F. Weber , Nicola A. Spaldin

Electronic structure of the transition metal (TM) dopants in ZnO is calculated by first principles approach. Analysis of the results is focused on the properties determined by the intrashell Coulomb coupling. The role of both direct and…

Materials Science · Physics 2019-02-27 A. Ciechan , P. Bogusławski

Double-layered Sr3Ru2O7 has received phenomenal consideration because it exhibits a plethora of exotic phases when perturbed. New phases emerge with the application of pressure, magnetic field, or doping. Here we show that creating a…

Strongly Correlated Electrons · Physics 2016-08-23 Chen Chen , Jisun Kim , V. B. Nascimento , Zhenyu Diao , Jing Teng , Biao Hu , Guorong Li , Fangyang Liu , Jiandi Zhang , Rongying Jin , E. W. Plummer

The modification and tailoring the characteristics of nanostructured materials are of great interest due to controllable and unusual inherent properties in such materials. A simple spray pyrolysis technique is used to prepare pure and…

Applied Physics · Physics 2019-09-24 Mai M. A. Ahmed , Wael Z. Tawfik , M. A. K. Elfayoumi , M. Abdel-Hafiez , S. I. El-Dek

A comparative study of the physical properties of undoped Zinc Oxide (ZnO) and Al doped Zinc Oxide (AZO) thin films were performed as a function of annealing temperature. The structural properties were analyzed using X-ray diffraction and…

Applied Physics · Physics 2019-09-06 Joydip Sengupta , R. K. Sahoo , C. D. Mukherjee

Wurtzite ZnO can be substituted with up to ~30% MgO to form a metastable ZnMgO alloy while still retaining the wurtzite structure. Because this alloy has a larger band gap than pure ZnO, ZnMgO/ZnO quantum wells and superlattices are of…

Other Condensed Matter · Physics 2009-12-16 Andrei Malashevich , David Vanderbilt

ZnO nanostructured films were prepared by chemical bath deposition method on glass substrates without any assistance of either microwave or high pressure autoclaves. The effect of solute concentration on the pure wurtzite ZnO nanostructure…

We present a first-principles study of the relationship between stress, temperature and electronic properties in piezoelectric ZnO. Our method is a plane wave pseudopotential implementation of density functional theory and density…

Materials Science · Physics 2009-10-31 Nicola A. Hill , Umesh Waghmare

Ni-doped MoS$_2$ is a layered material with useful tribological, optoelectronic, and catalytic properties. Experiment and theory on doped MoS$_2$ has focused mostly on monolayers or finite particles: theoretical studies of bulk Ni-doped…

Materials Science · Physics 2021-07-01 Enrique Guerrero , Rijan Karkee , David A. Strubbe

Ion implantation is an interesting method to dope semiconducting materials such as zinc oxide provided that the implantation-induced defects can be subsequently removed. Nitrogen implantation followed by anneals under O2 were carried out on…

We achieve fine tuning of graphene effective doping by applying ultrahigh pressures (> 10 GPa) using Atomic Force Microscopy (AFM) diamond tips. Specific areas in graphene flakes are irreversibly flattened against a SiO2 substrate. Our work…

Point defects in Ga- and Al-doped ZnO thin films are studied by means of first principles electronic structure calculations. Candidate defects are identified to explain recently observed differences in electrical and spectroscopical…

Materials Science · Physics 2016-10-06 E. Menéndez-Proupin , P. Palacios , P. Wahnón

Electron- and hole-doped La$_2$CoMnO$_6$(LCMO) are investigated using first principles DFT calculations. Hole and electron doping are achieved respectively by introducing Sr$^{2+}$ at La$^{3+}$ sites and by inducing O-site vacancies in…

Materials Science · Physics 2021-09-02 Anasua Khan , Swastika Chatterjee , T. K. Nath , A. Taraphder

We study the electronic structure and magnetism of 25% Mn substituted cubic Zirconia (ZrO2) with several homogeneous and heterogeneous doping profiles using density-functional theory calculations. We find that all doping profiles show…

Materials Science · Physics 2008-09-08 Xingtao Jia , Wei Yang , Minghui Qin , Xinglai Zhang , Mingai Sun , Jianping Li