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A simple experimentally accessible realization of current rectification by molecules (molecular films) bridging metal electrodes is described. It is based on the spatial asymmetry of the molecule and requires only one resonant conducting…

Soft Condensed Matter · Physics 2009-11-07 P. E. Kornilovitch , A. M. Bratkovsky , R. S. Williams

The scaling behavior for the rectification of bipolar nanopores is studied using the Nernst-Planck equation coupled to the Local Equilibrium Monte Carlo method. The bipolar nanopore's wall carries $\sigma$ and $-\sigma$ surface charge…

Mesoscale and Nanoscale Physics · Physics 2021-05-24 Dávid Fertig , Zsófia Sarkadi , Mónika Valiskó , Dezső Boda

Superconducting films in perpendicular magnetic field are found to rectify alternating currents. The effect has been observed both in plain and nanostructured superconducting films (niobium and lead). The rectified voltage appears both…

Superconductivity · Physics 2007-05-23 F. G. Aliev , A. P. Levanyuk , R. Villar , E. M. Gonzalez , V. V. Moshchalkov

We study current rectification effect in an asymmetric molecule HOOC-C$_6$H$_4$-(CH$_2$)$_n$ sandwiched between two Aluminum electrodes using an {\sl ab initio} nonequilibrium Green function method. The conductance of the system decreases…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Yan-hong Zhou , Xiao-hong Zheng , Ying Xu , Zhao Yang Zeng

We show the existence of a resonant behavior of the current of Brownian particles confined in a pulsating channel. The interplay between the periodic oscillations of the shape of the channel and a force applied along its axis leads to an…

Soft Condensed Matter · Physics 2016-12-15 M. Florencia Carusela , J. Miguel Rubí

Using the hypernetted-chain/mean spherical approximation (HNC/MSA) integral equations we study the electrical double layer inside and outside a model charged cylindrical vesicle (nanopore) immersed into a primitive model macroions solution,…

Mesoscale and Nanoscale Physics · Physics 2017-10-04 E. González-Tovar , M. Lozada-Cassou

Porous graphene has high mechanical strength and atomic layer thickness, which make it a promising material for material separation and biomolecule sensing. Electrostatic interactions between charges in aqueous solution are a kind of strong…

Chemical Physics · Physics 2016-08-02 Yinghua Qiu , Kun Li , Weiyu Chen , Wei Si , Qiyan Tan , Yunfei Chen

Confinement strongly influences electrochemical systems, where structural control has enabled advances in nanofluidics, sensing, and energy storage. In electric double-layer capacitors (EDLCs), or supercapacitors, energy density is governed…

Chemical Physics · Physics 2026-01-30 Bryce Rives , Filipe Henrique , Pawel Zuk , Ankur Gupta

Asymmetric behaviors of capacitance and charging dynamics in the cathode and anode are general for nanoporous supercapacitors. Understanding this behavior is essential for the optimal design of supercapacitors. Herein, we perform…

Chemical Physics · Physics 2021-05-06 Tangming Mo , Liang Zeng , Zhenxiang Wang , Svyatoslav Kondrat , Guang Feng

A minimal model for coherent transport through a donor/acceptor molecular junction is presented. The two donor and acceptor sites are described by single levels energetically separated by an intramolecular tunnel barrier. In the limit of…

Disordered Systems and Neural Networks · Physics 2009-11-11 Florian Pump , Gianaurelio Cuniberti

We demonstrate that magnetic multilayer nanopillars can be efficiently protected from oxidation by coating with silicon. Both the protected and the oxidized nanopillars exhibit an increase of reversal current at cryogenic temperatures.…

Materials Science · Physics 2009-11-13 Sergei Urazhdin , Phillip Tabor

Extraordinarily large but short electric field pulses are reported by many experiments to cause bipolar cancellation (BPC). This unusual cell response occurs if a first pulse is followed by a second pulse with opposite polarity. Possibly…

Subcellular Processes · Quantitative Biology 2018-07-04 Thiruvallur R. Gowrishankar , Julie V. Stern , Kyle C. Smith , James C. Weaver

In this study, we investigated the ionic current rectification of glass nanopipettes modified with bovine serum albumin - glutaraldehyde (BSA-GA) artificial membrane using solutions with various pHs. Ionic current rectification is a…

Chemical Physics · Physics 2018-02-09 Mustafa Sen

Nanoelectromechanical systems (NEMS) are devices integrating electrical and mechanical functionality on the nanoscale. Because of individual electron tunneling, such systems can show rich self-induced, highly non-linear dynamics. We show…

Mesoscale and Nanoscale Physics · Physics 2021-10-13 Christopher W. Wächtler , Alan Celestino , Alexander Croy , Alexander Eisfeld

The steady-state current-voltage response of ion-selective systems varies as the number of ion-selective components is varied. For the highly investigated unipolar system, including only one ion-selective component, it has been shown that…

Mesoscale and Nanoscale Physics · Physics 2024-11-27 Ramadan Abu-Rjal , Yoav Green

We characterize the role of electrostatic fluctuations on the charge selectivity of cylindrical nanopores confining electrolyte mixtures. To this end, we develop an extended one-loop theory that can account for correlation effects induced…

Soft Condensed Matter · Physics 2014-03-05 Sahin Buyukdagli , T. Ala-Nissila

Nanopore membranes are a versatile platform for a wide range of applications ranging from medical sensing to filtration and clean energy generation. To attain high-flux rectifying ionic flow, it is required to produce short channels…

Mesoscale and Nanoscale Physics · Physics 2023-05-12 Alexander Kiy , Shankar Dutt , Christian Notthoff , Maria E. Toimil-Molares , Nigel Kirby , Patrick Kluth

We observe current rectification in a molecular diode consisting of a semiconducting single-wall carbon nanotube and an impurity. One half of the nanotube has no impurity, and it has a current-voltage (I-V) charcteristic of a typical…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 R. D. Antonov , A. T. Johnson

We present a scaling behavior of a rectifying bipolar nanopore as a function of the parameter $\xi=R_{\mathrm{P}}/(\lambda z_{\mathrm{if}})$, where $R_{\mathrm{P}}$ is the radius of the pore, $\lambda$ is the characteristic screening length…

Mesoscale and Nanoscale Physics · Physics 2020-11-17 Dávid Fertig , Bartłomiej Matejczyk , Mónika Valiskó , Dirk Gillespie , Dezső Boda

The most common method to characterize the electrical response of a nanofluidic system is through its steady-state current-voltage response. In Part I, we demonstrated that this current-voltage response depends on the geometry, the layout…

Mesoscale and Nanoscale Physics · Physics 2025-06-11 Ramadan Abu-Rjal , Yoav Green