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How should one define thermodynamic quantities (internal energy, work, heat, etc.) for quantum systems coupled to their environments strongly? We examine three (classically equivalent) definitions of a quantum system's internal energy under…

In this paper, unambiguous redefinitions of heat and work are presented for quantum thermodynamic systems. We will use genuine reasoning based on which Clausius originally defined work and heat in establishing thermodynamics. The change in…

Quantum Physics · Physics 2023-03-15 B. Ahmadi , S. Salimi , A. S. Khorashad

Accurately describing work extraction from a quantum system is a central objective for the extension of thermodynamics to individual quantum systems. The concepts of work and heat are surprisingly subtle when generalizations are made to…

Quantum Physics · Physics 2015-03-30 Felix C. Binder , Sai Vinjanampathy , Kavan Modi , John Goold

Assigning the variations of internal energy into heat or work contributions is a challenging task due to the fact that these properties are trajectory dependent. A number of proposals have been put forward for open quantum systems following…

Quantum Physics · Physics 2021-09-01 Adrián Juan-Delgado , Aurélia Chenu

Operational quantum stochastic thermodynamics is a recently proposed theory to study the thermodynamics of open systems based on the rigorous notion of a quantum stochastic process or quantum causal model. In there, a stochastic trajectory…

Quantum Physics · Physics 2020-03-04 Philipp Strasberg

Underlying the classical thermodynamic principles are analogous microscopic laws, arising from the fundamental axioms of quantum mechanics. These define quantum thermodynamic variables such as quantum work and heat and characterize the…

Quantum Physics · Physics 2023-05-03 Roie Dann , Ronnie Kosloff

Understanding how to assign internal energy, heat, and work in quantum systems beyond weak coupling remains a central problem in quantum thermodynamics, particularly as the difference between competing definitions becomes increasingly…

Quantum Physics · Physics 2025-10-09 Alessandra Colla , Bassano Vacchini , Andrea Smirne

The separation of internal energy into heat and work in quantum thermodynamics is a controversial issue for a long time, and we revisit and solve this problem in this work. It is shown that the Hamiltonian plays dual roles for a quantum…

Quantum Physics · Physics 2025-01-03 Tao Zhou , Jiangyang Pu , Xiaohua Wu

We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths beyond perturbation theory. Our approach is based on the exact time-local quantum master equation for the reduced open…

Quantum Physics · Physics 2022-05-31 Alessandra Colla , Heinz-Peter Breuer

A key question in the thermodynamics of open quantum systems is how to partition thermodynamic quantities such as entropy, work, and internal energy between the system and its environment. We show that the only partition under which entropy…

Quantum Physics · Physics 2024-10-22 Parth Kumar , Caleb M. Webb , Charles A. Stafford

We study the nonequilibrium thermodynamics of pure decoherence processes in open quantum systems coupled to a thermal reservoir. We review various definitions of central quantities, such as internal energy, work, heat and entropy…

Quantum Physics · Physics 2025-06-16 Irene Ada Picatoste , Alessandra Colla , Heinz-Peter Breuer

Quantum thermodynamics has emerged as a central field for understanding how energy conversion processes occur in microscopic systems. In these systems, effects such as coherence, entanglement, and non-Markovianity play key roles. In this…

Quantum Physics · Physics 2025-12-02 J. M. Z. Choquehuanca

We take the perspective of open quantum systems and examine from their nonequilibrium dynamics the conditions when the physical quantities, their relations and the laws of thermodynamics become well defined and viable for quantum many body…

Quantum Physics · Physics 2018-01-30 Jen-Tsung Hsiang , C. H. Chou , Y. Subaşi , B. L. Hu

Considering an entropy-based division of energy transferred into heat and work, we develop an alternative theoretical framework for the thermodynamic analysis of two-level systems. When comparing these results with those obtained under the…

Quantum Physics · Physics 2021-04-14 Andrés Vallejo , Alejandro Romanelli , Raúl Donangelo

We study heat transfers in a single level quantum dot strongly coupled to fermionic reservoirs and subjected to a time-dependent protocol modulating the dot energy as well as the dot-reservoir coupling strength. The dynamics is described…

Statistical Mechanics · Physics 2016-01-01 Massimiliano Esposito , Maicol A. Ochoa , Michael Galperin

A key objective in nuclear and high-energy physics is to describe nonequilibrium dynamics of matter, e.g., in the early universe and in particle colliders, starting from the Standard Model. Classical-computing methods, via the framework of…

Understanding thermodynamics far from equilibrium at the quantum scale remains a fundamental challenge, particularly in the presence of quantum coherence. Here we develop a first-principles framework for nonequilibrium quantum…

Quantum Physics · Physics 2026-02-11 Md Manirul Ali , Po-Wen Chen

Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for closed and open quantum systems far from equilibrium, where…

Quantum Physics · Physics 2021-08-31 Philipp Strasberg , Andreas Winter

The internal energy of individual subsystems is not well defined in interacting quantum systems, leading to ambiguities in the definition of thermodynamic quantities. Applying the Schmidt basis formalism to general bipartite autonomous…

Quantum Physics · Physics 2024-09-27 Fabricio Toscano , Diego A. Wisniacki

The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…

Statistical Mechanics · Physics 2015-11-18 Robert H. Swendsen
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