Related papers: Methanol deuteration in high-mass protostars

Deuterium fractionation in the closest vicinity of a protostar is important in understanding its potential heritage to a planetary system. Here, we have detected the spectral line emission of CH3OH and its three deuterated species, CH2DOH,…

Methanol is the most complex molecule securely identified in interstellar ices and is a key chemical species for understanding chemical complexity in astrophysical environments. Important aspects of the methanol ice photochemistry are still…

We present the results of our studies of deuterated molecules (DCN, DNC, DCO$^+$, N$_2$D$^+$ and NH$_2$D) in regions of high-mass star formation, which include a survey of such regions with the 20-m Onsala radio telescope and mapping of…

The results of a maser survey toward ninety-nine protostars in the Orion molecular cloud complex are presented. The target sources are low-mass protostars identified from infrared observations. Single-dish observations were carried out in…

Observations of star forming environments revealed that the abundances of some deuterated interstellar molecules are markedly larger than the cosmic D/H ratio of 10-5. Possible reasons for this pointed to grain surface chemistry. How- ever,…

The deuterium fractionation of water can serve as a tracer for the chemical and physical evolution of water during star formation and can constrain the origin of water in Solar System bodies. We determine the HDO/H$_2$O ratio in the inner…

The dependence of the proton-to-electron mass ratio, mu, on the local matter density was investigated using methanol emission in the dense dark cloud core L1498. Towards two different positions in L1498, five methanol transitions were…

Context. The spatial distribution of molecules around starless cores is a powerful tool for studying the physics and chemistry governing the earliest stages of star formation. Aims. Our aim is to study the chemical differentiation in…

Numerical calculations of the sensitivity coefficients, Q_mu, of microwave molecular transitions in the ground torsion-rotation state of deuterated methanol (CH3OD, CD3OH, and CD3OD) to small variations in the fundamental physical constant…

We have performed experimental investigations of methanol formation via the reactions of low energy $CH_{3}^{+}$ ions with an amorphous solid water (ASW) surface around 10 K. A newly developed experimental apparatus enabled irradiation of…

Formaldehyde is a key precursor in the formation routes of many complex organic molecules (COMs) in space. It is also an intermediate step in CO hydrogenation sequence that leads to methanol formation on the surface of interstellar grains…

Observations of low mass protostars which probe small enough size scales to be within likely CO depletion regions show the highest [NH2D]/[NH3] ratios yet measured, of 4--33%. These molecular D/H ratios are higher than those measured on…

Complex organic molecules are only detected toward a fraction of high-mass protostars. The goal of this work is to investigate whether high-mass disks can explain the lack of methanol emission from some massive protostellar systems. We…

Water and methanol are key components of interstellar ices and gas in star- and planet-forming regions, but direct observations of water in low-mass protostars are challenging due to atmospheric absorption. We present high-resolution (R =…

Deuteration is a powerful tracer of the history of the cold prestellar phase in star forming regions. Apart from methanol, little is known about deuterium fractionation of complex organic molecules in the interstellar medium, especially in…

The abundances of deuterated molecules with respect to their main isotopologue counterparts have been determined to be orders of magnitude higher than expected from the cosmic abundance of deuterium relative to hydrogen. The increasing…

Context. Class II methanol masers at 6.7 and 12.2 GHz occur close to high-mass young stellar objects (HMYSOs). When they are observed simultaneously, such studies may contribute to refining the characterisation of local physical conditions.…

We present an interferometric survey of the 44 GHz class I methanol maser transition toward a sample of 69 sources consisting of High Mass Protostellar Object candidates and Ultracompact (UC) H II regions. We found a 38% detection rate (16…

We report the detection of methanol in the disk around the young outbursting star V883 Ori with the Atacama Large Millimeter/submillimeter Array (ALMA). Four transitions are observed with upper level energies ranging between 115 and 459 K.…

We present experimental results obtained from photoionization and photodissociation processes of abundant interstellar methanol (CH$_3$OH) as an alternative route for the production of H$_3^+$ in dense clouds. The measurements were taken at…