Related papers: Microscopic Theory of Adsorption Kinetics
The wave mechanics theory of microwave absorption challenges the long-standing impedance-matching and quarter-wavelength paradigms by demonstrating that conventional models mistakenly conflate bulk material parameters with thin-film…
We consider fluid adsorption near a rectangular edge of a solid substrate that interacts with the fluid atoms via long range (dispersion) forces. The curved geometry of the liquid-vapour interface dictates that the local height of the…
Simulations of the kinetic friction due to a layer of adsorbed molecules between two crystalline surfaces are presented. The adsorbed layer naturally produces friction that is consistent with Amontons' laws and insensitive to parameters…
We present a density-functional theory study addressing the on-surface adsorption of oxygen at the Pd(11N) (N =3,5,7) vicinal surfaces, which exhibit (111) steps and (100) terraces of increasing width. We find the binding to be…
We examine the phase transition of polymer adsorption as well as the underlying kinetics of polymer binding from dilute solutions on a structureless solid surface. The emphasis is put on the properties of regular multiblock copolymers,…
The Gibbs adsorption equation is the thermodynamic cornerstone for the description and understanding of the surface tension in a surfactant solution. It relates the decrease in surface tension to an increased surfactant adsorption. In the…
We investigate the critical behavior of a reaction-diffusion system exhibiting a continuous absorbing-state phase transition. The reaction-diffusion system strictly conserves the total density of particles, represented as a non-diffusive…
We present a detailed, microscopic transport theory for light in strongly scattering disordered systems whose constituent materials exhibit linear absorption or gain. Starting from Maxwell's equations, we derive general expressions for…
The dip-coating geometry, where a solid plate is withdrawn from or plunged into a liquid pool, offers a prototypical example of wetting flows involving contact-line motion. Such flows are commonly studied using the lubrication approximation…
A new approach that is a combination of classical thermodynamics and macroscopic kinetics is offered for studying the nucleation kinetics in condensed binary solutions. The theory covers the separation of liquid and solid solutions…
A new three-dimensional (3D) multiphase computational fluid dynamics (CFD) model for adsorption physics in packed beds of spherical beads is developed and validated. The model is constituted at a macroscopic scale that integrates new…
The mathematical model of surfactant adsorption under mixed barrier-diffusion control is analyzed using techniques from fractional calculus. The kinetic models of Henry, Langmuir, Frumkin, Volmer and van der Waals are considered. First,…
Surface adsorption, which is often coupled with surface dissolution, is generally unpredictable on alloys due to the complicated alloying and dissolution effects. Herein, we introduce the electronic gradient and cohesive properties of…
Conventional wetting theories on rough surfaces with Wenzel, Cassie-Baxter, and Penetrate modes suggest the possibility of tuning the contact angle by adjusting the surface texture. Despite decades of intensive study, there are still many…
Experiments of periodically sheared colloidal suspensions or soft amorphous solids display a transition from reversible to irreversible particle motion that, when analysed stroboscopically in time, is interpreted as an absorbing phase…
The success of density functional theory for the description of the adsorption of atoms on surfaces is well established, and based on recent calculations using gradient corrections, it has been shown that it also describes well the…
Extensive density-functional calculations are performed for chemisorption of atoms in the three first periods (H, B, C, N, O, F, Al, Si, P, S, and Cl) on the polar TiC(111) surface. Calculations are also performed for O on TiC(001), for…
The percolation of a liquid through a porous material is investigated with the help of equations of the Onsager type. An expression is derived for the molecular attraction, starting from Sutherland's potential approximation to the van der…
We develop a theory of static friction by modeling the homogeneous surfaces of contact as being composed of a regular array of compressible elastic smooth microscopic inclines. Static friction is thought of as the resistance due to having…
This review explores particle resuspension from surfaces due to fluid flows. The objective of this review is to provide a general framework and terminology for particle resuspension while highlighting the future developments needed to…