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Currently, there is a growing interest in the development of a new hierarchy of methods based on the concept of seniority, which has been introduced quite recently in quantum chemistry. Despite the enormous potential of these methods, the…

Chemical Physics · Physics 2022-12-07 Bruno Senjean , Saad Yalouz , Naoki Nakatani , Emmanuel Fromager

The crucial step in density-corrected Hartree-Fock density functional theory (DC(HF)-DFT) is to decide whether the density produced by the density functional for a specific calculation is erroneous and hence should be replaced by, in this…

Chemical Physics · Physics 2023-09-20 Daniel Graf , Alex J. W. Thom

Classical density functional theory (DFT) provides an exact variational framework for determining the equilibrium properties of inhomogeneous fluids. We report a generalization of DFT to treat the non-equilibrium dynamics of classical…

Soft Condensed Matter · Physics 2013-09-06 Matthias Schmidt , Joseph M. Brader

Context. The overdensity inside a cosmological sub-volume and the tidal fields from its surroundings affect the matter distribution of the region. The resulting difference between the local and global power spectra is characterized by the…

Cosmology and Nongalactic Astrophysics · Physics 2022-05-11 Gábor Rácz , István Szapudi , István Csabai

We extend to strongly correlated molecular systems the recently introduced basis-set incompleteness correction based on density-functional theory (DFT) [E. Giner et al., J. Chem. Phys. 149, 194301 (2018)]. This basis-set correction relies…

Chemical Physics · Physics 2020-05-20 Emmanuel Giner , Anthony Scemama , Pierre-François Loos , Julien Toulouse

Nuclear density functional theory is the prevalent theoretical framework for accurately describing nuclear properties at the scale of the entire chart of nuclides. Given an energy functional and a many-body scheme (e.g., single- or…

Nuclear Theory · Physics 2020-06-19 N. Schunck , J. O'Neal , M. Grosskopf , E. Lawrence , S. M. Wild

Constrained density functional theory (cDFT) is a versatile electronic structure method that enables ground-state calculations to be performed subject to physical constraints. It thereby broadens their applicability and utility. Automated…

Other Condensed Matter · Physics 2016-08-03 David D. O'Regan , Gilberto Teobaldi

We prove a novel inversion theorem for functionals given as power series in infinite-dimensional spaces and apply it to the inversion of the density-activity relation for inhomogeneous systems. This provides a rigorous framework to prove…

Mathematical Physics · Physics 2019-09-11 Sabine Jansen , Tobias Kuna , Dimitrios Tsagkarogiannis

An efficient solution of the Dirac Hamiltonian flow equations has been proposed through a novel expandsion with the inverse of the Dirac effective mass. The efficiency and accuracy of this new expansion have been demonstrated by reducing a…

Nuclear Theory · Physics 2019-10-31 Z. X. Ren , P. W. Zhao

Dirac materials are of great interest as condensed matter realizations of the Dirac and Weyl equations. In particular, they serve as a starting point for the study of topological phases. This physics has been extensively studied in…

Mesoscale and Nanoscale Physics · Physics 2020-08-11 P. Sathish Kumar , Igor F. Herbut , R. Ganesh

We consider the tight-binding model of graphene with slowly spatially varying hopping functions. We develop a low energy approximation as a derivative expansion in a Dirac spinor that is perturbative in the hopping function deformation. The…

High Energy Physics - Theory · Physics 2023-08-16 Matthew M. Roberts , Toby Wiseman

We introduce a density basis of the trigonometric polynomials that is suitable to mixture modelling. Statistical and geometric properties are derived, suggesting it as a circular analogue to the Bernstein polynomial densities. Nonparametric…

Methodology · Statistics 2019-02-26 Olivier Binette , Simon Guillotte

The spectroscopic quality of covariant density functional theory has been accessed by analyzing the accuracy and theoretical uncertainties in the description of spectroscopic observables. Such analysis is first presented for the energies of…

Nuclear Theory · Physics 2015-08-25 A. V. Afanasjev

The deformed relativistic Hartree-Bogoliubov theory in continuum with the density-dependent meson-nucleon couplings is developed. The formulism is briefly presented with the emphasis on handling the density-dependent couplings, meson…

Nuclear Theory · Physics 2012-06-06 Ying Chen , Lulu Li , Haozhao Liang , Jie Meng

Accurate determination of electronic properties of correlated oxides remains a significant challenge for computational theory. Traditional Hubbard-corrected density functional theory (DFT+U) frequently encounters limitations in precisely…

Materials Science · Physics 2024-03-19 Hyeondeok Shin , Kevin Gasperich , Tomas Rojas , Anh T. Ngo , Jaron T. Krogel , Anouar Benali

We derive the low energy effective theory on a brane in six-dimensional chiral supergravity. The conical 3-brane singularities are resolved by introducing cylindrical codimension one 4-branes whose interiors are capped by a regular…

High Energy Physics - Theory · Physics 2009-05-20 Frederico Arroja , Tsutomu Kobayashi , Kazuya Koyama , Tetsuya Shiromizu

We present a systematic Density Functional Theory (DFT) study of geometries and energies of the nucleic acid DNA bases (guanine, adenine, cytosine and thymine) and 30 different DNA base-pairs. We use a recently developed linear-scaling DFT…

Chemical Physics · Physics 2007-05-23 Maider Machado , Pablo Ordejon , Emilio Artacho , Daniel Sanchez-Portal , Jose M. Soler

The density functional theory of nuclear structure provides a many-particle wave function that is useful for static properties, but an extension of the theory is necessary to describe correlation effects or other dynamic properties. Here we…

Nuclear Theory · Physics 2009-11-11 Y. Alhassid , G. F. Bertsch , L. Fang , B. Sabbey

Empirical fitting of parameters in approximate density functionals is common. Such fits conflate errors in the self-consistent density with errors in the energy functional, but density-corrected DFT (DC-DFT) separates these two. We…

Chemical Physics · Physics 2020-12-02 Suhwan Song , Stefan Vuckovic , Eunji Sim , Kieron Burke

Relativistic Hartree-Fock-Bogoliubov (RHFB) theory with density-dependent meson-nucleon couplings is presented. The integro-differential RHFB equations are solved by expanding the different components of the quasi-particle spinors in the…

Nuclear Theory · Physics 2010-04-06 Wen Hui Long , Peter Ring , Nguyen Van Giai , Jie Meng
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