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The properties of MgO/Ag(001) ultrathin films with substitutional Mg atoms in the interface metal layer have been investigated by means of Auger electron diffraction experiments, ultraviolet photoemission spectroscopy, and density…

Materials Science · Physics 2014-11-26 T. Jaouen , P. Aebi , S. Tricot , G. Delhaye , B. Lépine , D. Sébilleau , G. Jézéquel , P. Schieffer

We study structural and electronic properties of graphene grown on SiC substrate using scanning tunneling microscope (STM), spot-profile-analysis low energy electron diffraction (SPA-LEED) and angle resolved photoemission spectroscopy…

Mesoscale and Nanoscale Physics · Physics 2017-07-19 Lunan Huang , Yun Wu , M. T. Hershberger , Daixiang Mou , Ben Schrunk , Michael C. Tringides , Myron Hupalo , Adam Kaminski

CO$_2$ capture using carbon-based materials, particularly graphene and graphene-like materials, is a promising strategy to deal with CO$_2$ emissions. However, significant gaps remain in our understanding of the molecular-level interaction…

Graphene oxide (GO) holds significant promise for electronic devices and nanocomposite materials. A number of models were proposed for GO structure, combining carboxyl, hydroxyl, carbonyl and epoxide groups at different locations. The…

Materials Science · Physics 2015-10-28 Vitaly V. Chaban , Oleg V. Prezhdo

Heterostructures involving graphene and bismuth, with their ability to absorb light over a very wide energy range, are of interest for engineering next-generation opto-electronics. Critical to the technological application of such…

Materials Science · Physics 2020-05-20 Ivan I. Naumov , Pratibha Dev

The interlayer gallery between two adjacent sheets of van der Waals materials is expected to modify properties of atoms and molecules confined at the atomic interfaces. Here, we directly image individual hydrogen atom intercalated between…

Mesoscale and Nanoscale Physics · Physics 2018-02-14 Wen-Xiao Wang , Yi-Wen Wei , Si-Yu Li , Xinqi Li , Xiaosong Wu , Ji Feng , Lin He

The calculated results of FeCl3 graphite intercalation compounds show the detailed features. The stage-1 FeCl3-graphite intercalation compounds present diversified electronic properties due to the intercalant. The first-principles…

Materials Science · Physics 2021-01-01 Li Wei-Bang , Lin Shih-Yang , Tsai Ming-Shuei , Lin Ming-Fa , Lin Kuang-I

We compute ionic free energy adsorption profiles at aqueous graphene interface by developing a self-consistent approach. To do so, we design a microscopic model for water and put the liquid on an equal footing with the graphene described by…

Soft Condensed Matter · Physics 2023-03-01 Anton Robert , Hélène Berthoumieux , Marie-Laure Bocquet

Hot electrons undergo Auger scattering during their relaxation process has a multiplication effect,which can generate more electrons above the Fermi level, thus improving the efficiency of photoelectric signal conversion.However,the…

We have investigated theoretically the adsorption of molecules onto graphene with divacancy defects. Using ab-initio density functional calculations, we have found that O2, CO, N2, B2 and H2O molecules all interact strongly with a divacancy…

Materials Science · Physics 2015-05-13 Biplab Sanyal , Olle Eriksson , Ulf Jansson , Helena Grennberg

Experimental and theoretical studies of manganese deposition on graphene/Ni(111) shows that a thin ferromagnetic Ni3Mn layer, which is protected by the graphene overlayer, is formed upon Mn intercalation. The electronic bands of graphene…

The distribution of ions and their impact on the structure of electrolyte interfaces plays an important role in many applications. Interestingly, recent experimental studies have suggested the preferential accumulation of $SO_4^{2-}$ ions…

Chemical Physics · Physics 2026-05-11 Ademola Soyemi , Tibor Szilvasi

The interaction between protons and graphene is attracting a large interest due to recent experiments showing that these charged species permeate through the 2D material following a low barrier (~ 0.8 eV) activated process. A possible…

Mesoscale and Nanoscale Physics · Physics 2019-01-10 Massimiliano Bartolomei , Marta I. Hernández , José Campos-Martınez , Ramón Hernández Lamoneda

The results of density functional theory calculations and measurements using X-ray photoelectron spectroscopy of Co-nanoparticles dispersed on graphene/Cu are presented. It is found that for low cobalt thickness (0.02 nm - 0.06 nm) the Co…

The inter-band optical absorption in graphene characterized by its fine-structure constant has a universal value of 2.3\% independent of the material parameters. However, for several graphene-based photonic applications, enhanced optical…

Materials Science · Physics 2016-03-23 Shaloo Rakheja , Parijat Sengupta

Optical properties of graphene are explored by using the generalized tight-binding model. The main features of spectral structures, the form, frequency, number and intensity, are greatly enriched by the complex relationship among the…

Computational Physics · Physics 2016-07-20 Chiun-Yan Lin , Thi-Nga Do , Yao-Kung Huang , Ming-Fa Lin

Graphene-based materials are the focus of intense research efforts to devise novel theranostic strategies for targeting the central nervous system. In this work, we have investigated the consequences of long-term exposure of primary rat…

We employ molecular dynamic simulations to study the reduction process of graphene-oxide (GO) in a chemically active environment enriched with hydrogen. We examine the concentration and pressure of hydrogen gas as a function of temperature…

Materials Science · Physics 2016-09-28 Ramin M. Abolfath , Kyeongjae Cho

Hydration properties of graphene oxide (GO) are essential for most of its potential applications. In this work, we employ atomistic molecular dynamics simulations to investigate seven GO compositions with different levels of oxygenation.…

Materials Science · Physics 2018-02-14 Antenor Neto , Vitaly V. Chaban , Eudes E. Fileti

We perform a detailed analysis of electronic polarizability of graphene with different theoretical approaches. From Kubo's linear response formalism, we give a general expression of frequency and wave-vector dependent polarizability within…

Mesoscale and Nanoscale Physics · Physics 2021-03-31 Tao Zhu , Mauro Antezza , Jian-Sheng Wang