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We present the magnetic properties of complete solid solutions of ZnCr$_2$O$_4$ and CoCr$_2$O$_4$: two well-studied oxide spinels with very different magnetic ground states. ZnCr$_2$O$_4$, with non-magnetic $d^{10}$ cations occupying the A…

Materials Science · Physics 2009-06-04 Brent C. Melot , Jennifer E. Drewes , Ram Seshadri , Arthur P. Ramirez

The $T$-dependence (2- 400 K) of the electron paramagnetic resonance (EPR), magnetic susceptibility, $\chi (T)$, and specific heat, $C_{v}(T)$, of the $normal$ antiferromagnetic (AFM) spinel ZnCr$_{2}$O$_{4}$ and the spin-glass (SG)…

The chromium spinels MgCr2O4 and ZnCr2O4 are prime examples of the highly frustrated pyrochlore lattice antiferromagnet. Experiment has carefully established that both materials, upon cooling, distort to lower symmetry and order…

Strongly Correlated Electrons · Physics 2025-02-28 Ludovic D. C. Jaubert , Yasir Iqbal , Harald O. Jeschke

In this work, a study of the magnetic behavior of the spinel ZnFe2O4 is presented by using the Monte Carlo simulations (MCS). The iron atoms provide the magnetism in this material. In fact, the magnetic spin of moment of the Fe3+ ions is…

Materials Science · Physics 2020-02-18 R. Khalladi , S. Idrissi , N. El Mekkaoui , H. Labrim , I. El Housni , S. Ziti , S. Mtougui , L. Bahmad

The crystal and magnetic structures of the spinel compounds ZnCr$_2$S$_4$ and ZnCr$_2$Se$_4$ were investigated by high resolution powder synchrotron and neutron diffraction. ZnCr$_2$Se$_4$ exhibits a first order phase transition at $T_N=21$…

Strongly Correlated Electrons · Physics 2009-11-13 F. Yokaichiya , A. Krimmel , V. Tsurkan , I. Margiolaki , P. Thompson , H. N. Bordallo , A. Buchsteiner , N. Stüßer , D. N. Argyriou , A. Loidl

We report the bulk magnetic properties of a yet unexplored vanadium-based multivalued spinel system, Zn3V3O8. A Curie-Weiss fit of our dc magnetic susceptibility data in the temperature region from 140 to 300 K yields a Curie constant C =…

Strongly Correlated Electrons · Physics 2015-06-22 Tanmoy Chakrabarty , Avinash V. Mahajan , Susanta Kundu

Ultrasound and magnetization studies of bond-frustrated ZnCr2S4 spinel are performed in static magnetic fields up to 18 T and in pulsed fields up to 62 T. At temperatures below the antiferromagnetic transition at T_N1 14 K the sound…

Strongly Correlated Electrons · Physics 2015-03-19 V. Tsurkan , S. Zherlitsyn , V. Felea , S. Yasin , Yu. Skourski , J. Deisenhofer , H. -A. Krug von Nidda , P. Lemmens , J. Wosnitza , A. Loidl

The intermetallic compound Nd$_2$Co$_{0.85}$Si$_{2.88}$ having a triangular lattice could be synthesized in single-phase only with defect crystal structure. Investigation through different experimental techniques indicate the presence of…

Co$_{1-x}$Mn$_x$Cr$_2$O$_4$ crystallizes as a normal spinel in the cubic $Fd \overline{3}m$ space group, and the end members have been reported to display a region of collinear ferrimagnetism as well as a low-temperature spin-spiral state…

We re-investigate the magnetically frustrated, {\it diamond-lattice-antiferromagnet} spinels FeAl$_2$O$_4$ and MnAl$_2$O$_4$ using magnetization measurements and diffuse scattering of polarized neutrons. In FeAl$_2$O$_4$, macroscopic…

Disordered Systems and Neural Networks · Physics 2015-06-19 Harikrishnan S. Nair , Zhendong Fu , Jörg Voigt , Yixi Su , Th. Brückel

The effects of magnetic dilution and applied pressure on frustrated spinel Ni$_{2-x}$Mg$_{x}$GeO$_{4}$ (0 $\leq x \leq 1.0$) are analyzed using specific heat, AC and DC magnetization and x-ray diffraction. The parent compound has two…

Materials Science · Physics 2015-11-11 J. T. Korobanik , K. Caslin , P. Reuvekamp , F. S. Razavi

We report detailed dc and ac magnetic susceptibilities, specific heat, and thermal conductivity measurements on the frustrated magnet ZnCr$_2$Se$_4$. At low temperatures, with increasing magnetic field, this spinel material goes through a…

Strongly Correlated Electrons · Physics 2018-04-10 C. C. Gu , Z. Y. Zhao , X. L. Chen , M. Lee , E. S. Choi , Y. Y. Han , L. S. Ling , L. Pi , Y. H. Zhang , G. Chen , Z. R. Yang , H. D. Zhou , X. F. Sun

Co$_3$O$_4$, ZnFe$_2$O$_4$, CoFe$_2$O$_4$, ZnCo$_2$O$_4$, and Fe$_3$O$_4$ thin films were fabricated by pulsed laser deposition at high and low temperatures resulting in crystalline single-phase normal, inverse, as well as disordered spinel…

Spintronics has emerged as a field of vast applicability, and layered magnetic materials have served as a ground for advancement in this direction. Here, we report the synthesis and detailed magnetic and specific heat studies on NdSbSe, (a…

Strongly Correlated Electrons · Physics 2025-01-22 Prabuddha Kant Mishra , Priyanka Nehla , Rishabh Shukla , Rie Umetsu , Ashok Kumar Ganguli

We report on x-ray diffraction, magnetic susceptibility, electron- spin resonance and heat- capacity studies of Co[Al_1-xCo_x]_2O_4 for Co concentrations 0<x<1. In this spinel system only the A-site Co^2+ cation is magnetic, while the…

Materials Science · Physics 2009-11-13 N. Tristan , V. Zestrea , G. Behr , R. Klingeler , B. Buechner , H. A. Krug von Nidda , A. Loidl , V. Tsurkan

We examine the evolution of magnetic properties in the normal spinel oxides Mg(1-x)Cu(x)Cr2O4 using magnetization and heat capacity measurements. The end-member compounds of the solid solution series have been studied in some detail because…

Materials Science · Physics 2012-09-11 Moureen C. Kemei , Stephanie L. Moffitt , Daniel P. Shoemaker , Ram Seshadri

In both spinel compounds GeCo$_2$O$_4$ and GeNi$_2$O$_4$ which order antiferromagnetically (at $T_N = 23.5 K$ and $T_{N_1} = 12.13 K$, $T_{N_2} = 11.46 K$) with different Curie Weiss temperatures ($T_{CW}$=80.5 K and -15 K), the usual…

Strongly Correlated Electrons · Physics 2009-11-11 Sébastien Diaz , Sophie De Brion , G. Chouteau , Benjamin Canals , Virginie Simonet , P. Strobel

Pure ultrafine ZnFe2O4 particles have been obtained from mechanosynthesis of the ZnO and Fe2O3 oxides. The average grain diameter was estimated from x-ray diffraction to be <d> = 36(6) nm. Refinement of neutron diffraction (ND) data showed…

Materials Science · Physics 2013-02-07 G. F. Goya , H. R. Rechenberg , M. Chen , W. B. Yelon

We have investigated the structural and magnetic properties of a new cubic spinel LiZn$_{2}$V$_{3}$O$_{8}$ (LZVO) through x-ray diffraction, dc and ac susceptibility, magnetic relaxation, aging, memory effect, heat capacity and $^{7}$Li…

Strongly Correlated Electrons · Physics 2020-01-01 S. Kundu , T. Dey , A. V. Mahajan , N. Büttgen

Magnetic properties of heterometallic warwickites $MgFeBO_4$, $Mg_{0.5}Co_{0.5}FeBO_4$, and $CoFeBO_4$ are presented, highlighting the effect of Co substitution on the magnetic properties of these compounds. The analysis of magnetization…

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