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In this article, we study zigzag graphene nanoribbons with edges reconstructed with Stone-Wales defects, by means of an empirical (first-neighbor) tight-binding method, with parameters determined by ab-initio calculations of very narrow…

Zigzag nanoribbons of monolayer graphene-like two-dimensional materials host spontaneous edge magnetism at the zigzag terminations, whose configuration controls the band gap. In this article, the edge magnetism of zigzag nanoribbons of…

Mesoscale and Nanoscale Physics · Physics 2022-01-12 Ma Luo

We present a scheme to categorize the structure of different layered phosphorene allotropes by mapping their non-planar atomic structure onto a two-color 2D triangular tiling pattern. In the buckled structure of a phosphorene monolayer, we…

Computational Physics · Physics 2014-11-25 Jie Guan , Zhen Zhu , David Tománek

The graphene and phosphorene nanostructures have a big potential application in a large area of actuals research in physics. However, their methods of synthesis still do not allow the production of perfect materials with an intact molecular…

Mesoscale and Nanoscale Physics · Physics 2018-02-23 Jan Smotlacha , Richard Pincak

We demonstrate that free graphene sheet edges can curl back on themselves,reconstructing as nanotubes. This results in lower formation energies than any other non-functionalised edge structure reported to date in the literature. We…

In this paper, we have studied functionalization of 5-7 edge-reconstructed graphene nanoribbons by ab initio density functional calculations. Our studies show that hydrogenation at the reconstructed edges is favorable in contrast to the…

Mesoscale and Nanoscale Physics · Physics 2012-10-04 Soumyajyoti Haldar , Sumanta Bhandary , Satadeep Bhattacharjee , Olle Eriksson , Dilip Kanhere , Biplab Sanyal

Phosphorene, the monolayer form of the (black) phosphorus, was recently exfoliated from its bulk counterpart. Phosphorene oxide, by analogy to graphene oxide, is expected to have novel chemical and electronic properties, and may provide an…

Materials Science · Physics 2015-06-22 Gaoxue Wang , Ravindra Pandey , Shashi P. Karna

Phosphorene, a 2D allotrope of phosphorus, is technologically very appealing because of its semiconducting properties and narrow band gap. Further reduction of the phosphorene dimensionality may spawn exotic properties of its electronic…

Polarization resolved micro-Raman spectroscopy was carried out at the edges of bilayer graphene. We find strong dependence of the intensity of the G band on the incident laser polarization, with its intensity dependence being 90 degrees out…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Milan Begliarbekov , Onejae Sul , Sokratis Kalliakos , Eui-Hyeok Yang , Stefan Strauf

Thin layers of black phosphorus have recently raised interest for their two-dimensional (2D) semiconducting properties, such as tunable direct bandgap and high carrier mobilities. This lamellar crystal of P atoms stacked together by weak…

Mesoscale and Nanoscale Physics · Physics 2014-08-22 A. Favron , E. Gaufrès , F. Fossard , P. L. Lévesque , A-L. Phaneuf-L'Heureux , N. Y-W. Tang , A. Loiseau , R. Leonelli , S. Francoeur , R. Martel

By virtue of being atomically thin, the electronic properties of heterostructures built from two-dimensional materials are strongly influenced by atomic relaxation. The atomic layers behave as flexible membranes rather than rigid crystals.…

Strongly Correlated Electrons · Physics 2025-01-07 Mohammed M. Al Ezzi , Gayani N. Pallewela , Christophe De Beule , E. J. Mele , Shaffique Adam

Phosphorene, a single atomic layer of black phosphorus, has recently emerged as a new twodimensional (2D) material that holds promise for electronic and photonic technology. Here we experimentally demonstrate that the electronic structure…

Graphene-based nanostructures exhibit a vast range of exciting electronic properties that are absent in extended graphene. For example, quantum confinement in carbon nanotubes and armchair graphene nanoribbons (AGNRs) leads to the opening…

The edge physics of graphene based systems is well known to be highly sensitive to the atomic structure at the boundary, with localized zero mode edge states found only on the zigzag type termination of the lattice. Here we demonstrate that…

Mesoscale and Nanoscale Physics · Physics 2018-05-30 M. Fleischmann , R. Gupta , D. Weckbecker , W. Landgraf , O. Pankratov , V. Meded , S. Shallcross

Three two-dimensional phosphorus nitride (PN) monolayer sheets (named as $\alpha$-, $\beta$-, and $\gamma$-PN, respectively) with fantastic structures and properties are predicted based on first-principles calculations. The $\alpha$-PN and…

Materials Science · Physics 2015-10-02 ShuangYing Ma , Chaoyu He , L. Z. Sun , Haiping Lin , Youyong Li , K. W. Zhang

Thin adhesive films can be removed from substrates, torn, and folded in distinct geometries under external driving forces. In two-dimensional materials, however, these processes can be self-driven as shown in previous studies on folded…

Mesoscale and Nanoscale Physics · Physics 2019-07-15 Johannes C. Rode , Dawei Zhai , Christopher Belke , Sung J. Hong , Hennrik Schmidt , Nancy Sandler , Rolf J. Haug

Achieving atomic precision in top-down manufacturing remains a fundamental challenge nanofabrication technology. Here, the focused electron beam of a scanning transmission electron microscope is used to demonstrate atomically precise…

Materials Science · Physics 2026-02-20 Ondrej Dyck , Andrew R. Lupini , Ivan Vlassiouk , Matthew Brahlek , Rob Moore , Stephen Jesse

In recent years, single element two-dimensional atom crystal materials have aroused extensive interest in many applications. Blue phosphorus, successfully synthesized on Au substrate by molecular beam epitaxy not long ago, shows unusual…

Materials Science · Physics 2018-10-16 Yipeng An , Songqiang Sun , Mengjun Zhang , Jutao Jiao , Dapeng Wu , Tianxing Wang , Kun Wang

Discovery of atomically thin black phosphorus (called phosphorene) holds promise to be used as an alternative two-dimensional material to graphene and transition metal dichalcogenides especially as an anode material for lithium-ion…

The atomic structure, stacking sequences and electronic structure of folded graphene nanoribbons (FGNRs) are investigated by first-principles calculations. It reveals that the common configurations of all FGNRs are racket-like structures…

Mesoscale and Nanoscale Physics · Physics 2016-01-20 Wenjin Yin , Yuee Xie , Li-Min Liu , Yuanping Chen , Ru-Zhi Wang , Xiao-Lin Wei , Leo Lau