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Chirality is a fundamental feature in all domains of nature, ranging from particle physics over electromagnetism to chemistry and biology. Chiral objects lack a mirror plane and inversion symmetry and therefore cannot be spatially aligned…

We study nonlinear response of a dimer composed of two identical Mie-resonant dielectric nanoparticles illuminated normally by a circularly polarized light. We develop a general theory describing hybridization of multipolar modes of the…

Resonant X-ray diffraction (RXD) provides a unique capability to investigate electronically ordered states in matter. Importantly, circular dichroism in RXD can determine the absolute chirality formed by anisotropic multipole arrangement.…

Strongly Correlated Electrons · Physics 2025-03-18 Hiroki Ueda , Yves Joly , Urs Staub

As characteristic lengths in plasmonics rapidly approach the sub-nm regime, quantum-informed models that can capture those aspects of the quantum nature of the electron gas that are not accessible by the standard approximations of classical…

Mesoscale and Nanoscale Physics · Physics 2018-12-20 Christos Tserkezis , A. T. Mina Yeşilyurt , Jer-Shing Huang , N. Asger Mortensen

The interaction of radiation with chiral molecular films is not macroscopically invariant under mirror reflections and, accordingly, chiroptical effects exist which affect the spatial symmetry of the radiation profile and which nearly…

Optics · Physics 2021-10-05 Alessandro Ciattoni

The second order optical response of centrosymmetric materials manifests itself mostly at their surface, being strongly suppressed in their bulk. However, the overall surface response is also suppressed in nanoparticles with a…

Optics · Physics 2021-09-22 Raksha Singla , W. Luis Mochán

In this work, we study second-harmonic generation a monocrystalline nanoparticle with a non-centrosymmetric crystalline lattice. It was shown that breaking the symmetry of the nanoparticle's shape can significantly affect the second…

Optics · Physics 2019-04-25 Kristina Frizyuk

Large optical chirality in the vicinity of achiral high index dielectric nanostructures has been recently demonstrated as useful means of enhancing molecular circular dichroism. We theoretically study the spatial dependence of optical…

Optics · Physics 2022-05-25 Krzysztof M. Czajkowski , Tomasz J. Antosiewicz

The near-field interaction of plasmonic nanostructures and chiral molecules induces circular dichroism in achiral nanostructure. The induced circular dichroism (ICD) strength is several orders greater than the molecular inherent CD (MCD),…

While plasmonic particles can provide optical resonances in a wide spectral range from the lower visible up to the near-infrared, often symmetry effects are utilized to obtain particular optical responses. By breaking certain spatial…

We consider high energy electron scattering by hydrogen atoms in the presence of a laser field of moderate power and higher frequencies. If the field is a superposition of a linearly and a circularly polarized laser beam in a particular…

Atomic Physics · Physics 2013-03-07 Aurelia Cionga , Fritz Ehlotzky , Gabriela Zloh

Circular dichroism is a technologically important phenomenon contrasting the absorption and resultant emission properties between left- and right-handed circularly polarized light. While the chiral handedness of systems mainly determines…

Optics · Physics 2023-03-21 Xiuhu Zhao , Jinxing Li , Mingjun Huang , Satoshi Aya

We demonstrate that an effect phenomenologically analogous to circular dichroism can arise even for dielectric and isotropic chiral spherical particles. By analyzing the polarimetry of light scattered from a chiral, lossless microsphere…

We present a rigorous finite element method to calculate circular dichroism (CD) in various systems consisting of nanostructures and oriented chiral molecules with electric quadrupole transitions. The interaction between oriented molecule…

Optics · Physics 2017-12-27 Weixuan Zhang , Tong Wu , Rongyao Wang , Xiangdong Zhang

Metasurfaces, the two-dimensional analogues of metamaterials, are ideal platforms for sensing molecular chirality at the nanoscale, e.g. of inclusions of natural optically active molecules, as they offer large accessible areas (they are…

Applied Physics · Physics 2020-08-19 Sotiris Droulias

Chirality is an intriguing property of certain molecules, materials or artificial nanostructures, which allows them to interact with the spin angular momentum of the impinging light field. Due to their chiral geometry, they can distinguish…

Optics · Physics 2016-11-03 Peter Banzer , Pawel Wozniak , Uwe Mick , Israel De Leon , Robert W. Boyd

Structured x-rays carrying an orbital angular momentum break spatial inversion symmetry and have been proposed as a means to probe chirality. We theoretically investigate twisted non-resonant x-ray diffraction from chiral molecules and…

Optics · Physics 2026-03-02 Akilesh Venkatesh , Phay J. Ho , Jérémy R. Rouxel

Optical activity is a fundamental phenomenon originating from the chiral nature of crystals and molecules. While intrinsic chiroptical responses of ordinary chiral materials to circularly polarized light are relatively weak, they can be…

Circular dichroism is widely used for characterizing organic and biological materials, but measurements at a single molecule level are challenging because differences in absorption for opposite helicities are small. Here we show that…

Mesoscale and Nanoscale Physics · Physics 2014-01-23 A. Yokoyama , M. Yoshida , A. Ishii , Y. K. Kato

We experimentally investigate the chiral optical response of an individual nanostructure consisting of three equally sized spherical nanoparticles made of different materials and arranged in \ang{90} bent geometry. Placing the nanostructure…

Optics · Physics 2019-07-30 Sergey Nechayev , René Barczyk , Uwe Mick , Peter Banzer