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Layered LiMO2 (M = Ni, Co, Mn, and Al mixture) cathode materials used for Li-ion batteries are reputed to be highly reactive through their surface, where the chemistry changes rapidly when exposed to ambient air. However, conventional…

Cathodes are critical components of rechargeable batteries. Conventionally, the search for cathode materials relies on experimental trial-and-error and a traversing of existing computational/experimental databases. While these methods have…

Chemical Physics · Physics 2021-05-19 Ziheng Lu , Bonan Zhu , Benjamin W. B. Shires , David O. Scanlon , Chris J. Pickard

Silicon (Si) anodes attract a lot of research attention for their potential to enable high energy density lithium-ion batteries (LIBs). Many studies focus on nanostructured Si anodes to counteract deterioration. In this work, we model LIBs…

Chemical Physics · Physics 2024-04-23 Franziska Kilchert , Max Schammer , Arnulf Latz , Birger Horstmann

In order to achieve a better understanding of degradation processes in lithium-ion batteries, the modelling of cell dynamics at the mircometer scale is an important focus of current mathematical research. These models lead to…

Numerical Analysis · Mathematics 2018-03-09 Mario Ohlberger , Stephan Rave , Sebastian Schmidt , Shiquan Zhang

Battery aging is a natural process that contributes to capacity and power fade, resulting in a gradual performance degradation over time and usage. State of Charge (SOC) and State of Health (SOH) monitoring of an aging battery poses a…

Systems and Control · Electrical Eng. & Systems 2021-06-25 Anirudh Allam , Simona Onori

Among the 'beyond Li-ion' battery chemistries, nonaqueous Li-O$_2$ batteries have the highest theoretical specific energy and as a result have attracted significant research attention over the past decade. A critical scientific challenge…

Lithium-ion batteries (LIBs) are becoming an important energy storage solution to achieve carbon neutrality, but it remains challenging to characterise their internal states for the assurance of performance, durability and safety. This work…

Classical Physics · Physics 2023-04-27 Ming Huang , Niall Kirkaldy , Yan Zhao , Yatish Patel , Frederic Cegla , Bo Lan

Electrochemistry exploits local current heterogeneities at various scales ranging from the micrometer to the nanometer. The last decade has witnessed unprecedented progress in the development of a wide range of electroanalytical techniques…

Optics · Physics 2022-11-16 Frederic Kanoufi

Effective management and just-in-time maintenance of lithium-ion batteries require the knowledge of unmeasured (internal) variables that need to be estimated. Observers are thus designed for this purpose using a mathematical model of the…

Systems and Control · Electrical Eng. & Systems 2023-04-20 E. Petri , T. Reynaudo , R. Postoyan , D. Astolfi , D. Nesic , S. Rael

The development of high-energy density solid-state batteries is critical for the achievement of carbon neutrality goals and the advancement of clean energy. Still, the fundamental understanding of lithium transport mechanisms and…

Electrochemical impedance spectra for battery electrodes are usually interpreted using models that assume isotropic active particles, having uniform current density and symmetric diffusivities. While this can be reasonable for amorphous or…

Chemical Physics · Physics 2013-09-24 J. Song , M. Z. Bazant

Lithium titanium oxide Li$_4$Ti$_5$O$_{12}$ (LTO) is an intriguing anode material promising particularly long lived batteries, due to its remarkable phase stability during (dis)charging of the cell. However, its usage is limited by its low…

Materials Science · Physics 2020-01-03 Matthias Kick , Cristina Grosu , Markus Schuderer , Christoph Scheurer , Harald Oberhofer

Power storage devices such as batteries are a crucial part of modern technology. The development and use of batteries has accelerated in the past decades, yet there are only a few techniques that allow gathering vital information from…

This article reviews the development of cathode materials for secondary lithium ion batteries since its inception with the introduction of lithium cobalt oxide in early 1980s. The time has passed and numerous cathode materials are designed…

Materials Science · Physics 2021-09-07 Ambesh Dixit

The operation efficiency of the electric transportation, energy storage, and grids mainly depends on the fundamental characteristics of the employed batteries. Fundamental variables like voltage, current, temperature, and estimated…

Systems and Control · Electrical Eng. & Systems 2024-11-11 Anupama R Itagi , Rakhee Kallimani , Krishna Pai , Sridhar Iyer , Onel L. A. López , Sushant Mutagekar

We present a coupled continuum formulation for the electrostatic, chemical, thermal and mechanical processes in battery materials. Our treatment applies on the macroscopic scale, at which electrodes can be modelled as porous materials made…

Chemical Physics · Physics 2017-07-25 Zhenlin Wang , Jason B. Siegel , Krishna Garikipati

Solid-state electrolytes have the potential to stabilize lithium metal anodes, which hold the promise to increase the energy density of lithium-ion batteries. However, lithium metal dendrites that occur locally at the solid-solid interface…

Materials Science · Physics 2025-05-09 Rajeev Gopal , Peng Bai

Lithium-ion batteries (LIBs) have found wide applications in a variety of fields such as electrified transportation, stationary storage and portable electronics devices. A battery management system (BMS) is critical to ensure the…

Systems and Control · Electrical Eng. & Systems 2024-02-02 Yiming Xu , Xiaohua Ge , Ruohan Guo , Weixiang Shen

Electrode manufacturing is at the core of the lithium ion battery (LIB) fabrication process. The electrode microstructure and the electrochemical performance are determined by the adopted manufacturing parameters. However, in view of the…

Chemical Physics · Physics 2022-06-14 Chaoyue Liu , Teo Lombardo , Jiahui Xu , Alain C. Ngandjong , Alejandro A. Franco

In the quest for better energy storage solutions, the role of designing effective electrodes is crucial. Previous research has shown that using materials like single-side fluorinated graphene can improve the stability of ion insertion in…

Materials Science · Physics 2024-08-28 Yu-Hsiu Lin , Jose L. Mendoza-Cortes