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If the second law of thermodynamics forbids a transition from one state to another, then it is still possible to make the transition happen by using a sufficient amount of work. But if we do not have access to this amount of work, can the…

Quantum Physics · Physics 2016-11-02 Álvaro M. Alhambra , Jonathan Oppenheim , Christopher Perry

Entropy in thermodynamics is an extensive quantity, whereas standard methods in statistical mechanics give rise to a non-extensive expression for the entropy. This discrepancy is often seen as a sign that basic formulas of statistical…

History and Philosophy of Physics · Physics 2012-09-06 Dennis Dieks

The basic notions of statistical mechanics (microstates, multiplicities) are quite simple, but understanding how the second law arises from these ideas requires working with cumbersomely large numbers. To avoid getting bogged down in…

Physics Education · Physics 2015-02-27 Thomas A. Moore , Daniel V. Schroeder

Thermodynamics is commonly presented as a theory of macroscopic systems in stable equilibrium, built upon assumptions of extensivity and scaling with system size. In this paper, we present a universal formulation of the elementary…

Quantum Physics · Physics 2026-03-26 Gian Paolo Beretta

The field of quantum resource theory (QRT) has emerged as an invaluable framework for the examination of small and strongly correlated quantum systems, surpassing the boundaries imposed by traditional statistical treatments. The fundamental…

Quantum Physics · Physics 2023-08-29 Gökhan Torun , Onur Pusuluk , Özgür E. Müstecaplıoğlu

Understanding the rich spatial and temporal structures in nonequilibrium thermal environments is a major subject of statistical mechanics. Because universal laws, based on an ensemble of systems, are mute on an individual system, exploring…

Statistical Mechanics · Physics 2019-04-19 Liyi Zhao , Ping Fang , Chushun Tian

A recently proposed quantum mechanical criterion `concavity of energy' for the second law of thermodynamics is studied also for classical particle systems confined in a bounded region by a potential with a time-dependent coupling constant.…

Statistical Mechanics · Physics 2020-12-22 C. Itoi , M. Amano

Quantum thermodynamics investigates how robust the second law of thermodynamics serves as the unique fundamental law in the small quantum world. To tackle this problem, the quantum coherence constitutes a major difficulty of investigations,…

Quantum Physics · Physics 2025-10-08 Naoto Shiraishi , Ryuji Takagi

Entropy production is the crucial quantity characterizing irreversible phenomena and the second law of thermodynamics. Yet, a ubiquitous definition eludes consensus. Given that entropy production arises from incomplete access to…

Quantum Physics · Physics 2024-08-26 Adalberto D. Varizi , Pedro S. Correia

We show that the natural scaling of measurement for a particular problem defines the most likely probability distribution of observations taken from that measurement scale. Our approach extends the method of maximum entropy to use…

Quantitative Methods · Quantitative Biology 2010-03-02 Steven A. Frank , D. Eric Smith

The irreversibility in a statistical system is traced to its probabilistic evolution, and the molecular chaos assumption is not its unique consequence as is commonly believed. Under the assumption that the rate of change of the each…

Statistical Mechanics · Physics 2008-03-10 P. D. Gujrati

The zeroth law of turbulence states that, for fixed energy input into large-scale motions, the statistical steady state of a turbulent system is independent of microphysical dissipation properties. The behavior, which is fundamental to…

Space Physics · Physics 2021-06-16 Romain Meyrand , Jonathan Squire , Alexander A. Schekochihin , William Dorland

We establish an analytical criterion for dynamical thermalization within harmonic systems, applicable to both classical and quantum models. Specifically, we prove that thermalization of various observables, such as particle energies in…

Statistical Mechanics · Physics 2025-07-29 Marco Cattaneo , Marco Baldovin , Dario Lucente , Paolo Muratore-Ginanneschi , Angelo Vulpiani

The eigenstate thermalization hypothesis provides a framework for understanding thermalization in isolated quantum many-body systems by characterizing statistical properties of local observables in energy eigenstates. Here we demonstrate…

Statistical Mechanics · Physics 2026-05-11 Pavel Orlov , Rustem Sharipov , Enej Ilievski

The generalized second laws of quantum thermodynamics are usually formulated in terms of R\'enyi divergences and the associated family of generalized free energies. In catalytic thermal transformations, this framework typically certifies…

Quantum Physics · Physics 2026-04-24 Ali Can Günhan , Onur Pusuluk , Thomas Oikonomou , G. Baris Bagci

The superposition principle lies at the heart of many non-classical properties of quantum mechanics. Motivated by this, we introduce a rigorous resource theory framework for the quantification of superposition of a finite number of linear…

Quantum Physics · Physics 2017-12-19 T. Theurer , N. Killoran , D. Egloff , M. B. Plenio

Recent literature in the last Maximum Entropy workshop introduced an analogy between cumulative probability distributions and normalized utility functions. Based on this analogy, a utility density function can de defined as the derivative…

Artificial Intelligence · Computer Science 2009-11-10 Ali E. Abbas

As performance gains through scaling data and/or model size experience diminishing returns, it is becoming increasingly popular to turn to ensembling, where the predictions of multiple models are combined to improve accuracy. In this paper,…

Machine Learning · Statistics 2024-11-04 Hyunsuk Kim , Liam Hodgkinson , Ryan Theisen , Michael W. Mahoney

We propose a new form of the Second Law inequality that defines a tight bound for extractable work from the non-equilibrium quantum state. In classical thermodynamics, the optimal work is given by the difference of free energy, what…

Quantum Physics · Physics 2023-02-14 Marcin Łobejko

The fluctuation theorem is a pivotal result of statistical physics. It quantifies the probability of observing fluctuations which are in violation of the second law of thermodynamics. More specifically, it quantifies the ratio of the…

Statistical Mechanics · Physics 2011-08-26 M. Belushkin , R. Livi , G. Foffi
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