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The unusually large hyperfine structure splittings in the 23P state of the 3He isotope is measured using electro-optic techniques with high precision laser spectroscopy. Originally designed to probe the fine structure of the 4He atom, this…

Atomic Physics · Physics 2012-03-14 Marc Smiciklas

Application of visible or infrared (IR) lasers for spectroscopy of highly-charged ions (HCI) has not been particularly extensive so far due to a mismatch in typical energies. We show here that the energy difference between the two lowest…

Atomic Physics · Physics 2018-03-14 Yuri Ralchenko

Optical atomic clocks using highly-charged ions hold an intriguing promise of metrology at the 19th significant figure. Here we study transitions within the $4f^{12}$ ground-state electronic configuration of highly charged ions. We consider…

Atomic Physics · Physics 2015-06-11 V. A. Dzuba , A. Derevianko , V. V. Flambaum

We perform high resolution spectroscopy on $^{176}$Lu$^+$ including the $^1S_0\leftrightarrow{^3}D_1$ and $^1S_0\leftrightarrow{^3}D_2$ clock transitions. Hyperfine structures and optical frequencies relative to the $^1S_0$ ground state of…

Atomic Physics · Physics 2019-01-09 R. Kaewuam , A. Roy , T. R. Tan , K. J. Arnold , M. D. Barrett

Optical atomic clocks are the most accurate measurement devices ever constructed and have found many applications in fundamental science and technology. The use of highly charged ions (HCI) as a new class of references for highest accuracy…

Mendeleev's periodic table successfully groups atomic elements according to their chemical and spectroscopic properties. However, it becomes less sufficient in describing the electronic properties of highly charged ions (HCIs) in which many…

Atomic Physics · Physics 2026-01-05 Chunhai Lyu , Christoph H. Keitel , Zoltán Harman

Compared to other stable isotopes of $\rm{Yb}^+$, $^{173}\rm{Yb}^+$ has a richer hyperfine structure, which leads to more favorable clock transitions, spectroscopic techniques for probing new physics, and more sophisticated quantum…

The hyperfine structure of $^{229}$Th$^{3+}$ ions in the nuclear ground state is investigated via laser spectroscopy of trapped Th$^{3+}$ ions that are sympathetically cooled by laser-cooled $^{88}$Sr$^+$ ions in a linear Paul trap. The…

Atomic Physics · Physics 2025-04-02 G. Zitzer , J. Tiedau , Ch. E. Düllmann , M. V. Okhapkin , E. Peik

We have realized a high-resolution time-of-flight mass spectrometer combined with a magneto-optical trap. The spectrometer enables excellent optical access to the trapped atomic cloud using specifically devised acceleration and deflection…

Molecular hydrogen ions are of metrological relevance due to the possibility of precise theoretical evaluation of their spectrum and of external-field-induced shifts. In homonuclear molecular ions the electric dipole $E1$ transitions are…

Atomic Physics · Physics 2021-01-20 P. Danev , D. Bakalov , V. I. Korobov , S. Schiller

Highly charged ions (HCIs) combine compact electronic structure with strong relativistic effects, offering both robustness against external perturbations and enhanced sensitivity to variations of the fine-structure constant. Recent advances…

Atomic Physics · Physics 2026-02-17 S. G. Porsev , M. S. Safronova

Unique spectroscopic possibilities open up if a laser beam interacts with relativistic lithium-like ions stored in the heavy ion ring accelerator SIS300 at the future Facility for Antiproton and Ion Research FAIR in Darmstadt, Germany. At a…

Atomic Physics · Physics 2015-06-26 H. Backe

This study analyzed the optical techniques for high resolution, low-noise spectroscopy of a hyperfine structure (HFS) made of ytterbium-isotope 171 ions ($^{171}\mathrm{Yb}^{3+}$:$\mathrm{Y}_2\mathrm{SiO}_5$). Large energy spacings in…

Optics · Physics 2024-08-21 Hee-Jin Lim , Ga-Hyun Choi , Ki Suk Hong

State-of-the-art optical clocks achieve fractional precisions of $10^{-18}$ and below using ensembles of atoms in optical lattices or individual ions in radio-frequency traps. Promising candidates for novel clocks are highly charged ions…

We use the phenomenon of electromagnetically-induced transparency in a three-level atomic system for hyperfine spectroscopy of upper states that are not directly coupled to the ground state. The three levels form a ladder system: the probe…

Optics · Physics 2007-05-23 Anusha Krishna , Kanhaiya Pandey , Ajay Wasan , Vasant Natarajan

Plasma impedance probes (PIPs) are a type of RF probe that primarily measure electron density. This work introduces two advancements: a streamlined analytical model for interpreting PIP-monopole measurements and techniques for achieving…

Plasma Physics · Physics 2023-07-27 John W. Brooks , Erik M. Tejero , Matthew C. Paliwoda , Michael S. McDonald

Recent experimental progress in cooling, trapping, and quantum logic spectroscopy of highly-charged ions (HCIs) made HCIs accessible for high resolution spectroscopy and precision fundamental studies. Based on these achievements, we explore…

We propose a novel class of atomic clocks based on highly charged ions. We consider highly-forbidden laser-accessible transitions within the $4f^{12}$ ground-state configurations of highly charged ions. Our evaluation of systematic effects…

Atomic Physics · Physics 2016-10-05 Andrei Derevianko , V. A. Dzuba , V. V. Flambaum

We report on magneto-optical trapping of the two fermionic isotopes of atomic titanium, $^{47}$Ti and $^{49}$Ti. Unlike the even mass-number isotopes, which were recently laser cooled, $^{47}$Ti and $^{49}$Ti have nonzero nuclear spins and,…

Measuring the hyperfine structure (HFS) of long-lived $^3P_2$ states of divalent atoms may offer the opportunity of extracting relatively unexplored nuclear magnetic octupole and electric hexadecapole moments. Here, using relativistic…

Atomic Physics · Physics 2009-11-13 K. Beloy , A. Derevianko , W. R. Johnson