Related papers: Rubisco function, evolution, and engineering
The carbon-silicate cycle regulates the atmospheric $CO_2$ content of terrestrial planets on geological timescales through a balance between the rates of $CO_2$ volcanic outgassing and planetary intake from rock weathering. It is thought to…
The cosmic origin of carbon, a fundamental building block of life, is still uncertain. Yield predictions for massive stars are almost exclusively based on single star models, even though a large fraction interact with a binary companion.…
The use of pressure to obtain new materials that can be recovered under ambient conditions is a central problem in high-pressure physics. Despite decades of research, this goal has only been achieved in the laboratory for a few notable…
Pools of carbon dioxide are found in natural geological accumulations and in engineered storage in saline aquifers. It has been thought that once this CO2 dissolves in the formation water, making it denser, convection streams will transport…
Carbon dioxide, CO2, capture by room-temperature ionic liquids (RTILs) is a vivid research area featuring both accomplishments and frustrations. This work employs the PM7-MD method to simulate adsorption of CO2 by 1,3-dimethylimidazolium…
Frustrated Lewis pairs (FLPs) are known for its ability to capture CO2. Although many FLPs have been reported experimentally and several theoretical studies have been carried out to address the reaction mechanism, the individual roles of…
Folding of ribozymes into well-defined tertiary structures usually requires divalent cations. How Mg$^{2+}$ ions direct the folding kinetics has been a long-standing unsolved problem because experiments cannot detect the positions and…
Dissolution of CO$_2$ in water followed by the subsequent hydrolysis reactions is of great importance to the global carbon cycle, and carbon capture and storage. Despite enormous previous studies, the reactions are still not fully…
We report new computational and experimental evidence of an efficient and astrochemically relevant formation route to formaldehyde (H$_2$CO). This simplest carbonylic compound is central to the formation of complex organics in cold…
Different hypotheses have been proposed to explain the mechanism for the extremely low friction coefficient of carbon coatings and its undesired dependence on air humidity. A decisive atomistic insight is still lacking because of the…
Understanding the climate dynamics at the inner edge of the habitable zone (HZ) is crucial for predicting the habitability of rocky exoplanets. Previous studies using Global Climate Models (GCMs) have indicated that planets receiving high…
The density-driven convection coupled with chemical reaction is the preferred mechanism for permanently storing CO2 in saline aquifers. This study uses a 2D visual Hele-Shaw cell to evaluate and visualize the density-driven convection…
An intriguing problem in climate science is the existence of Earth's glacial cycles. We show that it is possible to generate these periodic changes in climate by means of the Earth's carbon cycle as the main determinant factor. The carbon…
Global warming is seen as a drastic environmental problem nowadays. Carbon dioxide (CO 2 ) concentration in the Earth's atmosphere is linked to the average temperature on the surface of the planet. Carbon capture and storage is an important…
Among the major factors controlling the cerebral blood flow (CBF), the effect of PaCO2 is peculiar in that it violates autoregulatory CBF mechanisms and allows to explore the full range of the CBF. This research resulted in a simple…
Catalysis, the acceleration of product formation by a substance that is left unchanged, typically results from multiple elementary processes, including diffusion of the reactants toward the catalyst, chemical steps, and release of the…
Routinely navigating through an ever-changing and unsteady environment, and utilizing chemical energy, molecular motors transport the cell's crucial components, such as neurotransmitters and organelles. They generate force and pull cargo,…
Our planet is roughly closed to matter, but open to energy input from the sun. However, to harness this energy, organisms must transform matter from one chemical (redox) state to another. For example, photosynthetic organisms can capture…
The C--to--O ratio is a crucial determinant of the chemical properties of planets. The recent observation of WASP 12b, a giant planet with a C/O value larger than that estimated for its host star, poses a conundrum for understanding the…
Carbon-dioxide (CO2) is the main contributor to anthropogenic global warming, and the timing of its peak concentration in the atmosphere is likely to govern the timing of maximum radiative forcing. It is well-known that dynamics of…