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We prove the second law of thermodynamics and the nonequilibirum fluctuation theorem for pure quantum states.The entire system obeys reversible unitary dynamics, where the initial state of the heat bath is not the canonical distribution but…

Statistical Mechanics · Physics 2017-09-13 Eiki Iyoda , Kazuya Kaneko , Takahiro Sagawa

We study the internal dynamics of an elementary quantum system placed close to a body held at a temperature different from that of the surrounding radiation. We derive general expressions for lifetime and density matrix valid for bodies of…

Quantum Physics · Physics 2015-03-20 Bruno Bellomo , Riccardo Messina , Mauro Antezza

We discuss the possibility of defining an emergent local temperature in extended quantum many-body systems evolving out of equilibrium. For the most simple case of free-fermionic systems, we give an explicit formula for the effective…

Statistical Mechanics · Physics 2023-03-06 M. Coppola , D. Karevski

Open quantum systems are studied from the thermodynamical point of view unifying the principle of maximum informational entropy and the hypothesis of relaxation times hierarchy. The result of the unification is a non-Markovian and local in…

Quantum Physics · Physics 2014-11-24 Vitalii Semin , Francesco Petruccione

The laws of thermodynamics provide a clear concept of the temperature for an equilibrium system in the continuum limit. Meanwhile, the equipartition theorem allows one to make a connection between the ensemble average of the kinetic energy…

Statistical Mechanics · Physics 2009-11-13 Alex V. Popov , Rigoberto Hernandez

Recent experimental advances in ultrafast phenomena have triggered renewed interest in the dynamics of correlated quantum systems away from equilibrium. We review nonequilibrium dynamical mean-field theory studies of both the transient and…

Strongly Correlated Electrons · Physics 2020-05-25 Herbert F. Fotso , James K. Freericks

Starting at the mesoscopic level with a general formulation of stochastic thermodynamics in terms of Markov jump processes, we identify the scaling conditions that ensure the emergence of a (typically nonlinear) deterministic dynamics and…

Statistical Mechanics · Physics 2025-05-26 Gianmaria Falasco , Massimiliano Esposito

We give a proof of transient fluctuation relations for the entropy production (dissipation function) in nonequilibrium systems, which is valid for most time reversible dynamics. We then consider the conditions under which a transient…

Statistical Mechanics · Physics 2009-11-13 Debra J. Searles , Lamberto Rondoni , Denis J. Evans

We derive a condition for the realizability of heat released in nondeterministic processes from a fluctuation theorem, showing that this condition is strictly stronger than the probabilistic form of the second law of thermodynamics. With…

Statistical Mechanics · Physics 2024-09-26 Jihai Zhu

For students familiar with equilibrium statistical mechanics, the notion of a positive specific heat, being intimately related to the idea of stability, is both intuitively reasonable and mathematically provable. However, for system in…

Statistical Mechanics · Physics 2009-11-07 R. K. P. Zia , E. L. Praestgaard , O. G. Mouritsen

This paper proposes a simple mathematical model of non-stationary and non-linear stochastic dynamics, which approximates a (globally) non-stationary and non-linear stochastic process by its locally (or \emph{"piecewise"}) stationary…

In this paper we develop a generalized formalism for equilibrium thermodynamic systems when an information is shared between the system and the reservoir. The information results in a correction to the entropy of the system. This extension…

Statistical Mechanics · Physics 2013-05-10 Alessio Gagliardi , Aldo Di Carlo

It is sometimes argued that the unattainability of zero temperature is a consequence of the second law of thermodynamics. Historically, the independence of the unattainability of zero temperature from the second law was proven more than 80…

Statistical Mechanics · Physics 2018-04-06 Koun Shirai

The irreversible entropy increase described by the second law of thermodynamics is fundamentally tied to thermalization and the emergence of equilibrium. In the first part of our work (Ref: arXiv.2503.04152), we constructed an isolated gas…

Quantum Physics · Physics 2025-11-24 Xue-Yi Guo

We consider heat exchange processes between non-equilibrium aging systems (in their activated regime) and the thermal bath in contact. We discuss a scenario where two different heat exchange processes concur in the overall heat dissipation:…

Soft Condensed Matter · Physics 2009-11-10 A. Crisanti , F Ritort

We suggest a generalisation of the expression of the nonequilibrium density matrix obtained by Hershfield's method for the cases where both heat and charge steady state currents are present in a quantum open system. The finite-size quantum…

Mesoscale and Nanoscale Physics · Physics 2014-12-15 H. Ness

Optimality principles in nonequilibrium transport networks are linked to a thermodynamic formalism based on generalized transport potentials endowed with Legendre duality and related contact structure. This allows quantifying the distance…

Statistical Mechanics · Physics 2025-06-23 Amilcare Porporato , Shashank Kumar Anand , Salvatore Calabrese , Luca Ridolfi , Lamberto Rondoni

We propose a variational formulation for the nonequilibrium thermodynamics of discrete open systems, i.e., discrete systems which can exchange mass and heat with the exterior. Our approach is based on a general variational formulation for…

Mathematical Physics · Physics 2018-12-05 François Gay-Balmaz , Hiroaki Yoshimura

We give a decomposition expression for dissipative heat using the instantaneous diffusion coefficient in a nonequilibrium steady state. The dissipative heat can be expressed using three diffusion coefficients: instantaneous, equilibrium,…

Statistical Mechanics · Physics 2014-12-09 Soya Shinkai

The quantum thermodynamic behavior of small systems is investigated in presence of finite quantum dissipation. We consider the archetype cases of a damped harmonic oscillator and a free quantum Brownian particle. A main finding is that…

Quantum Physics · Physics 2007-05-23 Peter Hänggi , Gert-Ludwig Ingold