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Progress in ultracold experiments with polar molecules requires a clear understanding of their interactions and reactivity at ultra-low collisional energies. Two important theoretical steps in this process are the characterization of…

Atomic Physics · Physics 2015-05-18 Svetlana Kotochigova

We present the first experimental observation of cold collisions between two different species of neutral polar molecules, each prepared in a single internal quantum state. Combining for the first time the techniques of Stark deceleration,…

Mixed quantum/classical theory (MQCT) for the treatment of rotationally inelastic transitions during collisions of two identical molecules, described either as indistinguishable or distinguishable partners, is reviewed. The treatment of two…

Chemical Physics · Physics 2025-11-21 Dulat Bostan , Bikramaditya Mandal , Dmitri Babikov

We propose a one-channel, simple model to describe the dynamics of ultracold dipolar molecules around a F\"orster resonance. Slightly above a specific electric field, a collisional shielding can take place, suppressing the molecular losses…

Quantum Gases · Physics 2024-06-21 Lucas Lassablière , Goulven Quéméner

Low-energy two-dimensional scattering is particularly sensitive to the existence and properties of weakly-bound states. We show that interaction potentials $V(r)$ with vanishing zero-momentum Born approximation $\int d^2r V(r)=0$ lead to an…

Quantum Gases · Physics 2010-10-22 Michael Klawunn , Alexander Pikovski , Luis Santos

The experimental characterization of scattering resonances in low energy collisions has proven to be a stringent test for quantum chemistry calculations. Previous measurements on the NO-H$_2$ system at energies down to $10$ cm$^{-1}$…

We study ionization dynamics of aligned diatomic molecules N$_2$ in strong elliptical laser fields experimentally and theoretically. The alignment dependence of photoelectron momentum distributions (PMDs) of N$_2$ measured in experiments is…

We propose an effective model to describe the $A_{2g}$ signal in Raman scattering experiments in the URu$_{2}$Si$_{2}$ compound. We follow the scheme proposed earlier by Khveshchenko and Wiegmann [Phys. Rev. Lett. 73, 500 (1994)] to…

Strongly Correlated Electrons · Physics 2020-05-20 Carlene Silva de Farias , Marie-Aude Méasson , Alvaro Ferraz , Sébastien Burdin

We present a method for calculation of Raman modes of the quantum solid phase I solid hydrogen and deuterium. We use the mean-field assumption that the quantised excitations are localized on one molecule. This is done by explicit solution…

Quantum scattering calculations for strongly interacting molecular systems are computationally demanding due to the large number of molecular states coupled by the anisotropy of atom - molecule interactions. We demonstrate that thermal rate…

Chemical Physics · Physics 2026-01-06 Xuyang Guo , Kirk W. Madison , James L. Booth , Roman V. Krems

Scattering resonances due to the dipole-dipole interaction between ultracold molecules, induced by static or microwave fields, are studied theoretically. We develop a method for coupled-channel calculations that can efficiently impose many…

Quantum Gases · Physics 2023-07-11 Tijs Karman

We carry out quantum inelastic scattering calculations of collisions of Rb atoms with inverting NH3 and ND3 molecules in the energy range between 0 and 100 cm-1, which are important for experiments using velocity-controlled molecular beams…

Chemical Physics · Physics 2013-05-29 Piotr S. Żuchowski , Jeremy M. Hutson

In this work we report ab initio calculations for the $H_2^+$ molecule interacting with ultrashort intense laser pulses. We analyse several observables that can, in principle, be available experimentally, in order to get a deeper…

Atomic Physics · Physics 2017-05-25 R. E. F. Silva

Collision phenomena are ubiquitous and of importance in determining the microscopic structures and intermolecular interactions of atoms and molecules. The existing approaches are mostly based on atomic or molecular scatterings, which are…

Quantum Physics · Physics 2022-03-01 Shiming Song , Min Jiang , Yushu Qin , Yu Tong , Wenzhe Zhang , Xi Qin , Ren-Bao Liu , Xinhua Peng

Compared to purely atomic collisions, ultracold molecular collisions potentially support a much larger number of Fano-Feshbach resonances due to the enormous number of ro-vibrational states available. In fact, for alkali-metal dimers we…

Atomic Physics · Physics 2012-10-19 Michael Mayle , Goulven Quéméner , Brandon P. Ruzic , John L. Bohn

A theoretical model of resonant hyper-Raman scattering by an ensemble of spherical semiconductor quantum dots has been developed. The electronic intermediate states are described as Wannier-Mott excitons in the framework of the envelope…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 E. Menendez-Proupin , C. Trallero-Giner , A. Garcia-Cristobal

xploiting quantum interference remains a significant challenge in ultracold inelastic scattering. In this work, we propose a method to enable detectable quantum interference within the two-body loss rate resulting from various inelastic…

Quantum Gases · Physics 2024-12-03 Ting Xie , Chuan-Cun Shu

In the past, light-assisted cold collisions between laser cooled atoms have been widely studied in magneto-optical atom traps (MOTs). We describe here theoretical studies of dynamical interactions, specifically cold collisions, between…

Atomic Physics · Physics 2009-11-10 J. Piilo , K. -A. Suominen

When circularly polarized light is scattered from a rotating target, a rotational Doppler shift (RDS) emerges from an exchange of angular momentum between the spinning object and the electromagnetic field. Here, we used coherently spinning…

The molecular anion C$_2^-$ has been of interest in the last few years as a candidate for laser cooling due to its electronic structure and favourable branching ratios to the ground electronic and vibrational state. Molecular hydrogen has…