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Amorphous grain boundary complexions act as toughening features within a microstructure because they can absorb dislocations more efficiently than traditional grain boundaries. This toughening effect should be a strong function of the local…

Materials Science · Physics 2023-08-09 Pulkit Garg , Timothy J. Rupert

Amorphous materials lack long-range order but short-range order can still persist through the recurrence of similar local packing motifs. While the short-range order in bulk amorphous phases has been well studied and identified as an…

Materials Science · Physics 2017-02-15 Zhiliang Pan , Timothy J. Rupert

Amorphous interfacial complexions have been shown to restrict grain growth and improve damage tolerance in nanocrystalline alloys, with increased chemical complexity stabilizing the complexions themselves. Here, we investigate local…

Materials Science · Physics 2026-03-05 Esther C. Hessong , Zhengyu Zhang , Tianjiao Lei , Mingjie Xu , Toshihiro Aoki , Timothy J. Rupert

Amorphous grain boundary complexions have been shown to increase the plasticity of nanocrystalline alloys as compared to ordered grain boundaries. Here, the effect of an important structural descriptor, amorphous complexion thickness, on…

Amorphous grain-boundary (GB) complexions in thermally stable nanocrystalline alloys are commonly assumed to be structurally homogeneous, yet their disordered nature makes them susceptible to local short-range ordering (SRO). The influence…

Materials Science · Physics 2026-05-27 Frederic Sansoz , Eve-Audrey Picard

Grain boundaries have extensive influence on the performance of crystal materials. However, the atomic-scale structure and its relation with local and crystallographic symmetries remain elusive in low-symmetry crystals. Herein, we find that…

Materials Science · Physics 2024-09-24 Yuchao Yan , Yingying Liu , Ziyi Wang , Da Liu , Xu Gao , Yan Wang , Cheng Li , KeKe Ma , Ning Xia , Zhu Jin , Tianqi Deng , Hui Zhang , Deren Yang

Segregation-induced structural transitions in metallic grain boundaries are studied with hybrid atomistic Monte Carlo/molecular dynamics simulations using Cu-Zr as a model system, with a specific emphasis on understanding the effect of…

Materials Science · Physics 2016-04-27 Zhiliang Pan , Timothy J. Rupert

Interfacial segregation can stabilize grain structures and even lead to grain boundary complexion transitions. However, understanding of the complexity of such phenomena in polycrystalline materials is limited, as most studies focus on…

Materials Science · Physics 2021-07-02 P Garg , Z Pan , V Turlo , TJ Rupert

Many physical systems are composed of polyhedral cells of varying sizes and shapes. These structures are simple in the sense that no more than three faces meet at an edge and no more than four edges meet at a vertex. This means that…

Materials Science · Physics 2022-01-13 Frank H. Lutz , Jeremy K. Mason , Emanuel A. Lazar , Robert D. MacPherson

We study numerically and analytically the coarsening of stripe phases in two spatial dimensions, and show that transient configurations do not achieve long ranged orientational order but rather evolve into glassy configurations with very…

Statistical Mechanics · Physics 2009-11-07 Denis Boyer , Jorge Viñals

Complex concentrated alloys with intrinsic chemical heterogeneity are promising candidates for nuclear applications, where local chemical order can strongly influence defect evolution under irradiation. Grain boundaries also contribute to…

Materials Science · Physics 2026-03-20 Ian Geiger , Penghui Cao , Timothy J. Rupert

Grain boundary-based mechanisms are known to control the plastic deformation and failure of nanocrystalline metals, with manipulation of the boundary structure a promising path for tuning this response. In this study, the role of…

Materials Science · Physics 2021-05-26 Jenna L. Wardini , Charlette M. Grigorian , Timothy J. Rupert

Impurities in crystalline materials introduce disorder into an otherwise ordered structure due to the formation of lattice defects and grain boundaries. The properties of the resulting polycrystal can differ remarkably from those of the…

Soft Condensed Matter · Physics 2015-05-20 Andrew T. Gray , Elizabeth Mould , C. Patrick Royall , Ian Williams

Amorphous complexions have recently been demonstrated to simultaneously enhance the ductility and stability of certain nanocrystalline alloys. In this study, three quinary alloys (Cu-Zr-Hf-Mo-Nb, Cu-Zr-Hf-Nb-Ti, and Cu-Zr-Hf-Mo-W) are…

Materials Science · Physics 2022-02-02 Charlette M. Grigorian , Timothy J. Rupert

Grain boundaries (GBs) and interfaces in polycrystalline materials are significant research subjects in the field of materials science. Despite a more than 50-year history of their study, there are still many open questions. The main…

Materials Science · Physics 2021-06-28 Arslan B. Mazitov , Artem R. Oganov

In polycrystalline materials, grain boundaries are sites of enhanced atomic motion, but the complexity of the atomic structures within a grain boundary network makes it difficult to link the structure and atomic dynamics. Here we use a…

Complexions are phase-like interfacial features that can influence a wide variety of properties, but the ability to predict which material systems can sustain these features remains limited. Amorphous complexions are of particular interest…

Materials Science · Physics 2017-08-22 Jennifer D. Schuler , Timothy J. Rupert

Grain boundaries, the two-dimensional (2D) defects between differently oriented crystals, control mechanical and transport properties of materials. Our fundamental understanding of grain boundaries is still incomplete even after nearly a…

A simple analytical model of intergranular normal stresses is proposed for a general elastic polycrystalline material with arbitrary shaped and randomly oriented grains under uniform loading. The model provides algebraic expressions for the…

Materials Science · Physics 2023-04-21 Samir El Shawish , Timon Mede

The macroscopic behavior of polycrystalline materials is influenced by the local variation of properties caused by the presence of impurities and defects. The effect of these impurities at the atomic scale can either embrittle or strengthen…

Materials Science · Physics 2014-01-23 M. Rajagopalan , M. A. Tschopp , K. N. Solanki
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