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Fluctuation theorems have elevated the second law of thermodynamics to a statistical realm by establishing a connection between time-forward and time-reversal probabilities, providing invaluable insight into nonequilibrium dynamics. While…

Quantum Physics · Physics 2025-06-05 Hui Li , Jie Xie , Hyukjoon Kwon , Yixin Zhao , M. S. Kim , Lijian Zhang

We generalize the thermal pure quantum (TPQ) formulation of statistical mechanics, in such a way that it is applicable to systems whose Hilbert space is infinite dimensional. Assuming particle systems, we construct the grand-canonical TPQ…

Statistical Mechanics · Physics 2014-10-02 Masahiko Hyuga , Sho Sugiura , Kazumitsu Sakai , Akira Shimizu

We study the speed of fluctuation of a quantum system around its thermodynamic equilibrium state, and show that the speed will be extremely small for almost all times in typical thermodynamic cases. The setting considered here is that of a…

Quantum Physics · Physics 2017-08-01 Noah Linden , Sandu Popescu , Anthony J Short , Andreas Winter

The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy…

Soft Condensed Matter · Physics 2009-10-30 Elliott H. Lieb , Jakob Yngvason

When the strength of interaction between a quantum system and bath is non-negligible, the equilibrium state can deviate from the Gibbs state. But the expression of such a mean force Gibbs state in an arbitrary parameter regime is unknown…

Quantum Physics · Physics 2025-08-27 Prem Kumar

Preparing ground states and thermal states is essential for simulating quantum systems on quantum computers. Despite the hope for practical quantum advantage in quantum simulation, popular state preparation approaches have been challenged.…

Certain fluctuations in particle number at fixed total energy lead exactly to a cut-power law distribution in the one-particle energy, via the induced fluctuations in the phase-space volume ratio. The temperature parameter is expressed…

Statistical Mechanics · Physics 2014-12-10 Tamas Sandor Biro , Peter Van , Gergely Gabor Barnafoldi , Karoly Urmossy

We re-interprete the microcanonical conditions in the quantum domain as constraints for the interaction of the "gas-subsystem" under consideration and its environment ("container"). The time-average of a purity-measure is found to equal the…

Quantum Physics · Physics 2009-11-07 Jochen Gemmer , Alexander Otte , Guenter Mahler

We rigorously analyze the non-equilibrium thermodynamic behavior of various formulations of quantum Brownian motion (QBM) using the framework of stochastic thermodynamics. While the widely used Caldeira-Leggett master equation exhibits…

Quantum Physics · Physics 2026-04-06 Simone Artini , Gabriele Lo Monaco , Alberto Imparato , Mauro Paternostro , Sandro Donadi

The thermodynamic and kinetic uncertainty relations indicate trade-offs between the relative fluctuation of observables and thermodynamic quantities such as dissipation and dynamical activity. Although these relations have been well studied…

Statistical Mechanics · Physics 2022-04-12 Tan Van Vu , Keiji Saito

We present a consistent thermodynamic theory for the resonant level model in the wide band limit, whose level energy is driven slowly by an external force. The problem of defining 'system' and 'bath' in the strong coupling regime is…

Mesoscale and Nanoscale Physics · Physics 2017-05-05 Anton Bruch , Mark Thomas , Silvia Viola Kusminskiy , Felix von Oppen , Abraham Nitzan

We initially prepare a quantum linear oscillator weakly coupled to a bath in equilibrium at an arbitrary temperature. We disturb this system by varying a Hamiltonian parameter of the coupled oscillator, namely, either its spring constant or…

Statistical Mechanics · Physics 2015-05-27 Ilki Kim

The evolution of a driven quantum system is said to be adiabatic whenever the state of the system stays close to an instantaneous eigenstate of its time-dependent Hamiltonian. The celebrated quantum adiabatic theorem ensures that such pure…

Quantum Physics · Physics 2021-10-04 Nikolai Il`in , Anastasia Aristova , Oleg Lychkovskiy

For a small driven system coupled strongly to a heat bath, internal energy and exchanged heat are identified such that they obey the usual additive form of the first law. By identifying this exchanged heat with the entropy change of the…

Statistical Mechanics · Physics 2016-02-03 Udo Seifert

The second law of ordinary thermodynamics and the second law of steady state thermodynamics, as proposed by Oono and Paniconi, are investigated from the microscopic point of view for the open quantum system. Based on the H-theorem of…

Statistical Mechanics · Physics 2007-05-23 Satoshi Yukawa

Master equations are a vital tool to model heat flow through nanoscale thermodynamic systems. Most practical devices are made up of interacting sub-system, and are often modelled using either local master equations (LMEs) or global master…

Quantum Physics · Physics 2021-05-05 Stefano Scali , Janet Anders , Luis A. Correa

The second law of thermodynamics states that the entropy of an isolated system can only increase over time. This appears to conflict with the reversible evolution of isolated quantum systems under the Schr\"odinger equation, which preserves…

Quantum Physics · Physics 2025-01-16 Florian Meier , Tom Rivlin , Tiago Debarba , Jake Xuereb , Marcus Huber , Maximilian P. E. Lock

A quantum master equation (QME) is derived for the many-body density matrix of an open current-carrying system weakly coupled to two metal leads. The dynamics and the steady-state properties of the system for arbitrary bias are studied…

Statistical Mechanics · Physics 2016-08-31 Upendra Harbola , Massimiliano Esposito , Shaul Mukamel

The urgent need for reliable simulation tools to match the extreme accuracy needed to control tailored quantum devices highlights the importance of understanding open quantum systems and their modeling. To this end, we compare here the…

A perturbative quantum master equation is derived for a system interacting with its environment, which is more general than the ones derived before. Our master equation takes into account the effect of the energy exchanges between the…

Statistical Mechanics · Physics 2009-11-10 M. Esposito , P. Gaspard
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