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We investigate quantum thermal state preparation algorithms based on system-bath interactions and uncover a surprising phenomenon in the weak-coupling regime. We rigorously prove that, if the system-bath interaction is engineered so that…

Quantum Physics · Physics 2026-05-18 Hongrui Chen , Zhiyan Ding , Ruizhe Zhang

The fluctuation dissipation theorem~(FDT) is a hallmark of thermal equilibrium systems in the Gibbs state. We address the question whether the FDT is obeyed by isolated quantum systems in an energy eigenstate. In the framework of the…

Statistical Mechanics · Physics 2020-08-05 Jae Dong Noh , Takahiro Sagawa , Joonhyun Yeo

Quantum thermalization describes how closed quantum systems can effectively reach thermal equilibrium, resolving the apparent incongruity between the reversibility of Schr\"odinger's equation and the second law of thermodynamics. Despite…

Quantum Physics · Physics 2026-01-08 Saúl Pilatowsky-Cameo , Soonwon Choi

We study the notion of work fluctuations in quantum field theory, highlighting that the most common definitions used in finite-dimensional quantum systems cannot be applied to quantum field theory (QFT). Then we propose work distributions…

Quantum Physics · Physics 2020-11-20 Adam Teixidó-Bonfill , Alvaro Ortega , Eduardo Martín-Martínez

This work brings together Keldysh non-equilibrium quantum theory and thermodynamics, by showing that a real-time diagrammatic technique is an equivalent of stochastic thermodynamics for non-Markovian quantum machines (heat engines,…

Mesoscale and Nanoscale Physics · Physics 2021-03-16 Robert S. Whitney

The principle of microscopic reversibility lies at the core of fluctuation theorems, which have extended our understanding of the second law of thermodynamics to the statistical level. In the quantum regime, however, this elementary…

Noncommutativity of observables is a central feature of quantum physics. It plays a fundamental role in the formulation of the uncertainty principle for complementary variables and strongly affects the laws of thermodynamics for systems…

Quantum Physics · Physics 2025-10-07 Franklin L. S. Rodrigues , Eric Lutz

A fundamental principle of chaotic quantum dynamics is that local subsystems eventually approach a thermal equilibrium state. Large subsystems thermalize slower: their approach to equilibrium is limited by the hydrodynamic build-up of…

We show how statistical thermodynamics can be formulated in situations in which thermodynamics applies, while equilibrium statistical mechanics does not. A typical case is, in the words of Landau and Lifshitz, that of partial (or…

Statistical Mechanics · Physics 2013-04-16 A. Carati , A. Maiocchi , L. Galgani

Based on quantum statistical mechanics and microscopic quantum dynamics, we prove Planck's and Kelvin's principles for macroscopic systems in a general and realistic setting. We consider a hybrid quantum system that consists of the…

Statistical Mechanics · Physics 2016-05-04 Hal Tasaki

Recently, there has been a considerable progress on the issue of the thermodynamic second law, which is known as the law of entropy increase or irreversibility. In particular, a novel symmetry known as the Gallavotti-Cohen symmetry is found…

Statistical Mechanics · Physics 2018-08-01 Hyunggyu Park

We describe a method to obtain the reduced density matrix (RDM) correct up to second order in system-bath coupling in \emph{nonequilibrium} steady state situations. The RDM is obtained via a scheme based on analytic continuation, using the…

Statistical Mechanics · Physics 2013-11-22 Juzar Thingna , Jian-Sheng Wang , Peter Hänggi

We present the Born-Markov approximated Redfield quantum master equation (RQME) description for an open system of non-interacting particles (bosons or fermions) on an arbitrary lattice of $N$ sites in any dimension and weakly connected to…

Statistical Mechanics · Physics 2016-06-16 Archak Purkayastha , Abhishek Dhar , Manas Kulkarni

We study the quantum fluctuation theorem in the one-time measurement (OTM) scheme, where the work distribution of the backward process has been lacking and which is considered to be more informative than the two-time measurement (TTM)…

Quantum Physics · Physics 2023-11-20 Kenji Maeda , Tharon Holdsworth , Sebastian Deffner , Akira Sone

The thermodynamic uncertainty relation (TUR) imposes a fundamental constraint between current fluctuations and entropy production, providing a refined formulation of the second law for micro- and nanoscale systems. Quantum violations of the…

Quantum Physics · Physics 2026-01-28 Yang Li , Fu-Lin Zhang

The circumstances under which a system reaches thermal equilibrium, and how to derive this from basic dynamical laws, has been a major question from the very beginning of thermodynamics and statistical mechanics. Despite considerable…

Quantum Physics · Physics 2017-08-01 Noah Linden , Sandu Popescu , Anthony J. Short , Andreas Winter

In the framework of theory of open quantum systems, we derive quantum master equations for the ultrastrong system-bath coupling regime and, more generally, the strong-decoherence regime. In this regime, the strong decoherence is…

Quantum Physics · Physics 2021-09-07 Anton Trushechkin

We examine a biomolecular machine involving a driven, observable process coupled to a hidden process in a kinetically cooperative manner. A stochastic thermodynamics framework is employed to analyze a fluctuation theorem for the…

Statistical Mechanics · Physics 2025-11-14 D. Evan Piephoff , Jianshu Cao

We consider a single harmonic oscillator coupled to a bath at zero temperature. As is well known, the oscillator then has a higher average energy than that given by its ground state. Here we show analytically that for a damping model with…

Quantum Physics · Physics 2009-11-13 ILki Kim , Guenter Mahler

Physical devices operating out of equilibrium are inherently affected by thermal fluctuations, limiting their operational precision. This issue is pronounced at microscopic and especially quantum scales and can only be mitigated by…