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In quantum thermodynamics, the decomposition of energy exchanges into heat and work remains an open problem beyond weak-coupling and slow-driving regimes. Recent formulations have shown that quantum coherence introduces additional energy…

Quantum Physics · Physics 2026-05-20 Mario Reis , Maron F. Anka , Vinicius Gomes de Paula , Clebson Cruz

We establish quantum thermodynamics for open quantum systems weakly coupled to their reservoirs when the system exhibits degeneracies. The first and second law of thermodynamics are derived, as well as a finite-time fluctuation theorem for…

Statistical Mechanics · Physics 2017-03-08 Gregory Bulnes Cuetara , Massimiliano Esposito , Gernot Schaller

The separation of internal energy into heat and work in quantum thermodynamics is a controversial issue for a long time, and we revisit and solve this problem in this work. It is shown that the Hamiltonian plays dual roles for a quantum…

Quantum Physics · Physics 2025-01-03 Tao Zhou , Jiangyang Pu , Xiaohua Wu

Quantum thermodynamics supplies a consistent description of quantum heat engines and refrigerators up to the level of a single few level system coupled to the environment. Once the environment is split into three;a hot, cold and work…

Quantum Physics · Physics 2015-04-17 Ronnie Kosloff , Amikam Levy

Thermodynamics has recently been extended to small scales with resource theories that model heat exchanges. Real physical systems exchange diverse quantities: heat, particles, angular momentum, etc. We generalize thermodynamic resource…

Quantum Physics · Physics 2016-03-02 Nicole Yunger Halpern , Joseph M. Renes

The second law of thermodynamics prohibits spontaneous heat from a cold to a hot body. However, it has been theoretically and experimentally shown that energy can flow from a cold to a hot body if the bodies are initially correlated. We…

Quantum Physics · Physics 2022-12-06 Tharon Holdsworth , Ryoichi Kawai

Master equation could be applied to model various kinds of biochemical systems. A general theory for its time-dependent nonequilibrium thermodynamics is rigorously derived. We not only introduce a concept of general internal energy, but…

Statistical Mechanics · Physics 2009-04-16 Hao Ge

Interactions between a quantum system and its environment at low temperatures can lead to violations of thermal laws for the system. The source of these violations is the entanglement between system and environment, which prevents the…

Other Condensed Matter · Physics 2015-05-20 Nathan S. Williams , Karyn Le Hur , Andrew N. Jordan

Several prior attempts to formulate the Laws of Thermodynamics for a small region within a larger quantum system have led to inconsistencies and unexplained infinities. The entropy and external work, in particular, require careful analysis…

Quantum Physics · Physics 2025-06-26 Parth Kumar , Charles A. Stafford

We examine the relationship between the second law of thermodynamics and the energy eigenstates of quantum many-body systems that undergo cyclic unitary evolution. Using a numerically optimized control protocol, we analyze how the work…

Quantum Physics · Physics 2023-08-08 Shotaro Z. Baba , Nobuyuki Yoshioka , Takahiro Sagawa

I give a self-contained introduction to the resource theory approach to quantum thermodynamics. I will introduce in an elementary manner the technical machinery necessary to unpack and prove the core statements of the theory. The topics…

Quantum Physics · Physics 2019-10-24 Matteo Lostaglio

Environments in quantum thermodynamics usually take the role of heat baths. These baths are Markovian, weakly coupled to the system, and initialized in a thermal state. Whenever one of these properties is missing, standard quantum…

Quantum Physics · Physics 2024-08-02 Alessandra Colla , Heinz-Peter Breuer

The interplay between quantum-mechanical properties, such as coherence, and classical notions, such as energy, is a subtle topic at the forefront of quantum thermodynamics. The traditional Carnot argument limits the conversion of heat to…

Quantum Physics · Physics 2016-02-23 Kamil Korzekwa , Matteo Lostaglio , Jonathan Oppenheim , David Jennings

Thermodynamics plays an important role both in the foundations of physics and in technological applications. An operational perspective adopted in recent years is to formulate it as a quantum resource theory. At the core of this theory is…

Quantum Physics · Physics 2023-12-13 Thomas Theurer , Elia Zanoni , Carlo Maria Scandolo , Gilad Gour

The second law of thermodynamics dictates that heat flows spontaneously from a high-temperature entity to a lower-temperature one. Yet, recent advances have demonstrated that quantum correlations between a system and its thermal environment…

Thermodynamics at the nanoscale is known to differ significantly from its familiar macroscopic counterpart: the possibility of state transitions is not determined by free energy alone, but by an infinite family of free-energy-like…

Quantum Physics · Physics 2018-12-21 Markus P. Mueller

In this paper, unambiguous redefinitions of heat and work are presented for quantum thermodynamic systems. We will use genuine reasoning based on which Clausius originally defined work and heat in establishing thermodynamics. The change in…

Quantum Physics · Physics 2023-03-15 B. Ahmadi , S. Salimi , A. S. Khorashad

The emergence of irreversibility in physical processes, despite the fundamentally reversible nature of quantum mechanics, remains an open question in physics. This thesis explores the intricate relationship between quantum mechanics and…

Quantum Physics · Physics 2024-10-25 Alberto Rolandi

There exist two formulations for quantum heat engine that models an energy transfer between two microscopic systems. One is semi-classical scenario, and the other is full quantum scenario. The former is formulated as a unitary evolution for…

Quantum Physics · Physics 2017-04-05 Masahito Hayashi , Hiroyasu Tajima

One of the fundamental questions in the emerging field of quantum thermodynamics is the role played by coherence in energetic processes that occur at the quantum level. Here, we address this issue by investigating two different quantum…

Quantum Physics · Physics 2021-01-04 Bertúlio de Lima Bernardo