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We present a general computational protocol for the evaluation of extensive molecular response properties in complex environments within a polarizable quantum embedding framework. The approach extends multilevel density functional theory…

Chemical Physics · Physics 2026-02-11 Alberto Barlini , Julien Bloino , Henrik Koch , Tommaso Giovannini

We introduce a hybrid classical-quantum algorithm to compute dynamical correlation functions and excitation spectra in many-body quantum systems, with a focus on molecular systems. The method combines classical preparation of a perturbed…

Quantum Physics · Physics 2025-10-30 Alessandro Santini , Stefano Barison , Filippo Vicentini

Double-quantum two-dimensional coherent spectroscopy (MDCS) is a powerful optical method that is used to study optical properties of atomic and complex molecular systems and semiconductor materials. Double-quantum 2D spectra and…

Optics · Physics 2020-10-21 Bachana Lomsadze , Steven T. Cundiff

Open quantum systems are ubiquitous in nature and central to quantum technologies. A common description of their dynamics is given by the celebrated Lindblad master equation, which can be generalized to the non-Markovian scenario. In this…

Quantum Physics · Physics 2025-01-15 Miralem Sinanović , Alessandro Ciani , Shai Machnes , Frank K. Wilhelm

We present ultra-fast quantum chemical methods for the calculation of infrared and ultraviolet-visible spectra designed to provide fingerprint information during autonomous and interactive explorations of molecular structures.…

Chemical Physics · Physics 2022-08-30 Francesco Bosia , Thomas Weymuth , Markus Reiher

Generalized master equations valid for the third order response of an optically driven multi-level electronic system are derived within Zwanzig projection formalism. Each of three time intervals of the response function is found to require…

Quantum Physics · Physics 2012-01-30 Tomas Mancal , Frantisek Sanda

Neural network quantum state (NNQS) has emerged as a promising candidate for quantum many-body problems, but its practical applications are often hindered by the high cost of sampling and local energy calculation. We develop a…

Quantum Physics · Physics 2023-11-02 Yangjun Wu , Chu Guo , Yi Fan , Pengyu Zhou , Honghui Shang

We present a numerical method to simulate a system of multiple emitters coupled to a non-interacting bath, in any parameter regime. Our method relies on a Block Lanczos transformation that maps the whole system onto a strip geometry, whose…

Quantum Physics · Physics 2025-08-25 Irene Papaefstathiou , Daniel Malz , J. Ignacio Cirac , Mari Carmen Bañuls

Radiation reaction has been investigated traditionally in classical dynamics and recently in non-linear QED for high-intensity field physics by high-intensity lasers. The non-linearity of QED is predicted as the coupling between a highly…

Mathematical Physics · Physics 2017-08-25 Keita Seto

Reaction diffusion systems describe the behaviour of dynamic, interacting, particulate systems. Quantum stochastic processes generalise Brownian motion and Poisson processes, having operator valued It\^{o} calculus machinery. Here it is…

Mathematical Physics · Physics 2023-05-31 Chris D Greenman

We derive a general expression for the electron nonequilibrium (NE) distribution function in the context of steady state quantum transport through a two-terminal nanodevice with interaction. The central idea for the use of NE distributions…

Mesoscale and Nanoscale Physics · Physics 2014-02-26 H. Ness

Mixed-quantum-classical molecular dynamics simulation implies an effective measurement on the electronic states owing to continuously tracking the atomic forces.Based on this insight, we propose a quantum trajectory mean-field approach for…

Chemical Physics · Physics 2014-08-08 Wei Feng , Luting Xu , Xin-Qi Li , Weihai Fang , YiJing Yan

Accurately predicting response properties of molecules such as the dynamic polarizability and hyperpolarizability using quantum mechanics has been a long-standing challenge with widespread applications in material and drug design. Classical…

Chemical Physics · Physics 2020-09-01 Xiaoxia Cai , Wei-Hai Fang , Heng Fan , Zhendong Li

We study the nonequilibrium properties of an electronic circuit composed of a double quantum dot (DQD) channel coupled to a quantum point contact (QPC) within the framework of stochastic thermodynamics. We show that the transition rates…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 Gregory Bulnes Cuetara , Massimiliano Esposito

Applications of quantum simulation algorithms to obtain electronic energies of molecules on noisy intermediate-scale quantum (NISQ) devices require careful consideration of resources describing the complex electron correlation effects. In…

Quantum Physics · Physics 2020-04-17 Mekena Metcalf , Nicholas P. Bauman , Karol Kowalski , Wibe A. de Jong

We present $\vec{k}$-dependent one-particle spectra and corresponding effective bandstructures for the $2d$ Hubbard model calculated within the dynamical molecular field theory (DMFT). This method has proven to yield highly nontrivial…

Condensed Matter · Physics 2016-08-31 Th. Pruschke , Th. Obermeier , J. Keller , M. Jarrell

The algebraic reformulation of molecular Quantum Electrodynamics (mQED) at finite temperatures is applied to Nuclear Magnetic Resonance (NMR) in order to provide a foundation for the reconstruction of much more detailed molecular…

Quantum Physics · Physics 2020-09-25 Kolja Them

Using a real-time path integral approach we develop an algorithm to calculate multi-time correlation functions of open few-level quantum systems that is applicable to highly nonequilibrium dynamics. The calculational scheme fully keeps the…

Mesoscale and Nanoscale Physics · Physics 2018-09-12 Michael Cosacchi , Moritz Cygorek , Florian Ungar , Andreas M. Barth , Alexei Vagov , Vollrath Martin Axt

By means of quantum stochastic calculus we construct a model for an atom with two degenerate levels and stimulated by a laser and we compute its fluorescence spectrum; let us stress that, once the model for the unitary atom-field dynamics…

Quantum Physics · Physics 2009-11-07 Alberto Barchielli , Nicola Pero

We introduce an extended formulation of the non-Markovian stochastic Schr\"odinger equation with complex frequency modes (extended cNMSSE), designed for simulating open quantum system dynamics under arbitrary spectral densities. This…

Quantum Physics · Physics 2025-09-10 Yukai Guo , Zeyu Huang , Xing Gao