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We investigated the origin of the identical polarization angle dependences between surface-enhanced resonant Raman scattering (SERRS) and plasmon resonance for two types of single silver nanoparticle aggregates. The first type (Type I), in…

Optics · Physics 2023-05-30 Tamitake Itoh , Yuko S. Yamamoto

The review is devoted to explanation of SERS in terms of the dipole and quadrupole light-molecule interactions arising in surface fields strongly varying in space in the region of the strongly irregular surface roughness. The main SERS…

Chemical Physics · Physics 2013-10-01 A. M. Polubotko

We present a general model study of surface-enhanced resonant Raman scattering and fluorescence, focusing on the interplay between electromagnetic (EM) effects and the molecular dynamics as treated by a density matrix calculation. The model…

Other Condensed Matter · Physics 2007-05-23 Peter Johansson , Hongxing Xu , Mikael Käll , ;

Surface enhanced Raman scattering (SERS) process results in a tremendous increase of Raman scattering cross section of molecules adsorbed to plasmonic metals and influenced by numerous physico-chemical factors such as geometry and optical…

Chemical Physics · Physics 2021-02-23 Shimon Rubin , Phuong H. L. Nguyen , Yeshaiahu Fainman

We have investigated the effects of tuning the localized surface plasmon resonances (LSPRs) of silver nanoparticles on the fluorescence intensity, lifetime, and Raman signal from nearby fluorophores. The presence of a metallic structure can…

Other Condensed Matter · Physics 2009-11-13 N. I. Cade , T. Ritman-Meer , D. Richards

We present a microscopic model for surface-enhanced Raman scattering (SERS) from molecules adsorbed on small noble-metal nanoparticles. In the absence of direct overlap of molecular orbitals and electronic states in the metal, the main…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Vitaliy N. Pustovit , Tigran V. Shahbazyan

The long-range action of surface-enhanced Raman scattering (SERS) is probed via distance-dependent measurements of molecular Raman spectra. To this end, identical SERS substrates composed of irregular silver nanoisland arrays were covered…

Materials Science · Physics 2015-06-12 V. I. Kukushkin , A. B. Van'kov , I. V. Kukushkin

We explored the surface enhanced Raman scattering (SERS) activity of the InN nanostructures, possessing surface electron accumulation (SEA), using the Rhodamine 6G (R6G) molecules. SERS enhancement is observed for the InN nanostructures…

Materials Science · Physics 2018-08-14 Kishore K. Madapu , Sandip Dhara

The Dipole-Quadrupole theory of Surface Enhanced Hyper Raman Scattering (SEHRS), created by the authors is expounded in details. Peculiarities of the behavior of electromagnetic field on rough metal surfaces are considered. It is…

Optics · Physics 2014-11-17 V. P. Chelibanov , A. M. Polubotko

Electromagnetic (EM) coupling between molecular exciton and plasmon has been studied using in Rayleigh scattering or extinction spectroscopy. However, evaluating EM coupling involving subradiant plasmon is challenging because this resonance…

Optics · Physics 2026-05-15 Tamitake Itoh , Yuko S. Yamamoto

This study examines the Raman scattering and charge transfer properties of molecules adsorbed on the surface of a tetrahedral Au$_{120}$ nanoparticle based on the time-dependent density functional tight-binding (TD-DFTB) method. We study…

Chemical Physics · Physics 2024-09-18 Sajal Kumar Giri , George C. Schatz

Surface enhanced Raman scattering mediated by surface plasmons polaritons with wave vector much larger than those of light is considered. The excitation of these polaritons and their efficient Raman scattering due to low group velocity and…

Optics · Physics 2015-06-04 Tomas Lopez-Rios

We investigate the propagation of surface-enhanced resonant Raman scattering (SERRS) light by several micrometers through a one-dimensional hotspot (1D HS) located between a plasmonic nanowire dimer (NWD). The propagation exhibits the…

Optics · Physics 2021-06-23 Tamitake Itoh , Yuko S. Yamamoto , Jeyadevan Balachandran

Low-frequency Raman scattering experiments have been performed on thin films consisting of nickel-silver composite nanoparticles embedded in alumina matrix. It is observed that the Raman scattering by the quadrupolar modes, strongly…

Condensed Matter · Physics 2007-05-23 H. Portales , L. Saviot , E. Duval , M. Gaudry , E. Cottancin , M. Pellarin , J. Lerme , M. Broyer

We investigate theoretically the optical properties associated to plasmon resonances of metal nanowires with cross section given by low-order Chebyshev nanoparticles (like rounded-tip nanostars or nanoflowers). The impact of the nanoflower…

Optics · Physics 2009-10-23 V. Giannini , R. Rodriguez-Oliveros , J. A. Sanchez-Gil

We report that rhomb-shaped metal nanoantenna arrays support multiple plasmonic resonances, making them favorable bio-sensing substrates. Besides the two localized plasmonic dipole modes associated with the two principle axes of the rhombi,…

We discuss the effect of the local field polarization in metallic nanostructures where large field enhancements can be induced by excitation of localized surface plasmons. To demonstrate the importance of these effects, we study a few model…

Chemical Physics · Physics 2007-05-23 E. C. Le Ru , P. G. Etchegoin

The dependence of surface-enhanced Raman scattering (SERS) spectra on the precise axial position of the laser focus relative to a solid nanostructured substrate has received little to no attention in the literature. Here we show this…

Optics · Physics 2026-03-31 Fran Nekvapil , Cosmin Farcău

We investigate the far-field optical resonances of individual dimer nanoantennas using confocal scattering spectroscopy. Experiments on a single-antenna array with varying arm lengths and interparticle gap sizes show large spectral shifts…

Materials Science · Physics 2009-11-11 O. L. Muskens , J. Gomez Rivas , V. Giannini , J. A. Sanchez-Gil

The surface-enhanced Raman scattering in graphene deposited on AlxGa1-xN/GaN axial heterostructure nanowires was investigated. The intensity of graphene Raman spectra was found not to be correlated with aluminium content. Analysis of…

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