Related papers: Water UV-shielding in the terrestrial planet-formi…
Mid-infrared spectroscopy is one of the few ways to observe the composition of the terrestial planet forming zone, the inner few au, of proto-planetary disks. The species currently detected in the disk atmosphere, for example CO, CO2, H2O…
The chemical composition of the inner region of protoplanetary disks can trace the composition of planetary building material. The exact elemental composition of the inner disk has not yet been measured and tensions between models and…
An understanding of the abundance and distribution of water vapor in the innermost region of protoplanetary disks is key to understanding the origin of habitable worlds and planetary systems. Past observations have shown H2O to be abundant…
Radiative cooling by molecules is a crucial process for hydrodynamic escape, as it can efficiently remove the thermal energy driving the outflow, acquired through X-ray and extreme UV absorption. Carbon oxides, such as CO and CO2, and their…
Water photolysis and hydrogen loss from the upper atmospheres of terrestrial planets is of fundamental importance to climate evolution but remains poorly understood in general. Here we present a range of calculations we performed to study…
Carbon dioxide is one of the major contributors to the radiative forcing, increasing both the temperature and the humidity of Earth's atmosphere. If the stellar irradiance increases and water becomes abundant in the stratosphere of an…
Terrestrial and sub-Neptune planets are expected to form in the inner ($<10~$AU) regions of protoplanetary disks. Water plays a key role in their formation, although it is yet unclear whether water molecules are formed in-situ or…
Carbon dioxide (CO2) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO2 is an indicator of the metal enrichment (i.e., elements heavier than helium, also called…
JWST has shown that CO2 and CO are common on the surfaces of objects in the Kuiper belt and have apparent surface coverages even higher than that of water ice, though water ice is expected to be significantly more abundant in the bulk…
In the conventional habitable zone (HZ) concept, a CO$_{2}$-H$_2$O greenhouse maintains surface liquid water. Through the water-mediated carbonate-silicate weathering cycle, atmospheric CO$_{2}$ partial pressure (pCO$_{2}$) responds to…
Carbon Dioxide (CO2) is one of the most important greenhouse gases after water vapor (H2O) which plays significant role in the climate process. Accurate space-based measurement of CO2 is of great significance in inferring the location of…
We present the first Spitzer Infrared Spectrograph observations of the 15.2 micron bending mode of CO2 ice towards field stars behind a quiescent dark cloud. CO2 ice is detected towards 2 field stars (Elias 16, Elias 3) and a single…
We present a computational study into the adsorption properties of CO$_2$ on amorphous and crystalline water surfaces under astrophysically relevant conditions. Water and carbon dioxide are two of the most dominant species in the icy…
The UV environment is a key boundary condition for the origin of life. However, considerable uncertainty exists as to planetary conditions and hence surface UV at abiogenesis. Here, we present two-stream multi-layer clear-sky calculations…
[Abridged] The infrared ro-vibrational emission lines from organic molecules in the inner regions of protoplanetary disks are unique probes of the physical and chemical structure of planet forming regions and the processes that shape them.…
We investigate the chemical stability of CO2-dominated atmospheres of desiccated M dwarf terrestrial exoplanets using a 1-dimensional photochemical model. Around Sun-like stars, CO2 photolysis by Far-UV (FUV) radiation is balanced by…
We present an integrated thermal-chemical model for the atmosphere of the inner region of a protoplanetary disk that includes irradiation by both far ultraviolet (FUV) and X-ray radiation. We focus on how the photodissociation of water and…
Carbon dioxide (CO2), an important trace species that is gradually increasing in the atmosphere due to anthropogenic activities, causes enhanced warming in the lower atmosphere. The increased concentration of CO2 in the upper atmosphere…
Water photodissociation in the 114 - 144 nm UV range forms excited OH which emits at mid-infrared wavelengths via highly excited rotational lines. These lines have only been detected with Spitzer in several proto-planetary disks and shocks.…
Our interpretation of terrestrial exoplanet atmospheric spectra will always be limited by the accuracy of the data we use as input in our forward and retrieval models. Ultraviolet molecular absorption cross sections are one category of…