Related papers: Resolving Vibrations in a Polyatomic Molecule with…
The hydrogen molecule has become a test ground for quantum electrodynamical calculations in molecules. Expanding beyond studies on stable hydrogenic species to the heavier radioactive tritium-bearing molecules, we report on a measurement of…
Precision sensing, and in particular high precision magnetometry, is a central goal of research into quantum technologies. For magnetometers, often trade-offs exist between sensitivity, spatial resolution, and frequency range. The…
Single molecule spectroscopy aims at unveiling often hidden but potentially very important contributions of single entities to a system's ensemble response. Albeit contributing tremendously to our ever growing understanding of molecular…
Nonstationary molecular states which contain electronic coherences can be impulsively created and manipulated by using recently-developed ultrashort optical and X-ray pulses via photoexcitation, photoionization and Auger processes. We…
X-ray as well as electron diffraction are powerful tools for structure determination of molecules. Studies on randomly oriented molecules in the gas-phase address cases in which molecular crystals cannot be generated or the interaction-free…
A high sensitivity atom flux sensor based on atomic absorption spectroscopy has been designed and implemented to control electron beam evaporators and effusion cells in a molecular beam epitaxy system. Using a high-resolution spectrometer…
Using a mid-infrared quantum cascade laser and wavelength modulation absorption spectroscopy, we measure the frequencies of ro-vibrational transitions of N$_2$O in the 17 $\mu$m region with uncertainties below 5 MHz. These lines,…
We present a formalism to study molecular polaritons based on the bosonization of molecular vibronic states. This formalism accommodates an arbitrary number of molecules $N$, excitations and internal vibronic structures, making it ideal for…
We show that light-pulse atom interferometry with atomic point sources and spatially resolved detection enables multi-axis (two rotation, one acceleration) precision inertial sensing at long interrogation times. Using this method, we…
We study beating of a probe field with a time-varying susceptibility in a coherently prepared Raman medium. We consider the general case of an arbitrary variation of susceptibility, which corresponds to a superposition of an arbitrary…
We present here an analysis of the sensitivity of a time-domain atomic interferometer to the phase noise of the lasers used to manipulate the atomic wave-packets. The sensitivity function is calculated in the case of a three pulse…
We present a new formulation of ab initio molecular dynamics which exploits the efficiency of plane waves in adaptive curvilinear coordinates, and thus provides an accurate treatment of first-row elements. The method is used to perform a…
The chaotic nature of x-ray free-electron-laser pulses is a major bottleneck that has limited the joint temporal and spectral resolution of spectroscopic measurements. We show how to use the stochastic x-ray field statistics to overcome…
We realize and model a Rydberg-state atom interferometer for measurement of phase and intensity of radio-frequency (RF) electromagnetic waves. A phase reference is supplied to the atoms via a modulated laser beam, enabling atomic…
Time-resolved near-infrared absorption spectroscopy of single non-repeatable transient events is performed at high spectral resolution with a dual-comb interferometer using a continuous-wave laser followed by a single electro-optic…
Bringing increasingly complex polyatomic molecules within reach of precision measurement experiments offers fascinating and far-reaching prospects ranging from Earth sciences and astrophysics, to metrology and quantum sciences. Here, we…
It is known that ultrasound techniques yield non-intrusive measurements of hydrodynamic flows. For example, the study of the echoes produced by a large number of particle insonified by pulsed wavetrains has led to a now standard velocimetry…
The short and intense pulses of the new X-ray free electron lasers, now operational or under construction, may make possible diffraction experiments on single molecule-sized objects with high resolution, before radiation damage destroys the…
In order to enable investigations of the fuel flow inside unmodified injectors, we have developed a new experimental approach to measure time-resolved vibration spectra of diesel nozzles using a three dimensional laser vibrometer. The…
Atomic force microscopy (AFM) routinely achieves structural information in the sub-nm length scale. Measuring time resolved properties on this length scale to understand kinetics at the nm scale remains an elusive goal. We present a general…