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We demonstrate the self-assembly of C$_{60}$ and pentacene (Pn) molecules into acceptor-donor heterostructures which are well-ordered and -- despite the high degree of symmetry of the constituent molecules -- {\it chiral}. Pn was deposited…

Mesoscale and Nanoscale Physics · Physics 2013-09-03 Joseph A. Smerdon , Rees B. Rankin , Jeffrey Greeley , Nathan Guisinger , Jeffrey Guest

The transfer of chirality across length-scales is an intriguing and universal natural phenomenon. However, connecting the properties of individual building blocks to the emergent features of their resulting large-scale structure remains a…

Quasicrystals are unique materials characterized by long-range order without periodicity. They are observed in systems such as metallic alloys, soft matter, and particle simulations. Unlike periodic crystals, which are invariant under…

Computational Physics · Physics 2024-11-14 Nydia Roxana Varela-Rosales , Michael Engel

Bio-conjugated nanomaterials play a promising role in the development of novel supramolecular structures, molecular machines, and biosensing devices. In this study, lipid-conjugated gold nanoparticles were synthesized and allowed to form a…

Materials Science · Physics 2012-07-24 Subhasish Chatterjee , Markrete Krikorian , Harry D. Gafney , Bonnie Gersten

Van der Waals heterostructures of atomically thin layers with rotational misalignments, such as twisted bilayer graphene, feature interesting structural moir\'e superlattices. Due to the quantum coupling between the twisted atomic layers,…

The controlled self-assembly of thiol stabilized gold nanocrystals in a mediating solvent and confined within mesoporous alumina was probed in situ with small angle x-ray scattering. The evolution of the self-assembly process was controlled…

Colloidal particles in polymer solutions and functionalized nanoparticles often exhibit short-range attraction coupled with long-range repulsion (SALR) leading to the spontaneous formation of symmetric patterns. Chiral nanostructures formed…

Soft Condensed Matter · Physics 2019-09-19 Jakub Pekalski , Eldar Bildanov , Alina Ciach

We show that chiral symmetry can be broken spontaneously in one-component systems with isotropic interactions, i.e. many-particle systems having maximal a priori symmetry. This is achieved by designing isotropic potentials that lead to…

Materials Science · Physics 2012-05-16 Erik Edlund , Oskar Lindgren , Martin Nilsson Jacobi

The self-assembly of binary nanoparticle superlattices from colloidal mixtures is a promising method for the fabrication of complex colloidal co-crystal structures. However, binary mixtures often form amorphous or metastable phases instead…

Soft Condensed Matter · Physics 2022-05-11 R. Allen LaCour , Timothy C. Moore , Sharon C. Glotzer

We experimentally investigate the chiral optical response of an individual nanostructure consisting of three equally sized spherical nanoparticles made of different materials and arranged in \ang{90} bent geometry. Placing the nanostructure…

Optics · Physics 2019-07-30 Sergey Nechayev , René Barczyk , Uwe Mick , Peter Banzer

The assembly of filamentous bundles with controlled diameters is common in biological systems and desirable for the development of nanomaterials. We discuss dynamical simulations and free energy calculations on patchy spheres with chiral…

Soft Condensed Matter · Physics 2015-05-18 Yasheng Yang , Robert B. Meyer , Michael F. Hagan

The self-assembly of nanocrystals enables new classes of materials whose properties are controlled by the periodicities of the assembly, as well as by the size, shape and composition of the nanocrystals. While self-assembly of spherical…

Chirality is an intriguing property of certain molecules, materials or artificial nanostructures, which allows them to interact with the spin angular momentum of the impinging light field. Due to their chiral geometry, they can distinguish…

Optics · Physics 2016-11-03 Peter Banzer , Pawel Wozniak , Uwe Mick , Israel De Leon , Robert W. Boyd

Programmable assembly of nanoparticles into structures other than hexagonal lattices remains challenging. Assembling an open checkerboard or square lattice is harder to achieve compared to a close-packed hexagonal structure. Here, we…

Colloidal particles can spontaneously self-assemble into ordered structures, which not only can manipulate the propagation of light, but also vibration or phonons. Using Monte Carlo simulation, we study the self-assembly of perfectly…

Soft Condensed Matter · Physics 2024-03-11 Ji-Dong Hu , Ting Wang , Qun-Li Lei , Yu-qiang Ma

Two-dimensional colloidal halide perovskite nanocrystals are promising materials for light emitting applications. In addition, they can be used as components to create a variety of materials through physical and chemical transformations.…

Monodispersed magnetite (Fe3O4) nanoparticles were synthesized. Transmission electron microscopy study shows that the nanoparticles are in the shape of Wagner-Seitz crystals. The magnetite nanoparticles self-assemble into body-centered…

Materials Science · Physics 2007-05-23 R. K. Zheng , Hongwei Gu , Bing Xu , K. K. Fung , X. X. Zhang

The inherently weak chiroptical responses of natural materials limit their usage for controlling and enhancing chiral light-matter interactions. Recently, several nanostructures with subwavelength scale dimensions were demonstrated, mainly…

We investigate a mechanism to produce superconductivity by strong purely repulsive interactions for flat dispersion $\varepsilon \sim k^4$, without using pairing instability in Fermi-liquid. The resulting superconductors break both…

Strongly Correlated Electrons · Physics 2025-01-24 Minho Kim , Abigail Timmel , Long Ju , Xiao-Gang Wen

Colloidal crystal structures with complexity and diversity rivaling atomic and molecular crystals have been predicted and obtained for hard particles by entropy maximization. However, so far homochiral colloidal crystals, which are…

Soft Condensed Matter · Physics 2015-10-13 Pablo F. Damasceno , Andrew S. Karas , Benjamin A. Schultz , Michael Engel , Sharon C. Glotzer
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