Related papers: Treating geometric phase effects in nonadiabatic d…
The analysis of geometric phases is briefly reviewed by emphasizing various gauge symmetries involved. The analysis of geometric phases associated with level crossing is reduced to the familiar diagonalization of the Hamiltonian in the…
Treating a many-body Fermi system in terms of a single particle in a deforming mean field. We relate adiabatic geometric phase to susceptibility for the noncyclic case, and to its derivative for the cyclic case. Employing the semiclassical…
Adiabatic pumping is characterized by a geometric contribution to the pumped charge, which can be non-zero even in the absence of a bias. However, as the driving speed is increased, non-adiabatic excitations gradually reduce the pumped…
Nonadiabatic ring-polymer molecular dynamics employs the mapping approach to describe nonadiabatic effects within the ring-polymer ansatz. In this paper, it is generalized to allow for the nuclear and electronic degrees of freedom to be…
Low-energy Hamiltonians with a linear crossing in their energy dispersion (dubbed Dirac Hamiltonians) have recently been the subject of intense investigations. The linear dispersion is often the result of an approximation in the energy…
Real-time simulations of laser-driven electron dynamics contain information about molecular optical properties through all orders in response theory. These properties can be extracted by assuming convergence of the power series expansion of…
Quantum molecular dynamics requires an accurate representation of the molecular potential energy surface from a minimal number of electronic structure calculations, particularly for nonadiabatic dynamics where excited states are required.…
We study Hamiltonian form of unfree gauge symmetry where the gauge parameters have to obey differential equations. We consider the general case such that the Dirac-Bergmann algorithm does not necessarily terminate at secondary constraints,…
Geometric phases play a crucial role in diverse fields. In chemistry they appear when a reaction path encircles an intersection between adiabatic potential energy surfaces and the molecular wavefunction experiences quantum-mechanical…
We propose a general, fully gate-based quantum algorithm for counterdiabatic driving. The algorithm does not depend on heuristics as in previous variational methods, and exploits regularisation of the adiabatic gauge potential to suppress…
We introduce an alternative way to derive the generalized form of the master equation recently presented by J. P. Pekola et al. [Phys. Rev. Lett. 105, 030401 (2010)] for an adiabatically steered two-level quantum system interacting with a…
Quantum computation has demonstrated advantages over classical computation for special hard problems, where a set of universal quantum gates is essential. Geometric phases, which have built-in resilience to local noise, have been used to…
We decompose the quantum adiabatic evolution as the products of gauge invariant unitary operators and obtain the exact nonadiabatic correction in the adiabatic approximation. A necessary and sufficient condition that leads to adiabatic…
We study dynamical tunneling in a near-integrable Hamiltonian with three degrees of freedom. The model Hamiltonian does not have any discrete symmetry. Despite this lack of symmetry we show that the mixing of near-degenerate quantum states…
We propose and solve a minimal model of dynamic passage through a second-order phase transition in the presence of symmetry breaking interactions and no dissipation. Our model generalizes the Hamiltonian dynamics of the Painleve'-2 equation…
The interaction between electronic and vibrational degrees of freedom in single-molecule junctions may result from the dependence of the electronic energies or the electronic states of the molecular bridge on the nuclear displacement. The…
Recently, nonadiabatic geometric quantum computation has been received great attentions, due to its fast operation and intrinsic error resilience. However, compared with the corresponding dynamical gates, the robustness of implemented…
Among various approaches in proving gauge independence, models containing an explicit gauge dependence are convenient. The well-known example is the gauge parameter in the covariant gauge fixing which is of course most suitable for the…
Adiabatic gauge potential is the origin of nonadiabatic transitions. In counterdiabatic driving, which is a method of shortcuts to adiabaticity, adiabatic gauge potential can be used to realize identical dynamics to adiabatic time evolution…
Appearance of adiabatic geometric phase shift in the context of noncommutative quantum mechanics is studied using an exactly solvable model of 2D simple harmonic oscilator in Moyal plane, where momentum non-commutativity are also considered…