Related papers: Treating geometric phase effects in nonadiabatic d…
Nonadiabatic holonomic quantum computation has received increasing attention due to the merits of both robustness against control errors and high-speed implementation. A crucial step in realizing nonadiabatic holonomic quantum computation…
Direct dynamics methods using Gaussian wavepackets have to rely only on local properties, such as gradients and hessians at the center of the wavepacket, so as to be compatible with the usual quantum chemistry methods. Matrix elements of…
We study the dynamics of non-adiabatic transitions in non-Hermitian multi-level parabolic models where the separations of the diabatic energies are quadratic function of time. The model Hamiltonian has been used to describe the…
We study effects of nonadiabatic couplings in a model of a diatomic molecule in the context of attosecond transient absorption spectroscopy. By using a model system consisting of four diabatic electronic states and with a variable strength…
We present a comprehensive computational framework for simulating nonadiabatic molecular dynamics with explicit inclusion of geometric phase (GP) effects. Our approach is based on a generalized two-level Hamiltonian model that can represent…
The geometric phase stands as a foundational concept in quantum physics, revealing deep connections between geometric structures and quantum dynamical evolution. Unlike dynamical phases, geometric phases exhibit intrinsic resilience to…
We use the theory of dynamical invariants to yield a simple derivation of noncyclic analogues of the Abelian and non-Abelian geometric phases. This derivation relies only on the principle of gauge invariance and elucidates the existing…
Adiabatic transformation can be approximated as alternating unitary operators of a Hamiltonian and its parameter derivative as proposed in a gate-based approach to counterdiabatic driving (van Vreumingen, arXiv:2406.08064). In this paper,…
The second quantized approach to geometric phases is reviewed. The second quantization generally induces a hidden local (time-dependent) gauge symmetry. This gauge symmetry defines the parallel transport and holonomy, and thus it controls…
We discuss the basic theoretical framework for non-Hermitian quantum systems with particular emphasis on the diagonalizability of non-Hermitian Hamiltonians and their $GL(1,\mathbb{C})$ gauge freedom, which are relevant to the adiabatic…
We investigate geometric phase (GP) effects in nonadiabatic transitions through a conical intersection (CI) in an N-dimensional linear vibronic coupling (ND-LVC) model. This model allows for the coordinate transformation encompassing all…
A precise definition of an adiabaticity parameter $\nu$ of a time-dependent Hamiltonian is proposed. A variation of the time-dependent perturbation theory is presented which yields a series expansion of the evolution operator…
An approach to the quantum-classical mechanics of phase space dependent operators, which has been proposed recently, is remodeled as a formalism for wave fields. Such wave fields obey a system of coupled non-linear equations that can be…
Nonadiabatic geometric quantum computation (NGQC) has emerged as an excellent proposal for achieving fast and robust quantum control against control errors. However, previous NGQC protocols could not be strongly resilient against the noise…
We present an efficient implementation of analytical non-adiabatic derivative coupling elements for the coupled cluster singles and doubles model. The derivative coupling elements are evaluated in a biorthonormal formulation in which the…
At present, several models for quantum computation have been proposed. Adiabatic quantum computation scheme particularly offers this possibility and is based on a slow enough time evolution of the system, where no transitions take place. In…
We present a reformulation of quantum adiabatic theory in terms of an emergent electromagnetic framework, emphasizing the physical consequences of geometric structures in parameter space. Contrary to conventional approaches, we demonstrate…
The Hamiltonian formulation for a non-Abelian gauge theory in two spatial dimensions is carried out in terms of a gauge-invariant matrix parametrization of the fields. The Jacobian for the relevant transformation of variables is given in…
A single-loop scenario is proposed to realize nonadiabatic geometric quantum computation. Conventionally, a so-called multi-loop approach is used to remove the dynamical phase accumulated in the operation process for geometric quantum…
We develop the theory of the nonadiabatic geometric phase, in both the Abelian and non-Abelian cases, in quaternionic Hilbert space.