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The atomic cluster expansion (ACE) (Drautz, 2019) yields a highly efficient and intepretable parameterisation of symmetric polynomials that has achieved great success in modelling properties of many-particle systems. In the present work we…

Computational Physics · Physics 2023-05-05 Dexuan Zhou , Huajie Chen , Cheuk Hin Ho , Christoph Ortner

Atomic cluster expansion (ACE) methods provide a systematic way to describe particle local environments of arbitrary body order. For practical applications it is often required that the basis of cluster functions be symmetrized with respect…

Materials Science · Physics 2024-02-27 James M. Goff , Charles Sievers , Mitchell A. Wood , Aidan P. Thompson

The Atomic Cluster Expansion (ACE) (Drautz, Phys. Rev. B 99, 2019) has been widely applied in high energy physics, quantum mechanics and atomistic modeling to construct many-body interaction models respecting physical symmetries.…

Numerical Analysis · Mathematics 2024-01-08 Cheuk Hin Ho , Timon S. Gutleb , Christoph Ortner

The Atomic Cluster Expansion (ACE) [R. Drautz, Phys. Rev. B, 99:014104 (2019)] provides a systematically improvable, universal descriptor for the environment of an atom that is invariant to permutation, translation and rotation. ACE is…

Computational Physics · Physics 2023-08-15 Christoph Ortner

We present an atomic cluster expansion (ACE) for carbon that improves over available classical and machine learning potentials. The ACE is parameterized from an exhaustive set of important carbon structures at extended volume and energy…

Materials Science · Physics 2023-06-13 Minaam Qamar , Matous Mrovec , Yury Lysogorskiy , Anton Bochkarev , Ralf Drautz

Machine learning interatomic potentials are revolutionizing large-scale, accurate atomistic modelling in material science and chemistry. Many potentials use atomic cluster expansion or equivariant message passing frameworks. Such frameworks…

Computational Physics · Physics 2024-07-31 Bingqing Cheng

We present a highly accurate and transferable parameterization of water using the atomic cluster expansion (ACE). To efficiently sample liquid water, we propose a novel approach that involves sampling static calculations of various ice…

Materials Science · Physics 2024-06-21 Eslam Ibrahim , Yury Lysogorskiy , Ralf Drautz

We present a general-purpose parameterization of the atomic cluster expansion (ACE) for magnesium. The ACE shows outstanding transferability over a broad range of atomic environments and captures physical properties of bulk as well as…

Materials Science · Physics 2023-05-08 Eslam Ibrahim , Yury Lysogorskiy , Matous Mrovec , Ralf Drautz

A quantitative first-principles description of complex substitutional materials like alloys is challenging due to the vast number of configurations and the high computational cost of solving the quantum-mechanical problem. Therefore,…

Materials Science · Physics 2025-06-24 Adrian Stroth , Claudia Draxl , Santiago Rigamonti

Traditionally, interatomic potentials assume local bond formation supplemented by long-range electrostatic interactions when necessary. This ignores intermediate range multi-atom interactions that arise from the relaxation of the electronic…

Materials Science · Physics 2022-11-07 Anton Bochkarev , Yury Lysogorskiy , Christoph Ortner , Gábor Csányi , Ralf Drautz

The atomic cluster expansion is a general polynomial expansion of the atomic energy in multi-atom basis functions. Here we implement the atomic cluster expansion in the performant C++ code \verb+PACE+ that is suitable for use in large scale…

We study the convergence of a linear atomic cluster expansion (ACE) potential with respect to its basis functions, in terms of the effective two-body interactions of elemental Carbon and Silicon systems. We build ACE potentials with…

Computational Physics · Physics 2025-07-30 Apolinario Miguel Tan , Franco Pellegrini , Stefano de Gironcoli

Equivariant atomistic machine learning models have largely been built on spherical-tensor representations, where explicit angular-momentum coupling introduces substantial complexity and systematic extensions beyond energies and forces…

Machine Learning · Statistics 2026-03-09 Zemin Xu , Wenbo Xie , P. Hu

The Atomic Cluster Expansion (Drautz, Phys. Rev. B 99, 2019) provides a framework to systematically derive polynomial basis functions for approximating isometry and permutation invariant functions, particularly with an eye to modelling…

Numerical Analysis · Mathematics 2021-05-13 Genevieve Dusson , Markus Bachmayr , Gabor Csanyi , Ralf Drautz , Simon Etter , Cas van der Oord , Christoph Ortner

We derive an adaptive hierarchical method of estimating high dimensional probability density functions. We call this method of density estimation the "adaptive cluster expansion" or ACE for short. We present an application of this approach,…

Neural and Evolutionary Computing · Computer Science 2010-12-17 Stephen Luttrell

Using the maximum entropy method, we derive the "adaptive cluster expansion" (ACE), which can be trained to estimate probability density functions in high dimensional spaces. The main advantage of ACE over other Bayesian networks is its…

Neural and Evolutionary Computing · Computer Science 2007-05-23 Stephen Luttrell

We review some recently published methods to represent atomic neighbourhood environments, and analyse their relative merits in terms of their faithfulness and suitability for fitting potential energy surfaces. The crucial properties that…

Computational Physics · Physics 2015-06-11 Albert P. Bartók , Risi Kondor , Gábor Csányi

A new approach to the geometrization of the electron theory is proposed. The particle wave function is represented by a geometric entity, i.e., Clifford number, with the translation rules possessing the structure of Dirac equation for any…

Quantum Physics · Physics 2015-05-27 B. I. Lev

The optimized effective potential equations for atoms have been solved by parameterizing the potential. The expansion is tailored to fulfill the known asymptotic behavior of the effective potential at both short and long distances. Both…

Atomic Physics · Physics 2007-05-23 A. Sarsa , F. J. Galvez , E. Buendia

Machine-learned interatomic potentials enable large systems to be simulated for long time scales at near ab-initio accuracy. This accuracy is achieved by fitting extremely flexible model architectures to high quality reference data. In…

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