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We extend the use of coupled cluster (CC) trial states in the phaseless auxiliary-field quantum Monte Carlo (AFQMC) method beyond single and double excitations to include both triple and quadruple excitations. With this AFQMC/CC hierarchy,…

Chemical Physics · Physics 2025-10-09 Eirik F. Kjønstad , Yann Damour , Sandeep Sharma , Garnet Kin-Lic Chan

We propose a practical method for accurately evaluating molecular energies using a hybrid approach that integrates fault-tolerant quantum computers with classical computing. Our scheme comprises two complementary methods: quantum dominant…

Quantum Physics · Physics 2026-03-04 Nobuki Inoue , Hisao Nakamura

The factorized form of the unitary coupled-cluster approximation is one of the most promising methodologies to prepare trial states for strongly correlated systems within the variational quantum eigensolver framework. The factorized form of…

Quantum Physics · Physics 2022-01-05 Luogen Xu , Joseph T. Lee , J. K. Freericks

Downfolding coupled cluster (CC) techniques are powerful tools for reducing the dimensionality of many-body quantum problems. This work investigates how ground-state downfolding formalisms can target excited states using non-Aufbau…

Chemical Physics · Physics 2023-10-24 Nicholas P. Bauman

At large scales, quantum systems may become advantageous over their classical counterparts at performing certain tasks. Developing tools to analyse these systems at the relevant scales, in a manner consistent with quantum mechanics, is…

Quantum Physics · Physics 2024-11-12 Timon Schapeler , Robert Schade , Michael Lass , Christian Plessl , Tim J. Bartley

We propose a general strategy to develop quantum many-body approximations of primitives in linear algebra algorithms. As a practical example, we introduce a coupled-cluster inspired framework to produce approximate Hamiltonian moments, and…

Chemical Physics · Physics 2025-12-30 Yuhang Ai , Huanchen Zhai , Johannes Tölle , Garnet Kin-Lic Chan

A powerful tool emerging from the study of many-body quantum dynamics is that of dual-unitary circuits, which are unitary even when read `sideways', i.e., along the spatial direction. Here, we show that this provides the ideal framework to…

Quantum Physics · Physics 2024-06-25 David T. Stephen , Wen Wei Ho , Tzu-Chieh Wei , Robert Raussendorf , Ruben Verresen

In a recent paper, J. Chem. Phys. 162, 214101 (2025), a novel approach for the rigidification of a molecular cluster was proposed, in which starting with an all-atom (AA) potential, a coarse-grained (CG) potential for the associated cluster…

Chemical Physics · Physics 2025-09-08 João V. M. Pimentel , Vladimir A. Mandelshtam

Among various approaches toward quantum computation, measurement-based quantum computation (MBQC) multiplexed in time domain is currently a promising method for addressing the need for scalability. MBQC requires two components: cluster…

The calculation time for the energy of atoms and molecules scales exponentially with system size on a classical computer but polynomially using quantum algorithms. We demonstrate that such algorithms can be applied to problems of chemical…

Quantum Physics · Physics 2007-05-23 Alán Aspuru-Guzik , Anthony D. Dutoi , Peter J. Love , Martin Head-Gordon

We present a framework of an auxiliary field quantum Monte Carlo (QMC) method for multi-orbital Hubbard models. Our formulation can be applied to a Hamiltonian which includes terms for on-site Coulomb interaction for both intra- and…

Strongly Correlated Electrons · Physics 2009-10-30 Yukitoshi Motome , Masatoshi Imada

We propose a new application of quantum computing to the field of natural language processing. Ongoing work in this field attempts to incorporate grammatical structure into algorithms that compute meaning. In (Coecke, Sadrzadeh and Clark,…

Computation and Language · Computer Science 2016-08-05 William Zeng , Bob Coecke

Measurement based quantum computation (MBQC) is an effective paradigm for universal quantum computation. In this scheme, the universal set of quantum gates are realized by only local measurements on the prior prepared cluster states. The…

Quantum Physics · Physics 2013-11-26 Ding Zhong , Jian Wang , Ning Dai , Liang-Zhu Mu , Heng Fan

The variational quantum eigensolver has been proposed as a low-depth quantum circuit that can be employed to examine strongly correlated systems on today's noisy intermediate-scale quantum computers. We examine details associated with the…

Quantum Physics · Physics 2020-08-26 Luogen Xu , Joseph T. Lee , J. K. Freericks

The unitary cluster Jastrow (UCJ) ansatz and its variant known as local UCJ (LUCJ) are promising choices for variational quantum algorithms for chemistry due to their combination of physical motivation and hardware efficiency. The…

Quantum Physics · Physics 2025-12-01 Wan-Hsuan Lin , Fangchun Liang , Mario Motta , Haimeng Zhang , Kenneth M. Merz , Kevin J. Sung

Using trial wavefunctions prepared on quantum devices to reduce the bias of auxiliary-field quantum Monte Carlo (QC-AFQMC) has established itself as a promising hybrid approach to the simulation of strongly correlated many body systems.…

Quantum Physics · Physics 2024-09-16 Matthew Kiser , Matthias Beuerle , Fedor Simkovic

Molecular fragment or embedding methods are powerful techniques for overcoming scalability limitations in electronic structure theory by dividing large molecular systems into individual units that are small enough to be treated using…

Chemical Physics · Physics 2017-08-14 Jason N. Byrd , Robert W. Molt, , Rodney J. Bartlett , Beverly A. Sanders

Neural quantum states (NQS) provide a flexible and highly expressive parameterization of wave functions for strongly correlated problems in quantum chemistry. Despite rapid advances in network architectures, the evaluation of electronic…

Chemical Physics · Physics 2026-02-16 Marco Julian Solanki , Lexin Ding , Markus Reiher

Representations of quantum computations are almost always based on a tensor product $\otimes$-structure. This coincides with what we are able to execute in our experiments, as well as what we observe in Nature, but it makes certain familiar…

Quantum Physics · Physics 2021-11-05 Luca Mondada

The quantum hybrid algorithm has become a very promising and speedily method today for solving the larger-scale optimization in the noisy intermediate-scale quantum (NISQ) era. The unit commitment (UC) problem is a fundamental problem in…

Quantum Physics · Physics 2025-10-10 Jian Liu , Xu Zhou , Zhuojun Zhou , Le Luo