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When the interaction between a molecular system and confined light modes in an optical or plasmonic cavity is strong enough to overcome the dissipative process, hybrid light-matter states (polaritons) become the fundamental excitations in…

Mesoscale and Nanoscale Physics · Physics 2020-01-08 Yu Zhang , Tammie Nelson , Sergei Tretiak

Polaritonic states arise when a bright optical transition of a molecular ensemble is resonantly matched to an optical cavity mode frequency. Here, we lay the groundwork to study the behavior of polaritons in clean, isolated systems by…

Chemical Physics · Physics 2023-10-20 Adam D. Wright , Jane C. Nelson , Marissa L. Weichman

We present the effects of resonator birefringence on the cavity-enhanced interfacing of quantum states of light and matter, including the first observation of single photons with a time-dependent polarisation state that evolves within their…

Quantum Physics · Physics 2019-03-27 Thomas D. Barrett , Oliver Barter , Dustin Stuart , Ben Yuen , Axel Kuhn

The strong coupling between molecules and photonic modes in a Fabry-P\'{e}rot optical cavity, which forms hybrid light-matter states called polaritons, has been demonstrated as a promising route to control the rates of chemical reactions.…

Quantum Physics · Physics 2025-05-22 Kunyang Sun , Matthew Du , Joel Yuen-Zhou

Resonant vibrational strong coupling (VSC) between molecular vibrations and quantized field modes of low-frequency optical cavities constitutes the conceptual cornerstone of vibro-polaritonic chemistry. In this work, we theoretically…

Chemical Physics · Physics 2025-12-02 Eric W. Fischer

It is usually considered that the spectrum of an optical cavity coupled to an atomic medium does not exhibit a normal-mode splitting unless the system satisfies the strong coupling condition, meaning the Rabi frequency of the coherent…

Quantum Physics · Physics 2017-01-06 Y. -H. Lien , G. Barontini , M. Scheucher , M. Mergenthaler , J. Goldwin , E. A. Hinds

We present a theoretical study of the collective quasiparticle excitations responsible for the electromagnetic response of ultrathin plane-parallel homogeneous periodic single-wall carbon nanotube arrays and weakly inhomogeneous single-wall…

Mesoscale and Nanoscale Physics · Physics 2021-03-09 Igor V. Bondarev , Chandra M. Adhikari

In this paper we study cavity optomechanical systems in which the position of a mechanical oscillator modulates both the resonance frequency (dispersive coupling) and the linewidth (dissipative coupling) of a cavity mode. Using a quantum…

Quantum Physics · Physics 2013-05-21 Talitha Weiss , Christoph Bruder , Andreas Nunnenkamp

Experiments show that light-matter strong coupling affects chemical properties, though the underlying mechanism remains unclear. We present an ab initio quantum electrodynamics coupled cluster method for the collective strong coupling…

Chemical Physics · Physics 2024-11-18 Matteo Castagnola , Marcus T. Lexander , Henrik Koch

When an atom strongly couples to a cavity, it can undergo coherent vacuum Rabi oscillations. Controlling these oscillatory dynamics quickly relative to the vacuum Rabi frequency enables remarkable capabilities such as Fock state generation…

Optics · Physics 2014-10-31 Ranojoy Bose , Tao Cai , Kaushik Roy Choudhury , Glenn S. Solomon , Edo Waks

Cavity quantum electrodynamics (C-QED) effects, such as Rabi splitting, Rabi oscillations and superradiance, have been demonstrated with nitrogen vacancy center spins in diamond in microwave resonators at cryogenic temperature. In this…

Quantum Physics · Physics 2022-07-14 Yuan Zhang , Qilong Wu , Shi-Lei Su , Qing Lou , ChongXin Shan , Klaus Mølmer

We study an atom-cavity system in which the cavity has several degenerate transverse modes. Mode-resolved cavity transmission spectroscopy reveals well-resolved atom-cavity resonances for several cavity modes, a signature of collective…

Despite recent numerical evidence, one of the fundamental theoretical mysteries of polaritonic chemistry is how and if collective strong coupling can induce local changes of the electronic structure to modify chemical properties. Here we…

We consider an ensemble of homonuclear diatomic molecules coupled to the two polarization directions of a Fabry-P\'erot cavity via fully quantum simulations. Accompanied by analytical results, we identify a coupling mechanism mediated…

Chemical Physics · Physics 2024-01-22 Niclas Krupp , Oriol Vendrell

A promising approach to merge atomic systems with scalable photonics has emerged recently, which consists of trapping cold atoms near tapered nanofibers. Here, we describe a novel technique to achieve strong, coherent coupling between a…

Quantum Physics · Physics 2015-06-03 D. E. Chang , L. Jiang , A. V. Gorshkov , H. J. Kimble

We study the motion of two atoms trapped at distant positions in the field of a driven standing wave high-Q optical resonator. Even without any direct atom-atom interaction the atoms are coupled through their position dependent influence on…

Quantum Physics · Physics 2007-05-23 J. K. Asbóth , P. Domokos , H. Ritsch

We investigate Rabi oscillation of an atom ensemble in Gaussian spatial distribution. By using the ultrafast laser interaction with the cold atomic rubidium vapor spatially confined in a magneto-optical trap, the oscillatory behavior of the…

Atomic Physics · Physics 2016-06-09 Han-gyeol Lee , Hyosub Kim , Jaewook Ahn

Strong light-matter interactions between molecules and quantized electromagnetic fields inside an optical cavity open up novel possibilities, though inevitably influenced by disorder, an inherent attribute of realistic molecular systems.…

Chemical Physics · Physics 2025-05-29 Robert F. Catuto , Hsing-Ta Chen

We study ultracold atoms in a finite size one-dimensional optical lattice prepared in the Mott insulator phase and commonly coupled to a single cavity mode. Due to resonance dipole-dipole interactions among the atoms, electronic excitations…

Quantum Physics · Physics 2009-08-10 Hashem Zoubi , Helmut Ritsch

Achieving and controlling strong light-matter interactions in many-body systems is of paramount importance both for fundamental understanding and potential applications. In this paper we demonstrate both experimentally and theoretically how…

Mesoscale and Nanoscale Physics · Physics 2016-12-26 Pierre Fauche , Christian Gebhardt , Maxim Sukharev , Renaud A. L. Vallee