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The Bochkov-Kuzovlev nonlinear fluctuation-dissipation theorem is used to derive Narayanaswamy's phenomenological theory of physical aging, in which this highly nonlinear phenomenon is described by a linear material-time convolution…

Statistical Mechanics · Physics 2017-01-04 Jeppe C. Dyre

Although it has been known for half a century that the physical aging of glasses in experiments is described well by a linear thermal-history convolution integral over the so-called material time, the microscopic definition and…

Soft Condensed Matter · Physics 2022-11-30 Ian M. Douglass , Jeppe C. Dyre

The random first order transition theory of the dynamics of supercooled liquids is extended to treat aging phenomena in nonequilibrium structural glasses. A reformulation of the idea of ``entropic droplets'' in terms of libraries of local…

Soft Condensed Matter · Physics 2009-11-10 Vassiliy Lubchenko , Peter G. Wolynes

The noncrystalline glassy state of matter plays a role in virtually all fields of materials science and offers complementary properties to those of the crystalline counterpart. The caveat of the glassy state is that it is out of equilibrium…

This paper presents simulations of the physical aging of a binary Kob-Andersen-type Lennard-Jones liquid following large temperature up-jumps from equilibrated states of high relaxation time. The purpose is to investigate how well the…

Soft Condensed Matter · Physics 2026-04-14 Aude Y. Amari , Lorenzo Costigliola , Jeppe C. Dyre

This paper studies physical aging by computer simulations of a 2:1 Kob-Andersen binary Lennard-Jones mixture, a system that is less prone to crystallization than the standard 4:1 composition. Starting from thermal-equilibrium states, the…

Soft Condensed Matter · Physics 2021-03-03 Saeed Mehri , Trond S. Ingebrigtsen , Jeppe C. Dyre

Aging to the equilibrium liquid state of organic glasses is studied. The glasses were prepared by cooling the liquid to temperatures just below the glass transition. Aging following a temperature jump was studied by measuring the dielectric…

Soft Condensed Matter · Physics 2013-01-29 Tina Hecksher , Niels Boye Olsen , Kristine Niss , Jeppe C. Dyre

The physical aging of supercooled glycerol induced by upward temperature steps of amplitude reaching 45 K was studied by a new method consisting in heating a micrometer-thick liquid film at a rate of up to 60 000 K/s, holding it at a…

Soft Condensed Matter · Physics 2023-06-16 Marceau Hénot , François Ladieu

Physical ageing is the generic term for irreversible processes in glassy materials resulting from molecular rearrangements. One formalism for describing such ageing processes involves the concept of material time, which may be thought of as…

This paper presents accurate data for the physical aging of organic glasses just below the glass transition probed by monitoring the following quantities after temperature up and down jumps: the shear-mechanical resonance frequency (around…

Soft Condensed Matter · Physics 2017-01-04 Tina Hecksher , Niels Boye Olsen , Jeppe C. Dyre

This paper derives and discusses the configuration-space Langevin equation describing a physically aging R-simple system and the corresponding Smoluchowski equation. Externally controlled thermodynamic variables like temperature, density,…

Soft Condensed Matter · Physics 2018-04-20 Jeppe C. Dyre

A high-resolution, temperature oscillation-based probe of physical aging in complex systems is introduced. The Fourier analysis of the measured responses allows one to extract a high-order aging-related complex susceptibility that is not…

Chemical Physics · Physics 2023-08-14 Kevin Moch , Roland Böhmer , Catalin Gainaru

Understanding glasses is considered to be one of the most fundamental problems in statistical physics. A theoretical approach to unravel their universal properties is to consider the validity of equilibrium concepts such as temperature and…

Soft Condensed Matter · Physics 2015-06-25 Ping Wang , Chaoming Song , Hernan A. Makse

We present a detailed study of simple `tree' models for off equilibrium dynamics and aging in glassy systems. The simplest tree describes the landscape of a random energy model, whereas multifurcating trees occur in the solution of the…

Condensed Matter · Physics 2009-10-22 J-P. Bouchaud , D. S. Dean

The relaxation dynamics of many disordered systems, such as structural glasses, proteins, granular materials or spin glasses, is not completely frozen even at very low temperatures. This residual motion leads to a change of the properties…

Soft Condensed Matter · Physics 2009-10-31 Walter Kob , Francesco Sciortino , Piero Tartaglia

The experimental time scale dependence of thermodynamic relations in out-of-equilibrium systems with aging phenomena is investigated theoretically by using only aging properties of the two-time correlation functions and the generalized…

Disordered Systems and Neural Networks · Physics 2009-10-31 Mitsuhiro Kawasaki

We present time-dependent dielectric loss data at different frequencies for a variety of glass formers after cooling below the glass temperature. The observed aging dynamics is described using a modified Kohlrausch-Williams-Watts law, which…

Disordered Systems and Neural Networks · Physics 2007-05-23 P. Lunkenheimer , R. Wehn , U. Schneider , A. Loidl

Using molecular dynamics computer simulations we investigate the out-of-equilibrium dynamics of a Lennard-Jones system after a quench from a high temperature to one below the glass transition temperature. By studying the radial distribution…

Statistical Mechanics · Physics 2009-10-31 Walter Kob , Jean-Louis Barrat , Francesco Sciortino , Piero Tartaglia

The mean-field dynamics of a particle in a random, but short range correlated potential, offers the opportunity of observing both aging and driven stationary regimes. Using a geometrical approach previously introduced by the author, we…

Condensed Matter · Physics 2009-10-31 Fabrice Thalmann

A model is proposed that considers aging and rejuvenation in a soft glassy material as respectively a decrease and an increase in free energy. The aging term is weighted by inverse of characteristic relaxation time suggesting greater…

Soft Condensed Matter · Physics 2015-02-25 Yogesh M. Joshi
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