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Hardware-efficient empirical variational ans\"atze for Variational Quantum Eigensolver simulations of Quantum Chemistry suffer from the lack of a direct connection to classical Quantum Chemistry methods. In the present work, we propose a…

Quantum Physics · Physics 2025-09-03 Davide Materia , Leonardo Ratini , Celestino Angeli , Leonardo Guidoni

We present numerical upscaling techniques for a class of linear second-order self-adjoint elliptic partial differential operators (or their high-resolution finite element discretization). As prototypes for the application of our theory we…

Numerical Analysis · Mathematics 2014-09-11 Axel Malqvist , Daniel Peterseim

We propose a quantum algorithm based on ridge regression model, which get the optimal fitting parameters w and a regularization hyperparameter {\alpha} by analysing the training dataset. The algorithm consists of two subalgorithms. One is…

Quantum Physics · Physics 2021-04-28 Menghan Chen , Chaohua Yu , Gongde Guo , Song Lin

This paper can be seen as an attempt of rethinking the {\em Extra-Gradient Philosophy} for solving Variational Inequality Problems. We show that the properly defined {\em Reduced Gradients} can be used instead for finding approximate…

Optimization and Control · Mathematics 2023-12-05 Yurii Nesterov

We solve an eigenvalue equation that appears in several papers about a wide range of physical problems. The Frobenius method leads to a three-term recurrence relation for the coefficients of the power series that, under suitable truncation,…

Quantum Physics · Physics 2024-12-17 Paolo Amore , Francisco M. Fernández

This work is concerned with finite range bounds on the variance of individual eigenvalues of random covariance matrices, both in the bulk and at the edge of the spectrum. In a preceding paper, the author established analogous results for…

Probability · Mathematics 2013-09-25 Sandrine Dallaporta

We propose a method for finding approximate compilations of quantum unitary transformations, based on techniques from policy gradient reinforcement learning. The choice of a stochastic policy allows us to rephrase the optimization problem…

Quantum Physics · Physics 2022-09-14 David A. Herrera-Martí

We present a generalization of the variational principle that is compatible with any Hamiltonian eigenstate that can be specified uniquely by a list of properties. This variational principle appears to be compatible with a wide range of…

Chemical Physics · Physics 2020-02-07 Jacqueline A. R. Shea , Elise Gwin , Eric Neuscamman

We analyze transition potentials $(V(r) \stackrel{r\sim 0}{\rightarrow} {\alpha r^{-2}})$ in non-relativistic quantum mechanics using the techniques of supersymmetry. For the range $-1/4 < \alpha < 3/4$, the eigenvalue problem becomes…

High Energy Physics - Theory · Physics 2016-09-06 Asim Gangopadhyaya , Prasanta K. Panigrahi , Uday P. Sukhatme

Recent advances in quantum computing devices have brought attention to hybrid quantum-classical algorithms like the Variational Quantum Eigensolver (VQE) as a potential route to practical quantum advantage in chemistry. However, it is not…

A quantum model based on a Euler-Lagrange variational approach is proposed. In analogy with the classical transport, our approach maintain the description of the particle motion in terms of trajectories in a configuration space. Our method…

Mathematical Physics · Physics 2018-07-04 O. Morandi

We use a numerical-analytic technique to construct a sequence of successive approximations to the solution of a system of fractional differential equations, subject to Dirichlet boundary conditions. We prove the uniform convergence of the…

Numerical Analysis · Mathematics 2022-09-05 Kateryna Marynets , Dona Pantova

The investigation of symmetry nonrestoration scenarios has led to a controversy, with certain nonperturbative approximation schemes giving indications in sharp disagreement with those found within conventional perturbation theory. A…

High Energy Physics - Phenomenology · Physics 2016-09-06 G. Amelino-Camelia

We propose probabilistic representations for inverse Stein operators (i.e. solutions to Stein equations) under general conditions; in particular we deduce new simple expressions for the Stein kernel. These representations allow to deduce…

Probability · Mathematics 2019-06-21 Marie Ernst , Gesine Reinert , Yvik Swan

We give an inductive procedure for finding the extremal rays of the equivariant Littlewood-Richardson cone, which is closely related to the solution space to S. Friedland's majorized Hermitian eigenvalue problem. In so doing, we solve the…

Combinatorics · Mathematics 2021-06-17 Joshua Kiers

We consider the statistical mechanics of a classical particle in a one-dimensional box subjected to a random potential which constitutes a Wiener process on the coordinate axis. The distribution of the free energy and all correlation…

Condensed Matter · Physics 2009-10-28 Kurt Broderix , Reiner Kree

The variational approach is a cornerstone of computational physics, considering both conventional and quantum computing computational platforms. The variational quantum eigensolver (VQE) algorithm aims to prepare the ground state of a…

Quantum Physics · Physics 2022-12-16 Nikita Astrakhantsev , Guglielmo Mazzola , Ivano Tavernelli , Giuseppe Carleo

A variational principle is further developed for out of equilibrium dynamical systems by using the concept of maximum entropy. With this new formulation it is obtained a set of two first-order differential equations, revealing the same…

Data Analysis, Statistics and Probability · Physics 2019-03-22 Mario J. Pinheiro

The purpose of this work is to study a finite element method for finding solutions to the eigenvalue problem for the fractional Laplacian. We prove that the discrete eigenvalue problem converges to the continuous one and we show the order…

Numerical Analysis · Mathematics 2019-02-04 Juan Pablo Borthagaray , Leandro M. Del Pezzo , Sandra Martínez

The variational quantum eigensolver (VQE) and its variants, which is a method for finding eigenstates and eigenenergies of a given Hamiltonian, are appealing applications of near-term quantum computers. Although the eigenenergies are…

Quantum Physics · Physics 2020-02-12 Kosuke Mitarai , Yuya O. Nakagawa , Wataru Mizukami
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