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Electronic devices composed of single molecules constitute the ultimate limit in the continued downscaling of electronic components. A key challenge for single-molecule electronics is to control the temperature of these junctions.…

Mesoscale and Nanoscale Physics · Physics 2016-04-08 Jacob Lykkebo , Giuseppe Romano , Alessio Gagliardi , Alessandro Pecchia , Gemma C. Solomon

In this paper, we study the near-field radiative energy, linear-momentum, and angular-momentum transfer from a current-biased graphene to nanoparticles. The electric current through the graphene sheet induces nonequilibrium fluctuations,…

Optics · Physics 2024-02-19 Huimin Zhu , Gaomin Tang , Lei Zhang , Jun Chen

We report a new Quantum Mechanical/Molecular Dynamics (QM/MD) simulation loop to model the coupling between the electron and atom dynamics in solid/liquid interfacial systems. The method can describe simultaneously both the quantum…

Materials Science · Physics 2021-02-03 Joshua D Elliott , Alessandro Troisi , Paola Carbone

Molecule-electrode interfaces in molecular electronic junctions are prone to chemical reactions, structural changes, and localized heating effects caused by electric current. These can be exploited for device functionality or may be…

Mesoscale and Nanoscale Physics · Physics 2020-04-22 Riley J. Preston , Vincent F. Kershaw , Daniel S. Kosov

To assist the design of novel, highly efficient molecular junctions, a deep understanding of the precise charge transport mechanisms through these devices is of prime importance. In the present contribution, we describe a procedure to…

Chemical Physics · Physics 2020-01-13 Vincent Pohl , Lukas Eugen Marsoner Steinkasserer , Jean Christophe Tremblay

Vibronic effects in resonant electron transport through single-molecule junctions are analyzed. The study is based on generic models for molecular junctions, which include electronic states on the molecular bridge that are vibrationally…

Mesoscale and Nanoscale Physics · Physics 2011-03-15 R. Härtle , M. Thoss

The proper design and synthesis of molecular junctions for the purpose of establishing percolative networks of conductive nanoparticles represent an opportunity to develop more efficient thermally-conductive nanocomposites, with several…

In recent years, artificial intelligence has played an important role on accelerating the whole process of drug discovery. Various of molecular representation schemes of different modals (e.g. textual sequence or graph) are developed. By…

Machine Learning · Computer Science 2022-11-28 Tianyu Wu , Yang Tang , Qiyu Sun , Luolin Xiong

While heating of a current carrying Ohmic conductors is an obvious consequence of the diffusive nature of the conduction in such systems, current induced cooling has been recently reported in some molecular conduction junctions. In this…

Mesoscale and Nanoscale Physics · Physics 2009-09-25 Michael Galperin , Keiji Saito , Alexander V. Balatsky , Abraham Nitzan

The effect of electronic current on the atomic motion still poses many open questions, and several mechanisms are at play. Recently there has been focus on the importance of the current-induced non-conservative forces (NC) and Berry-phase…

Mesoscale and Nanoscale Physics · Physics 2011-10-20 Jing Tao Lü , Tue Gunst , Per Hedegård , Mads Brandbyge

We investigate charge transport in C$_{60}$-based single-molecule junctions with graphene electrodes employing a combination of density functional theory (DFT) electronic structure calculations and Landauer transport theory. In particular,…

Mesoscale and Nanoscale Physics · Physics 2017-01-12 Susanne Leitherer , Pedro B. Coto , Konrad Ullmann , Heiko B. Weber , Michael Thoss

In this thesis, I investigate the molecular electronic properties of molecular junctions formed from single molecules. I started my thesis by discusses the main theoretical methods using in this work density functional theory and the green…

Mesoscale and Nanoscale Physics · Physics 2016-10-18 Eman Nader Almutib

The energy dependent thermoelectric response of a single molecule contains valuable information about its transmission function and its excited states. However, measuring it requires devices that can efficiently heat up one side of the…

Machine learning potentials have emerged as a means to enhance the accuracy of biomolecular simulations. However, their application is constrained by the significant computational cost arising from the vast number of parameters compared to…

Molecular dynamics simulations at a constant electric potential are an essential tool to study electrochemical processes, providing microscopic information on the structural, thermodynamic, and dynamical properties. Despite the numerous…

We derive and employ a semi-classical Langevin equation obtained from path-integrals to describe the ionic dynamics of a molecular junction in the presence of electrical current. The electronic environment serves as an effective…

Mesoscale and Nanoscale Physics · Physics 2012-07-03 Jing Tao Lü , Mads Brandbyge , Per Hedegård , Tchavdar N. Todorov , Daniel Dundas

Molecular dynamics (MD) simulations play an important role in understanding and engineering heat transport properties of complex materials. An essential requirement for reliably predicting heat transport properties is the use of accurate…

The possibility of using single molecule junctions as electron pumps for energy conversion and storage is considered. It is argued that the small dimensions of these systems enable to make use of unique intra-molecular quantum coherences in…

Quantum Physics · Physics 2015-05-20 Roie Volkovich , Uri Peskin

Self-assembled-monolayer (SAM) molecular junctions (MJs) constitute a promising building block candidate for future molecular electronic devices. Transport properties of SAM-MJs are usually calculate using either the phenomenological…

Mesoscale and Nanoscale Physics · Physics 2015-06-30 Yonatan Dubi

We review charge transport across molecular monolayers, which is central to molecular electronics (MoE) using large-area junctions (NmJ). We strive to provide a wide conceptual overview of three main sub-topics. First, a broad introduction…

Materials Science · Physics 2017-03-17 Ayelet Vilan , Dinesh Aswal , David Cahen