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We develop a microscopic theory for biasing the quantum trajectories of an open quantum system, which renders rare trajectories typical. To this end we consider a discrete-time quantum dynamics, where the open system collides sequentially…

We develop a unified quantum geometric framework to understand reactive quantum dynamics. The critical roles of the quantum geometry of adiabatic electronic states in both adiabatic and non-adiabatic quantum dynamics are unveiled. A…

Chemical Physics · Physics 2025-05-19 Yujuan Xie , Ruoxi Liu , Bing Gu

There is currently much interest in the development of improved trajectory-based methods for the simulation of nonadiabatic processes in complex systems. An important goal for such methods is the accurate calculation of the rate constant…

Chemical Physics · Physics 2014-09-04 Jeremy O. Richardson , Michael Thoss

Conventional models of Josephson junction dynamics rely on the absence of low energy quasiparticle states due to a large superconducting gap. With this assumption the quasiparticle degrees of freedom become "frozen out" and the phase…

Superconductivity · Physics 2011-10-25 Jens Michelsen , Vitaly S. Shumeiko

Accurate description of nonadiabatic dynamics of molecules at metal surfaces involving electron transfer has been a longstanding challenge for theory. Here, we tackle this problem by first constructing high-dimensional neural network…

Materials Science · Physics 2024-01-05 Gang Meng , James Gardner , Wenjie Dou , Reinhard J. Maurer , Bin Jiang

Diabatization of the molecular Hamiltonian is a standard approach to removing the singularities of nonadiabatic couplings at conical intersections of adiabatic potential energy surfaces. In general, it is impossible to eliminate the…

Chemical Physics · Physics 2021-03-26 Seonghoon Choi , Jiří Vaníček

Recently, the technique of counterdiabatic driving, which provides an effective strategy for accelerating adiabatic quantum evolution, has been widely applied in the preparation of many-body quantum states. In this work, we propose a…

Quantum Physics · Physics 2026-05-15 Fengzhe Tang , Gangcheng Wang

Geometric phases, which accompany the evolution of a quantum system and depend only on its trajectory in state space, are commonly studied in two-level systems. Here, however, we study the adiabatic geometric phase in a weakly anharmonic…

Quantum Physics · Physics 2012-06-08 S. Berger , M. Pechal , S. Pugnetti , A. A. Abdumalikov , L. Steffen , A. Fedorov , A. Wallraff , S. Filipp

Dynamical quantum phase transitions (DQPTs) are non-equilibrium transitions characterized by the orthogonality between an initial quantum state and its time-evolved counterpart following a sudden quench. Recently, studies of this phenomenon…

Quantum Physics · Physics 2026-05-27 Kai Zhang , Chang Shu , Kai Sun

We study the many-body dynamics of stimulated Raman adiabatic passage in the presence of on-site interactions. In the classical mean-field limit, explored in Phys. Rev. Lett. {\bf 121}, 250405 (2018), interaction-induced chaos leads to the…

Quantum Gases · Physics 2019-04-03 Amit Dey , Doron Cohen , Amichay Vardi

Quantum adiabatic evolutions find a broad range of applications in quantum physics and quantum technologies. The traditional form of the quantum adiabatic theorem limits the speed of adiabatic evolution by the minimum energy gaps of the…

We present statistics of quantum jumps in the two-level system with landau-Zener Hamiltonian that undergoes a Markovian process. For the Landau-Zener model, which is successful in simulating adiabatic/non-adiabatic evolution and quantum…

Quantum Physics · Physics 2024-11-05 Laleh Memarzadeh , Rosario Fazio

Adiabatic quantum computation employs a slow change of a time-dependent control function (or functions) to interpolate between an initial and final Hamiltonian, which helps to keep the system in the instantaneous ground state. When the…

Quantum Physics · Physics 2014-06-26 Constantin Brif , Matthew D. Grace , Mohan Sarovar , Kevin C. Young

We analyze the influence of a dissipative environment on geometric phases in a quantum system subject to non-adiabatic evolution. We find dissipative contributions to the acquired phase and modification of dephasing, considering the cases…

Quantum Physics · Physics 2016-07-20 A. E. Svetogorov , Yu. Makhlin

Nonadiabatic effects appear due to avoided crossings or conical intersections that are either intrinsic properties in field-free space or induced by a classical laser field in a molecule. It was demonstrated that avoided crossings in…

Chemical Physics · Physics 2019-11-12 András Csehi , Markus Kowalewski , Gábor J. Halász , Ágnes Vibók

Nonadiabatic dynamical processes are one of the most important quantum mechanical phenomena in chemical, materials, biological, and environmental molecular systems, where the coupling between different electronic states is either inherent…

Chemical Physics · Physics 2022-05-24 Jian Liu , Xin He , Baihua Wu

We explore nonadiabatic quantum phase transitions in an Ising spin chain with a linearly time-dependent transverse field and two different spins per unit cell. Such a spin system passes through critical points with gapless excitations,…

Statistical Mechanics · Physics 2021-02-23 Bin Yan , Vladimir Y. Chernyak , Wojciech H. Zurek , Nikolai A. Sinitsyn

Rare nonadiabatic events play a central role in photochemistry but remain difficult to simulate because excited-state dynamics is computationally demanding and often stochastic. Here we introduce a deterministic and time-reversible…

Fast nonadiabatic control protocols known as shortcuts to adiabaticity have found a plethora of applications, but their use has been severely limited to speeding up the dynamics of isolated quantum systems. We introduce shortcuts for open…

Quantum Physics · Physics 2020-08-06 L. Dupays , I. L. Egusquiza , A. del Campo , A. Chenu

It is known that effects of dissipation or measurement backreaction in postselected quantum trajectories are described by non-Hermitian Hamiltonian, but their consequences in real-time dynamics of many-body systems are yet to be elucidated.…

Quantum Gases · Physics 2023-04-05 Tomoya Hayata , Yoshimasa Hidaka , Arata Yamamoto
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