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Accurate modeling of the electronic structure of warm dense matter is a challenging problem whose solution would allow a better understanding of material properties like equation of state, opacity, and conductivity, with resulting…

Plasma Physics · Physics 2021-07-14 M. Laraia , C. Hanson , N. R. Shaffer , D. Saumon , D. P. Kilcrease , C. E. Starrett

We present, within Kohn-Sham Density Functional Theory calculations, a quantitative method to identify and assess the partitioning of a large quantum mechanical system into fragments. We then show how within this framework simple…

Chemical Physics · Physics 2017-09-28 Stephan Mohr , Michel Masella , Laura E. Ratcliff , Luigi Genovese

The Maxwell-Bloch equations are a valuable tool to model light-matter interaction, where the application examples range from the description of pulse propagation in two-level media to the elaborate simulation of optoelectronic devices, such…

Quantum Physics · Physics 2021-07-27 Michael Riesch , Christian Jirauschek

We present a multigrid algorithm for self consistent solution of the Kohn-Sham equations in real space. The entire problem is discretized on a real space mesh with a high order finite difference representation. The resulting self consistent…

Materials Science · Physics 2009-10-31 Jian Wang , Thomas L. Beck

We present a method to invert a given density and find the Kohn-Sham (KS) potential in Density Functional Theory (DFT) which shares that density. Our method employs the concept of screening density, which is naturally constrained by the…

Chemical Physics · Physics 2020-05-05 Timothy J. Callow , Nektarios N. Lathiotakis , Nikitas I. Gidopoulos

We present an efficient real space formalism for hybrid exchange-correlation functionals in generalized Kohn-Sham density functional theory (DFT). In particular, we develop an efficient representation for any function of the real space…

Computational Physics · Physics 2024-06-26 Xin Jing , Phanish Suryanarayana

Reducing the many-fermion problem to a set of single-particle (s.p.) equations, the Kohn-Sham (KS) theory has provided a practical tool to implement \textit{ab initio} calculations of ground-state energies and densities in many-electron…

Quantum Physics · Physics 2023-09-18 H. Nakada

We introduce \textsc{qcmath}, a user-friendly quantum chemistry software tailored for electronic structure calculations, implemented using the Wolfram Mathematica language and available at \url{https://github.com/LCPQ/qcmath}. This…

Chemical Physics · Physics 2023-09-01 Enzo Monino , Antoine Marie , Pierre-François Loos

We consider the extension of the standard single-determinant Kohn-Sham method to the case of a multiconfiguration trial wavefunction. By applying the rigorous Kohn-Sham method to this case, we construct the proper interacting and…

Strongly Correlated Electrons · Physics 2008-12-08 Yair Kurzweil , M. Head-Gordon

Despite the wide availability of density functional theory (DFT) codes, their adoption by the broader materials science community remains limited due to challenges such as software installation, input preparation, high-performance computing…

This article is part-I of a review of density-functional theory (DFT) that is the most widely used method for calculating electronic structure of materials. The accuracy and ease of numerical implementation of DFT methods has resulted in…

Materials Science · Physics 2023-05-25 Prashant Singh , Manoj K Harbola

Localized representation of the Kohn-Sham subspace plays an important role in quantum chemistry and materials science. The recently developed selected columns of the density matrix (SCDM) method [J. Chem. Theory Comput. 11, 1463, 2015] is a…

Numerical Analysis · Mathematics 2017-08-22 Anil Damle , Lin Lin , Lexing Ying

A novel low complexity method to perform self-consistent electronic-structure calculations using the Kohn-Sham formalism of density functional theory is presented. Localization constraints are neither imposed nor required thereby allowing…

Computational Physics · Physics 2007-05-23 M. J. Rayson

We present CheSS, the "Chebyshev Sparse Solvers" library, which has been designed to solve typical problems arising in large-scale electronic structure calculations using localized basis sets. The library is based on a flexible and…

Solving linear systems of equations plays a fundamental role in numerous computational problems from different fields of science. The widespread use of numerical methods to solve these systems motivates investigating the feasibility of…

A mixed basis approach based on density functional theory is extended to one-dimensional(1D) systems. The basis functions here are taken to be the localized B-splines for the two finite non-periodic dimensions and the plane waves for the…

Materials Science · Physics 2016-04-20 Chung-Yuan Ren , Yia-Chung Chang , Chen-Shiung Hsue

Representation learning for the electronic structure problem is a major challenge of machine learning in computational condensed matter and materials physics. Within quantum mechanical first principles approaches, Kohn-Sham density…

Materials Science · Physics 2024-04-24 Bowen Hou , Jinyuan Wu , Diana Y. Qiu

A relativistic density-functional theory based on a Fock-space effective quantum-electrodynamics (QED) Hamiltonian using the Coulomb or Coulomb-Breit two-particle interaction is developed. This effective QED theory properly includes the…

Chemical Physics · Physics 2021-05-03 Julien Toulouse

The development of advanced software tools for power system analysis requires extensive programming expertise. Even when using open-source tools, programming skills are essential to modify built-in models. This can be particularly…

Software Engineering · Computer Science 2025-08-26 Izudin Dzafic , Rabih A. Jabr

We generalize the recently developped "internal" Density Functional Theory (DFT) and Kohn-Sham scheme to multicomponent systems. We obtain a general formalism, applicable for the description of multicomponent self-bound systems (as…

Quantum Physics · Physics 2015-03-19 Jeremie Messud
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