Related papers: Pressure-induced mixed states caused by spin-elast…
Pressure-induced phase transitions of spin-crossover materials were simulated by a Monte Carlo simulation in the constant pressure ensemble for the first time. Here, as the origin of the cooperative interaction, we adopt elastic interaction…
We study the two-step spin crossover in a double-layered elastic model based on transition metal complexes each taking high spin (HS) and low spin (LS) states. Here, only the simplest elastic interactions between adjacent molecules are…
Nuclear inelastic scattering (NIS) spectra were recorded for the spin-crossover complexes STP and ETP (STP = [Fe(1,1,1-trisf[N-(2-pyridylmethyl)-N-methylamino]methylg- ethane)](ClO4)2 and ETP =…
In spin crossover materials, an abrupt phase transition between a low spin state and a high spin state can be driven by temperature, pressure or by light irradiation. Of a special relevance are Fe(II) based coordination polymers where, in…
Hybrid perovskites have been at the forefront of condensed matter research particularly in context of device applications primarily in relation to applications in the field of solar cells. In this article, we demonstrate that several new…
Under the hydrostatic pressure $P=1.48$ GPa, polarized neutron elastic scattering experiments have been carried out on the coupled spin dimer system TlCuCl$_3$ with the gapped ground state at ambient pressure. Pressure-induced magnetic…
Magnetoresistance measurements on the quasi one-dimensional organic conductor (TMTSF)_2PF_6 performed in magnetic fields B up to 16T, temperatures T down to 0.12K and under pressures P up to 14kbar have revealed new phases on its P-B-T…
After the discovery of the phenomena of light-induced excited spin state trapping (LIESST), the functional properties of metal complexes have been studied intensively. Among them, cooperative phenomena involving low spin-high spin…
Ab initio calculations predict a metal-insulator transition at zero temperature to occur in La$_4$Ni$_3$O$_8$ at moderate pressures as a result of a pressure-induced spin-state transition. The spin-state transition that is seen at 105 K at…
Rapidly developing science and technology demand new materials with versatile and promising properties for practical applications. In this context, pseudo-octahedral iron(II) spin crossover (SCO) complexes are particularly appealing - not…
Photo-induced switching from the low-spin state to the high-spin state is studied in a model of spin-crossover materials, in which long-range interactions are induced by elastic distortions due to different molecular sizes the two spin…
A wide family of cobalt oxides of formulation (Pr,Ln,Ca)CoO3 (Ln being a lanthanide) exhibits a coupled valence and spin-state transition (VSST) at a temperature T*, which involves two concomitant modifications: (i) a change in the spin…
In studies of the QCD deconfining phase transition or crossover by means of heavy ion experiments, one ought to be concerned about non-equilibrium effects due to heating and cooling of the system. Motivated by this, we look at hysteresis…
A hybrid Potts model where a random concentration $p$ of the spins assume $q_0$ states and a random concentration $1-p$ of the spins assume $q>q_0$ states is introduced. It is known that when the system is homogeneous, with an integer spin…
A gradual spin-state transition occurs in LaCoO3 around T~80-120 K, whose detailed nature remains controversial. We studied this transition by means of inelastic neutron scattering (INS), and found that with increasing temperature an…
Spin-exchange collisions have been widely studied in recent years, and various quantum-mechanical scattering approaches have been developed to calculate the rates. However, these methods based on global knowledge of wavefunctions can be…
Spin-crossover complexes exhibit two stable configurations with distinct spin states. The investigation of these molecules using low-temperature scanning tunneling microscopy has opened new perspectives for understanding the associated…
We investigate the spin-squeezing behavior under thermal effects in a one-dimensional transverse field XY model with spin-1/2. The exact solution of the model helps us to compute the spin-squeezing parameter as a function of temperature and…
We analyze pressure effects on stripe states within a selfconsistent Hartree-Fock calculation for a model of a striped nickelates. The results show a transition induced by high pressure and predict possible new spin states. We describe…
We discuss the phenomenology of phase transitions studied with two control variables. Such measurements have become routine with magnetic field and temperature being varied for 1st order magnetic transitions with an ease not conceivable…