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In the last decade, much theoretical research has focused on studying the strong coupling between organic molecules (or quantum emitters, in general) and light modes. The description and prediction of polaritonic phenomena emerging in this…

Quantum interference between multiple pathways in molecular photodissociation often results in angular momentum polarization of atomic products and this can give deep insight into fundamental physical processes. For dissociation of diatomic…

Chemical Physics · Physics 2022-04-26 Chaya Weeraratna , Arthur G. Suits , Oleg S. Vasyutinskii

Polyatomic molecular ions contain many desirable attributes of a useful quantum system, including rich internal degrees of freedom and highly controllable coupling to the environment. To date, the vast majority of state-specific…

Quantum Physics · Physics 2018-03-14 David Patterson

Molecular polaritons are hybrid states of photonic and molecular character that form when molecules strongly interact with light. Strong coupling tunes energy levels and importantly, can modify molecular properties (e.g. photoreaction…

Chemical Physics · Physics 2023-02-14 Francesca Fassioli , Kyu Hyung Park , Sarah E. Bard , Gregory D. Scholes

We calculate the photoionization cross-section of a molecular endohedral. We limit ourselves to two-atomic molecules. The consideration is much more complex than for atomic endohedrals because the system even for almost spherical fullerenes…

Atomic and Molecular Clusters · Physics 2019-09-04 M. Ya. Amusia , L. V. Chernysheva , S. K. Semenov

Photonic molecules, i.e. artificial structures composed of coherently coupled optical cavities, are paradigmatic systems for investigating fundamental phenomena across photonics, quantum optics and topological physics. In recent years,…

Optics · Physics 2026-05-06 Tiantong Li , Katia Gallo

Photonic molecules - particular systems composed of coupled optical resonators - emulate the behavior of complex physical systems exhibiting discrete energy levels. In this work, we present a novel photonic molecule composed of two strongly…

Optics · Physics 2023-12-06 Sara Kacmoli , Deborah L. Sivco , Claire F. Gmachl

Soliton molecules, bound states composed of interacting fundamental solitons, exhibit remarkable resemblance with chemical compounds and phenomena in quantum mechanics. Whereas optical molecules composed of two or more temporally locked…

Photonic molecules can mimic interactions of atomic energy levels, offering new ways to manipulate cavity eigenstates. Current methods using evanescent coupling of multiple cavities face challenges in scalability, flexibility, and coupling…

The concepts of topology provide a powerful tool to tailor the propagation and localization of light. While electromagnetic waves have only two polarization states, engineered degeneracies of photonic modes provide novel opportunities…

The demonstration of strong and ultrastrong coupling regimes of cavity QED with polyatomic molecules has opened new routes to control chemical dynamics at the nanoscale. We show that strong resonant coupling of a cavity field with an…

Quantum Physics · Physics 2016-06-09 Felipe Herrera , Frank C. Spano

Optical cycling refers to repeated excitation and spontaneous emission on an electronic transition in an atom or molecule. Optical cycling in molecules can enable a wide range of quantum control and readout techniques, but unfortunately it…

Optically trapped Rydberg atoms are a suitable platform to explore quantum many-body physics mediated by long-range atom--atom interactions that can be engineered through externally applied light fields. However, this approach is limited to…

This chapter reviews the fundamental optical properties and applications of pho-tonic molecules (PMs) - photonic structures formed by electromagnetic coupling of two or more optical microcavities (photonic atoms). Controllable interaction…

Optics · Physics 2015-03-13 Svetlana V. Boriskina

This paper describes theoretical modelling of electrostatic lenses based on 3, 4 and 5 closely spaced cylindrical electrodes, respectively. In each case, modelling is carried out numerically using commercial packages SIMION and LENSYS, and…

Instrumentation and Detectors · Physics 2009-11-11 Omer Sise , Melike Ulu , Mevlut Dogan

To understand the photophysics of molecular aggregates, exciton model of J- and H-aggregate has been extensively utilized. However, it lacks consideration of crystal symmetry. Although discrete molecules may lack symmetry, their aggregates…

Mesoscale and Nanoscale Physics · Physics 2023-10-10 Qingyun Wan , Chi-Ming Che

We describe a new method of coherent optical control of internal dynamics of atomic collisions by means of two correlated light beams having entangled polarizations. We show that if excitation of a colliding pair of atoms is by two photons…

Quantum Physics · Physics 2015-06-23 M. D. Havey , D. V. Kupriyanov , I. M. Sokolov

We propose diatomic molecules built from gold and carbon-group atoms as promising candidates for optical cycling and precision measurements. We show that this class of molecules (AuX, X = C, Si, Ge, Sn, Pb) features laser-accessible…

Atomic Physics · Physics 2024-07-30 K. Cooper Stuntz , Kendall L. Rice , Lan Cheng , Benjamin L. Augenbraun

The study of electronic transitions within a molecule connected to the absorption or emission of light is a common task in the process of the design of new materials. The transitions are complex quantum mechanical processes and a detailed…

Human-Computer Interaction · Computer Science 2021-06-03 Talha Bin Masood , Signe Sidwall Thygesen , Mathieu Linares , Alexei I. Abrikosov , Vijay Natarajan , Ingrid Hotz

A photonic molecule (PM) is a miniature diffractive optical structure composed of resonance microcavities called atoms (e.g., cylinders or spheres) supporting a set of high-quality eigenmodes. All atoms in a PM are coupled by the…

Optics · Physics 2022-11-29 Yury E. Geints