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In this work, we report a high remnant polarization, 2Pr >70$\mu$C/cm$^2$ in thermally processed atomic layer deposited Hf0.5Zr0.5O2 (HZO) film on Silicon with NH3 plasma exposed thin TiN interlayer and Tungsten (W) as a top electrode. The…

Understanding surface collective dynamics in quantum materials is crucial for advancing quantum technologies. For example, surface phonon modes in quantum paraelectrics are thought to play an essential role in facilitating interfacial…

Epitaxial strain is a powerful means to engineer emergent phenomena in thin films and heterostructures. Here, we demonstrate that KTaO3, a cubic perovskite in bulk form, can be epitaxially strained into a highly tunable ferroelectric. KTaO3…

The ability to manipulate ferroelectrics at ultrafast speeds has long been an elusive target for materials research. Coherently exciting the ferroelectric mode with ultrashort optical pulses holds the promise to switch the ferroelectric…

Materials Science · Physics 2017-05-17 Roman Mankowsky , Alexander von Hoegen , Michael Först , Andrea Cavalleri

SrTiO$_3$ is an incipient ferroelectric on the verge of a polar instability, which is avoided at low temperatures by quantum fluctuations. Within this unusual quantum paraelectric phase, superconductivity persists despite extremely dilute…

Superconductivity · Physics 2019-09-12 Ryan Russell , Noah Ratcliff , Kaveh Ahadi , Lianyang Dong , Susanne Stemmer , John W. Harter

SrTiO$_{3}$ is known to be an incipient ferroelectric. It is thought that ferroelectric stability in SrTiO$_{3}$ is suppressed by a delicate competition with quantum fluctuation and antiferrodistortion. The ferroelectric phase can, however,…

Materials Science · Physics 2014-04-22 Ashima Arora , Goutam Sheet

An analytical model is developed to predict the temporal evolution of the lattice polarization in ferroelectric nanomembranes upon the excitation by a terahertz (THz) electromagnetic pulse of an arbitrary waveform, and the concurrent…

Materials Science · Physics 2025-11-04 Yujie Zhu , Aiden Ross , Xiangwei Guo , Venkatraman Gopalan , Long-Qing Chen , Jia-Mian Hu

The interplay of electronic and structural degrees of freedom is a prominent feature of many quantum materials and of particular interest in systems with strong ferroelectric fluctuations, such as SrTiO$_3$ (STO) and KTaO$_3$ (KTO). Both…

High entropy oxides (HEO) hold the potential to revolutionize the conventional material paradigms by leveraging high order of chemical disorder that induces highly desirable exotic phases for advanced applications. Here, we devise a…

We introduce an open-source, fully atomistic second-principles interatomic potential for lead titanate (PbTiO3), a benchmark ferroelectric material known for its strong polarization and hightemperature phase transitions. While density…

Materials Science · Physics 2025-10-10 Louis Bastogne , Philippe Ghosez

The ability to drive a spin system to state far from the equilibrium is indispensable for investigating spin structures of antiferromagnets and their functional nonlinearities for spintronics. While optical methods have been considered for…

Measuring terahertz waveforms in terahertz spectroscopy often relies on electrooptic sampling employing a ZnTe crystal. Although the nonlinearities in such zincblende semiconductors induced by intense terahertz pulses have been studied at…

Electro-optics, the tuning of optical properties of materials with electric fields, is key to a multitude of quantum and classical photonics applications. However, a major obstacle preventing many emerging use cases is inefficient…

Several SrTiO3 (STO) thin films without electrodes processed by pulsed laser deposition, of thicknesses down to 40 nm, were studied using infrared transmission and reflection spectroscopy. The complex dielectric responses of polar phonon…

Materials Science · Physics 2009-04-29 D. Nuzhnyy , J. Petzelt , S. Kamba , T. Yamada , M. Tyunina , A. K. Tagantsev , J. Levoska , N. Setter

Oxide growth with semiconductor-like accuracy has led to atomically precise thin films and interfaces that exhibit a plethora of phases and functionalities not found in the oxide bulk material. This yielded spectacular discoveries such as…

With the broad recent research on ferroelectric hafnium oxide for non-volatile memory technology, depolarization effects in HfO2-based ferroelectric devices gained a lot of interest. Understanding the physical mechanisms regulating the…

Emerging Technologies · Computer Science 2025-08-13 Luca Fehlings , Thomas Mikolajick , Beatriz Noheda , Erika Covi

Several defect configurations including oxygen vacancies have been investigated as possible origins of the reported room-temperature ferroelectricity of strontium titanate (STO) thin films [Appl. Phys. Letts. 91, 042908 (2007)].…

Materials Science · Physics 2015-05-13 Yong Su Kim , J. Kim , S. J. Moon , W. S. Choi , Y. J. Chang , J. -G. Yoon , J. Yu , J. -S. Chung , T. W. Noh

The discovery of very large piezo- and pyroelectric effects in ZrO2 and HfO2-based thin films opens up new opportunities to develop silicon-compatible sensor and actor devices. The effects are amplified close to the polar-orthorhombic to…

Materials Science · Physics 2022-06-02 Richard Ganser , Simon Bongarz , Alexander von Mach , Luis Azevedo Antunes , Alfred Kersch

We use ultrafast x-ray pulses to characterize the lattice response of SrTiO3 when driven by strong terahertz (THz) fields. We observe transient changes in the diffraction intensity with a delayed onset with respect to the driving field.…

Materials Science · Physics 2017-03-30 M. Kozina , T. van Driel , M. Chollet , T. Sato , J. M. Glownia , S. Wandel , M. Radovic , U. Staub , M. C. Hoffmann

Single-shot recording of terahertz electric signals has recently become possible at high repetition rates, by using the photonic time-stretch electro-optic sampling (EOS) technique. However the moderate sensitivity of time-stretch EOS is…