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At ambient pressure CaFe2As2 has been found to undergo a first order phase transition from a high temperature, tetragonal phase to a low temperature orthorhombic / antiferromagnetic phase upon cooling through T ~ 170 K. With the application…

The structural properties of EuCo2As2 have been studied up to 35 GPa, through the use of x-ray diffraction in a diamond anvil cell at a synchrotron source. At ambient conditions, EuCo2As2 (I4/mmm) has a tetragonal lattice structure with a…

Materials Science · Physics 2011-04-19 Matthew Bishop , Walter Uhoya , Georgiy Tsoi , Yogesh K. Vohra , Athena S. Sefat , Brian C. Sales

In this article we report the structural stability of Er$_2$Ti$_2$O$_7$ cubic pyrochlore with pressure using x-ray diffraction, Raman spectroscopy, photoluminescence, x-ray absorption and ab-initio calculations. Our studies establish a…

Materials Science · Physics 2024-06-07 M. Modak , Rahul Kaiwart , Santosh K. Gupta , A. Dwivedi , K. K. Pandey , A. K. Poswal , H. K. Poswal

In-situ high pressure single crystal X-ray diffraction study reveals that the quantum material CaMn$_2$Bi$_2$ undergoes a unique plane to chain structural transition between 2 and 3 GPa, accompanied by a large volume collapse. CaMn2Bi2…

Materials Science · Physics 2019-07-18 Xin Gui , Gregory J. Finkelstein , Keyu Chen , Tommy Yong , Przemyslaw Dera , Jinguang Cheng , Weiwei Xie

Lactose is widely used in agri-food and pharma industries. New materials that can be obtained from renewable sources are currently being sought. I have studied the effect of hydrostatic pressure on structural properties of currently known…

Materials Science · Physics 2025-07-08 Igor A. Fedorov

We have characterized the high-pressure behavior of alpha-SnWO4. The compound has been studied up to 30 GPa using a diamond-anvil cell and synchrotron powder X-ray diffraction. We report evidence of two structural phase transitions in the…

We explore the direct to indirect band gap transitions in MX$_2$ (M= Mo/W, X= S/Se) transition metal dichalcogenides heterobilayers for different system compositions, strains, and twist angles based on first principles density functional…

We studied the effect of external pressure on the optical response of the nodal-line semimetal candidate ZrSiTe by reflectivity measurements. At pressures of a few GPa, the reflectivity, optical conductivity, and loss function are strongly…

Materials Science · Physics 2019-07-24 J. Ebad-Allah , M. Krottenmüller , J. Hu , Y. L. Zhu , Z. Q. Mao , C. A. Kuntscher

The optical properties of two-dimensional materials can be effectively tuned by strain induced from a deformable substrate. In the present work we combine first-principles calculations based on density functional theory and the effective…

A detailed high pressure investigation is carried out using x-ray diffraction, Raman spectroscopy and low temperature resistivity measurements on hexagonal ZrSe$_{2}$ having an excess of 3 at.\% Zr. Structural studies show that the sample…

Strongly Correlated Electrons · Physics 2022-09-21 Bishnupada Ghosh , Mrinmay Sahu , Debabrata Samanta , Pinku Saha , Anshuman Mandal , Goutam Dev Mukherjee

On the basis of density functional theory electronic band structure calculations using the augmented spherical wave method, the electronic and magnetic properties of the orthorhombic and tetragonal phases of Ca3Mn2O7 were investigated and…

Materials Science · Physics 2007-08-02 S. F. Matar , V. Eyert , A. Villesuzanne , M. -H. Whangbo

The temperature dependent electrical resistivity of single crystalline SrFe2As2 and BaFe2As2 has been measured in a liquid medium, modified Bridgman anvil cell for pressures in excess of 75 kbar. These data allow for the determination of…

Superconductivity · Physics 2015-05-13 E. Colombier , S. L. Bud'ko , N. Ni , P. C. Canfield

The intermetallic compound BaFe2Al9 exhibits unusual physical properties associated with a charge density wave (CDW) transition. Unlike conventional CDW materials, which typically display subtle structural distortions or lattice…

Phonon density of states calculation shows that a new TiO2 polymorph with tridymite structure is mechanically stable. Enthalpies of 9 TiO2 polymorphs under different pressure are presented to study the relative stability of the TiO2…

Materials Science · Physics 2014-06-11 Tong Zhu , Shang-Peng Gao

High pressure behavior of potassium chlorate (KClO$_3$) has been investigated from 0-10 GPa by means of first principles density functional theory (DFT) calculations. The calculated ground state parameters, transition pressure and phonon…

Materials Science · Physics 2015-06-17 N. Yedukondalu , Vikas D. Ghule , G. Vaitheeswaran

The transition metal dichalcogenide PdTe$_2$ has attractive features based on its classification as a type-II Dirac semimetal and the occurrence of type-I superconductivity, providing a platform for discussion of a topological…

Cu2OSeO3 is known as a unique example of insulating multiferroic compounds with skyrmion spin texture, which is characterized by the chiral cubic crystal structure at ambient pressure. Recently, it has been reported that this compound shows…

Strongly Correlated Electrons · Physics 2020-11-18 E. Nishibori , S. Karatsu , C. Terakura , N. Takeshita , M. Kinoshita , S. Ishiwata , Y. Tokura , S. Seki

We performed X-ray diffraction and electrical resistivity measurement up to pressures of 5 GPa and the first-principles calculations utilizing experimental structural parameters to investigate the pressure-induced topological phase…

We present measurements of the superconducting and charge density wave critical temperatures (Tc and TCDW) as a function of pressure in the transition metal dichalchogenides 2H-TaSe2 and 2H-TaS2. Resistance and susceptibility measurements…

Tungsten ditelluride (WTe2) has attracted significant attention due to its interesting electronic properties, such as the unsaturated magnetoresistance and superconductivity. Recently, it has been proposed to be a new type of Weyl…

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