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In this work, we investigate the possibility of improving multireference-driven coupled cluster (CC) approaches with an algorithm that iteratively combines complete active space (CAS) calculations with tailored CC and externally corrected…

Chemical Physics · Physics 2025-03-06 Robin Feldmann , Max Mörchen , Jakub Lang , Michał Lesiuk , Markus Reiher

Coupled cluster (CC) methods are among the most accurate methods in quantum chemistry. However, the standard CC linear response formulation is not gauge invariant resulting in errors when modelling properties like optical rotation and…

Chemical Physics · Physics 2018-03-13 Rolf H. Myhre

It is shown how a chiral Lagrangian framework can be used to derive relationships connecting quark-level QCD correlation functions to mesonic-level two-point functions. Crucial ingredients of this connection are scale factor matrices…

High Energy Physics - Phenomenology · Physics 2016-01-12 Amir H. Fariborz , A. Pokraka , T. G. Steele

We use scalar-field Lagrangians with a non-canonical kinetic term to obtain unified dark matter models where both the dark matter and the dark energy, the latter mimicking a cosmological constant, are described by the scalar field itself.…

Astrophysics · Physics 2011-07-13 Daniele Bertacca , Nicola Bartolo , Antonaldo Diaferio , Sabino Matarrese

Unitary Coupled Cluster (UCC) theory is a promising variational method for electronic structure calculations, especially for strongly correlated systems and quantum computers. However, its practical application is limited by the steep…

Chemical Physics · Physics 2026-02-05 Prateek Vaish , Brenda Rubenstein

In this article, we investigate the numerical and theoretical aspects of the coupled-cluster method tailored by matrix-product states. We investigate chemical properties of the used method, such as energy size extensivity and the…

A framework to calculate two-particle matrix elements for fully antisymmetrized three-cluster configurations is presented. The theory is developed for a scattering situation described in terms of the Algebraic Model. This means that the…

Nuclear Theory · Physics 2009-11-06 V. Vasilevsky , A. V. Nesterov , F. Arickx , J. Broeckhove

We propose a multireference linearized coupled cluster theory using matrix product states (MPS-LCC) which provides remarkably accurate ground-state energies, at a computational cost that has the same scaling as multireference configuration…

Chemical Physics · Physics 2015-09-02 Sandeep Sharma , Ali Alavi

In a four-dimensional space I shall construct all of the conformally invariant, scalar-vector-tensor field theories that are consistent with conservation of charge, and flat space compatible. By the last assumption I mean that the…

General Relativity and Quantum Cosmology · Physics 2018-01-29 Gregory W. Horndeski

We consider two distinct coupled cluster (CC) perturbation series that both expand the difference between the energies of the CCSD (CC with single and double excitations) and CCSDT (CC with single, double, and triple excitations) models in…

Chemical Physics · Physics 2016-02-17 Kasper Kristensen , Janus Juul Eriksen , Devin A. Matthews , Jeppe Olsen , Poul Jørgensen

In single-reference coupled-cluster (CC) methods, one has to solve a set of non-linear polynomial equations in order to determine the so-called amplitudes which are then used to compute the energy and other properties. Although it is of…

Chemical Physics · Physics 2021-09-10 Antoine Marie , Fábris Kossoski , Pierre-François Loos

In a four-dimensional space, I shall construct all of the conformally invariant scalar-tensor field theories, which are flat space compatible; i.e., well-defined and differentiable when evaluated for a flat metric tensor and constant scalar…

General Relativity and Quantum Cosmology · Physics 2017-06-16 Gregory W. Horndeski

In this paper, we introduce Adaptive Cluster Lasso(ACL) method for variable selection in high dimensional sparse regression models with strongly correlated variables. To handle correlated variables, the concept of clustering or grouping…

Machine Learning · Statistics 2016-03-14 Niharika Gauraha , Swapan K. Parui

We propose to improve the convergence properties of the single-reference coupled cluster (CC) method through an augmented Lagrangian formalism. The conventional CC method changes a linear high-dimensional eigenvalue problem with exponential…

Computational Physics · Physics 2024-03-26 Fabian M. Faulstich , Yuehaw Khoo , Kangbo Li

The curse of dimensionality (COD) limits the current state-of-the-art {\it ab initio} propagation methods for non-relativistic quantum mechanics to relatively few particles. For stationary structure calculations, the coupled-cluster (CC)…

Quantum Physics · Physics 2015-06-03 Simen Kvaal

A formalism based on the complex-scaling method is presented to solve the few particle scattering problem in configuration space using bound state techniques with trivial boundary conditions. Several applications to A=3,4 systems are…

Nuclear Theory · Physics 2015-06-12 Rimantas Lazauskas , Jaume Carbonell

We construct a tridiagonal matrix representation for the three dimensions Dirac-Coulomb Hamiltonian that provides for a simple and straightforward relativistic extension of the complex scaling method. Besides the Coulomb interaction,…

Quantum Physics · Physics 2008-11-26 A. D. Alhaidari

We propose a new formulation of time-dependent coupled cluster with adaptive basis functions and division of the one-particle space into active and secondary subspaces. The formalism is fully bivariational in the sense of a real-valued…

Chemical Physics · Physics 2024-02-20 Mads Greisen Højlund , Ove Christiansen

Previous work has shown that mesonic fields in chiral Lagrangians can be systematically connected to quark-level operators in QCD sum rules through chiral-symmetry constrained and energy-independent scale factor matrices. This framework…

High Energy Physics - Phenomenology · Physics 2025-11-04 J. Ho , Amir H. Fariborz , T. G. Steele

Recently a new Lagrangian framework was introduced to describe interactions between scalar fields and relativistic perfect fluids. This allows two consistent generalizations of coupled quintessence models: non-vanishing pressures and a new…

Cosmology and Nongalactic Astrophysics · Physics 2015-09-30 Tomi S. Koivisto , Emmanuel N. Saridakis , Nicola Tamanini
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