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For the recent GW100 test set of molecular ionization energies, we present a comprehensive assessment of different GW methodologies: fully self-consistent GW (scGW), quasiparticle self-consistent GW (qsGW), partially self-consistent GW0…

Chemical Physics · Physics 2018-05-17 Fabio Caruso , Matthias Dauth , Michiel J. van Setten , Patrick Rinke

Phosphorene is a bidimensional material that has properties useful for semiconductor devices. In this work we studied the electronic and optical properties of this material using the $GW$ approximation and the Bethe-Salpeter equation (BSE)…

Mesoscale and Nanoscale Physics · Physics 2017-11-16 Fábio Ferreira , Ricardo Mendes Ribeiro

Novel results for the self-consistent single-particle spectral function and self-energy are presented for non-degenerate one-component Coulomb systems at various densities and temperatures. The GW^0-method for the dynamical self-energy is…

Plasma Physics · Physics 2009-11-13 Carsten Fortmann

Within the framework of many-body perturbation theory based on Green's functions, the $GW$ approximation has emerged as a pivotal method for computing quasiparticle energies and excitation spectra. However, its high computational cost and…

Chemical Physics · Physics 2025-12-25 Yueyang Zhang , Wei Wu , Peifeng Su

The self-consistent quasiparticle random-phase approximation (QRPA) approach is formulated in the canonical single-nucleon basis of the relativistic Hatree-Fock-Bogoliubov (RHFB) theory. This approach is applied to study the isobaric analog…

Nuclear Theory · Physics 2017-04-12 Z. M. Niu , Y. F. Niu , H. Z. Liang , W. H. Long , J. Meng

Quasiparticle (QP) excitations are extremely important for understanding and predicting charge transfer and transport in molecules, nanostructures and extended systems. Since density functional theory (DFT) within the Kohn-Sham (KS)…

Chemical Physics · Physics 2017-07-18 Vojtech Vlcek , Eran Rabani , Daniel Neuhauser , Roi Baer

Two examples of recent progress in applications of the Dyson-Schwinger equation (DSE) formalism are presented: (1) Strong coupling quantum electrodynamics in 4 dimensions (QED$_4$) is an often studied model, which is of interest both in its…

High Energy Physics - Phenomenology · Physics 2007-05-23 F. T. Hawes , K. Kusaka , A. G. Williams

In this paper, we study and implement the structural iterative eigensolvers for the large-scale eigenvalue problem in the Bethe-Salpeter equation (BSE) based on the reduced basis approach via low-rank factorizations in generating matrices,…

Numerical Analysis · Mathematics 2017-03-08 Peter Benner , Sergey Dolgov , Venera Khoromskaia , Boris N. Khoromskij

Calculations of excited states in Green's function formalism often invoke the diagonal approximation, in which the quasiparticle states are taken from a mean-field calculation. Here, we extend the stochastic approaches applied in the…

Computational Physics · Physics 2023-09-28 Annabelle Canestraight , Xiaohe Lei , Khaled Ibrahim , Vojtech Vlcek

We propose a simple many-body based screening mixing strategy to considerably enhance the performance of the Bethe-Salpeter (BS) approach for prediction of excitation energies of molecular systems. This strategy enables us to nearly…

Chemical Physics · Physics 2017-11-15 Vafa Ziaei , Thomas Bredow

A quantum-field approach to studying the Bose systems at finite temperatures and in states with spontaneously broken symmetry, in particular in a superfluid state, is proposed. A generalized model of a self-consistent field (SCF) for…

Statistical Mechanics · Physics 2013-06-11 Yu. M. Poluektov

Quantum chemistry simulations offer a cost-effective way for computational design of BODIPY photosensitizers with potential use in photodynamic therapy (PDT). However, accurate predictions of photophysical properties, such as excitation…

We apply the renormalized singles with correlation (RSc) Green's function in the $GW$ approximation to calculate accurate quasiparticle (QP) energies and orbitals. The RSc Green's function includes all orders of singles contributions from…

Chemical Physics · Physics 2022-10-19 Jiachen Li , Weitao Yang

We present quasiparticle self-consistent GW (QSGW) calculations of semimetallic bulk Bi. We go beyond the conventional QSGW method by including the spin-orbit coupling throughout the self-consistency cycle. This approach improves the…

Materials Science · Physics 2015-03-27 Irene Aguilera , Christoph Friedrich , Stefan Blügel

The problem of calculating of the mass spectrum of the two-body Bethe-Salpeter equation is studied with no reduction to the three-dimensional ("quasipotential") equation. The method to find the ground state and excited states for a channel…

High Energy Physics - Phenomenology · Physics 2015-06-25 A. Yu. Umnikov , F. C. Khanna

The recent developments of quantum computing present potential novel pathways for quantum chemistry, as the increased computational power of quantum computers could be harnessed to naturally encode and solve electronic structure problems.…

Quantum Physics · Physics 2024-03-01 Lila Cadi Tazi , Alex J. W. Thom

Electronic excitations and optical spectra of $CdF_{2}$ are calculated up to ultraviolet employing state-of-the-art techniques based on density functional theory and many-body perturbation theory. The GW scheme proposed by Hedin has been…

Materials Science · Physics 2015-06-15 Giancarlo Cappellini , Jürgen Furthmüller , Emiliano Cadelano , Friedhelm Bechstedt

The self-consistent Relativistic Quasiparticle Random Phase Approximation (RQRPA) is extended by the quasiparticle-phonon coupling (QPC) model using the Quasiparticle Time Blocking Approximation (QTBA). The method is formulated in terms of…

Nuclear Theory · Physics 2008-11-26 E. Litvinova , P. Ring , V. Tselyaev

A Dyson Bethe-Salpeter equation (Dyson-BSE) for fermion pairs is presented whose kernel has a static and a one frequency dependent contribution, analogous to the self energy of the single particle Dyson equation with the (static) mean field…

Nuclear Theory · Physics 2020-01-08 Peter Schuck

Spectroscopic and optical properties of nanosystems and point defects are discussed within the framework of Green's function methods. We use an approach based on evaluating the self-energy in the so-called GW approximation and solving the…

Materials Science · Physics 2009-11-11 Murilo L. Tiago , James R. Chelikowsky
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