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We study, using Monte Carlo simulations, the interaction between charged colloidal particles confined to the air-water interface. The dependence of force on ionic strength and counterion valence is explored. For 1:1 electrolyte, we find…

Soft Condensed Matter · Physics 2018-02-05 Matheus Girotto , Alexandre P. dos Santos , Yan Levin

Measurements of the surface diffusivity of colloidal spheres translating along a vapor/liquid inter- face show an unexpected decrease in diffusivity, or increase in surface drag (from the Stokes-Einstein relation) when the particles situate…

Soft Condensed Matter · Physics 2016-07-08 Joel Koplik , Charles Maldarelli

Although the dynamics of colloids in the vicinity of a solid interface has been widely characterized in the past, experimental studies of Brownian diffusion close to an air-water interface are rare and limited to particle-interface gap…

Soft Condensed Matter · Physics 2022-11-11 Stefano Villa , Christophe Blanc , Abdallah Daddi-Moussa-Ider , Antonio Stocco , Maurizio Nobili

We study the effective forces acting between colloidal particles trapped at a fluid interface which itself is exposed to a pressure field. To this end we apply what we call the ``force approach'', which relies solely on the condition of…

Soft Condensed Matter · Physics 2008-03-31 Alvaro Dominguez , Martin Oettel , Siegfried Dietrich

We consider the surface pressure of a colloid-laden liquid interface. As micron-sized particles of suitable wettability can be irreversibly bound to the liquid interface on experimental timescales, we use the canonical ensemble to derive an…

Soft Condensed Matter · Physics 2022-03-07 R. Mears , I. Muntz , J. H. J. Thijssen

Optical microscopy and multi-particle tracking are used to investigate the cross-correlated diffusion of quasi two-dimensional (2D) colloidal particles near an oil-water interface. It is shown that the effect of the interface on correlated…

Soft Condensed Matter · Physics 2015-06-15 Wei Zhang , Song Chen , Na Li , Jiazheng Zhang , Wei Chen

The evolution of an initially prepared distribution of micron sized colloidal particles, trapped at a fluid interface and under the action of their mutual capillary attraction, is analyzed by using Brownian dynamics simulations. At a…

Soft Condensed Matter · Physics 2011-11-29 J. Bleibel , A. Dominguez , M. Oettel , S. Dietrich

Gravitational effects in colloidal suspensions can be easily turned off by matching the density of the solid microparticles with the one of the surrounding fluid. By studying the motion of catalytic microswimmers with tunable buoyant…

Soft Condensed Matter · Physics 2022-11-09 Virginia Carrasco-Fadanelli , Ivo Buttinoni

We investigate the dynamics of colloids at a fluid interface driven by attractive capillary interactions. At submillimeter length scales, the capillary attraction is formally analogous to two-dimensional gravity. In particular it is a…

Soft Condensed Matter · Physics 2010-07-27 Alvaro Dominguez , Martin Oettel , S. Dietrich

We show theoretically that near a fluid-fluid interface a single active colloidal particle generating, e.g., chemicals or a temperature gradient experiences an effective force of hydrodynamic origin. This force is due to the fluid flow…

Soft Condensed Matter · Physics 2016-03-16 Alvaro Domínguez , Paolo Malgaretti , Mihail N. Popescu , Siegfried Dietrich

The dynamics of active colloids is very sensitive to the presence of boundaries and interfaces which therefore can be used to control their motion. Here we analyze the dynamics of active colloids adsorbed at a fluid-fluid interface. By…

Soft Condensed Matter · Physics 2019-11-18 T. Peter , P. Malgaretti , N. Rivas , A. Scagliarini , J. Harting , S. Dietrich

We analyze theoretically the electrostatic interaction of surface-charged colloids at water interfaces with special attention to the experimentally relevant case of large charge densities on the colloid-water interface. Whereas linear…

Soft Condensed Matter · Physics 2007-11-13 D. Frydel , S. Dietrich , M. Oettel

The effects of contact-line pinning are well-known in macroscopic systems, but are only just beginning to be explored at the microscale in colloidal suspensions. We use digital holography to capture the fast three-dimensional dynamics of…

Soft Condensed Matter · Physics 2017-09-13 Anna Wang , W. Benjamin Rogers , Vinothan N. Manoharan

The adsorption dynamics of a colloidal particle at a fluid interface is studied theoretically and numerically, documenting distinctly different relaxation regimes. The adsorption of a perfectly smooth particle is characterized by a fast…

Soft Condensed Matter · Physics 2017-07-18 Carlos E. Colosqui , Jeffrey F. Morris , Joel Koplik

The electrostatic interaction between colloidal particles trapped at the interface between two immiscible electrolyte solutions is studied in the limit of small inter-particle distances. Within an appropriate model exact analytic…

Soft Condensed Matter · Physics 2014-05-07 Arghya Majee , Markus Bier , S. Dietrich

When captured by a flat nematic-isotropic interface, colloidal particles can be dragged by it. As a result spatially periodic structures may appear, with the period depending on a particle mass, size, and interface…

Soft Condensed Matter · Physics 2009-11-11 J. L. West , K. Zhang , A. Glushchenko , D. Andrienko , M. Tasinkevych , Y. Reznikov

An interface between two miscible fluids is transient, existing as a non-equilibrium state before complete molecular mixing is reached. However, during the existence of such an interface, which typically be at short timescales, composition…

Deformable colloids and macromolecules adsorb at interfaces, as they decrease the interfacial energy between the two media. The deformability, or softness, of these particles plays a pivotal role in the properties of the interface. In this…

The connection between fundamental interactions acting in molecules in a fluid and macroscopically measured properties, such as the viscosity between colloidal particles coated with polymers, is studied here. The role that hydrodynamic and…

Soft Condensed Matter · Physics 2015-09-02 A. Gama Goicochea , M. A. Balderas Altamirano , R. Lopez-Esparza , M. A. Waldo , E. Perez

Using fluorescence microscopy we study the adsorption of single latex microparticles at a water/water interface between demixing aqueous solutions of polymers, generally known as a water-in-water emulsion. Similar microparticles at the…

Soft Condensed Matter · Physics 2018-05-23 Louis Keal , Carlos E. Colosqui , Hans Tromp , Cecile Monteux
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