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Reactions at solid-water interfaces play a foundational role in water treatment systems, catalysis, chemical separations, and in predicting chemical fate and transport in the environment. Over the last century, experimental measurements and…

Chemical Physics · Physics 2022-12-14 Anastasia G. Ilgen , Kevin Leung , Louise J. Criscenti , Jeffery A. Greathouse

Carbonous materials, such as graphene and carbon nanotube, have attracted tremendous attention in the fields of nanofluidics due to the slip at the interface between solid and liquid. The dependence of slip length for water on the types of…

Fluid Dynamics · Physics 2022-06-29 Han Li , Zhi Xu , Chen Ma , Ming Ma

Efficient and sustainable techniques for separating water-methanol mixtures are in high demand in the industry. Recent studies have revealed that membranes and 2D materials could achieve such separation. In our research, we explore the…

Soft Condensed Matter · Physics 2023-06-28 Roger Bellido-Peralta , Fabio Leoni , Carles Calero , Giancarlo Franzese

Adsorbed layers of water are ubiquitously present at surfaces and fill in microscopic pores, playing a central role in many phenomena in such diverse fields as materials science, geology, biology, tribology, nanotechnology. Despite such…

Mesoscale and Nanoscale Physics · Physics 2015-03-26 G. Algara-Siller , O. Lehtinen , F. C. Wang , R. R. Nair , U. Kaiser , H. A. Wu , I. V. Grigorieva , A. K. Geim

Geometry, stability, and thermal transport of graphene nanoquilts folded by hydrogenation are studied using molecular dynamics simulations. The hydrogenated graphene nanoquilts show increased thermodynamic stability and better transport…

Mesoscale and Nanoscale Physics · Physics 2016-01-20 Zhongwei Zhang , Yuee Xie , Qing Peng , Yuanping Chen

Measurements of the surface diffusivity of colloidal spheres translating along a vapor/liquid inter- face show an unexpected decrease in diffusivity, or increase in surface drag (from the Stokes-Einstein relation) when the particles situate…

Soft Condensed Matter · Physics 2016-07-08 Joel Koplik , Charles Maldarelli

We study the influence of chain stiffness on droplet flow in a nano-channel, coated with semiflexible hydrophobic polymers by means of non-equilibrium molecular-dynamics simulations. The studied system is then a moving droplet in the slit…

Soft Condensed Matter · Physics 2017-10-18 Kevin Speyer , Claudio Pastorino

Direct Numerical Simulations of two superposed fluids in a channel with a textured surface on the lower wall have been carried out. A parametric study varying the viscosity ratio between the two fluids has been performed to mimic both {\bf…

Fluid Dynamics · Physics 2019-05-22 I. Arenas , E. Garcia , M. K. Fu , P. Orlandi , M. Hultmark , S. Leonardi

We present a versatile setup for investigating the nanofluidic behavior of nanoparticles as a function of the gap distance between two confining surfaces. The setup is designed as an open system which operates with small amounts of…

Soft Condensed Matter · Physics 2017-01-17 Stefan Fringes , Felix Holzner , Armin W. Knoll

Graphene nanoslit pore is used for nanofluidic devices like water desalination, ion-selective channels, ionic transistors, sensing, molecular sieving, blue energy harvesting, and protein sequencing. It is a strenuous task to prepare…

Soft Condensed Matter · Physics 2023-01-04 Jeet Majumdar , Subhadeep Dasgupta , Soham Mandal , Mohd Moid , Manish Jain , Prabal K. Maiti

We perform systematic molecular dynamics simulations of water confined between two nanoscale plates at T=300 K. We investigate the effect of pressure (-0.15 GPa <= P <= 0.2 GPa) and plate separation (0.4 nm <= d <= 1.6 nm) on the phase…

Chemical Physics · Physics 2016-09-08 Nicolas Giovambattista , Peter J. Rossky , Pablo G. Debenedetti

The issue of ice accumulation at low-temperature circumstances causes multiple problems and serious damages in many civil infrastructures which substantially influence human daily life. However, despite the significant consideration in…

Chemical Physics · Physics 2020-11-24 Amir Afshar , Dong Meng

Recent experiments have shown that the out-of-plane dielectric constant of water confined in nanoslits of graphite and hexagonal boron nitride (hBN) is vanishingly small. Despite extensive effort based mainly on classical force-field…

Chemical Physics · Physics 2022-11-28 Thomas Dufils , Christoph Schran , Ji Chen , Andre K. Geim , Laura Fumagalli , Angelos Michaelides

Various bandstructure engineering methods have been studied to improve the performance of graphitic transparent conductors; however none demonstrated an increase of optical transmittance in the visible range. Here we measure in situ optical…

Multilayered graphene-based nanoporous membranes with electrolyte incorporated between individual sheets is a unique nano-heterostructure system in which nanoconfined electrons in graphene and ions confined in between sheets are intimately…

Mesoscale and Nanoscale Physics · Physics 2020-06-30 Jing Xiao , Hualin Zhan , Zaiquan Xu , Xiao Wang , Ke Zhang , Zhiyuan Xiong , George P. Simon , Zhe Liu , Dan Li

We revisit the theory of ion transport in parallel-plate channels and also discuss how the wettability of a solid and the mobility of adsorbed surface charges impact the transport of ions. It is shown that depending on the ratio of the…

Soft Condensed Matter · Physics 2021-09-29 Olga I. Vinogradova , Elena F. Silkina , Evgeny S. Asmolov

The lubricating ability of graphite largely depends on the environmental humidity, essentially the amount of water in between its layers. In general, intercalated molecules in layered materials modify their extraordinary properties by…

Materials Science · Physics 2019-01-09 A. Qadir , Y. W. Sun , W. Liu , P. Goldberg Oppenheimer , Y. Xu , C. J. Humphreys , D. J. Dunstan

We have explored the phase behavior of a set of water-like models in slit pores of nanoscopic dimensions. The interaction between water and pore walls mimics the graphite surface. A version of density functional method is used as…

Soft Condensed Matter · Physics 2021-10-12 O. Pizio , S. Sokolowski , V. M. Trejos

Experimental investigations of hydrophobic/water interfaces often return controversial results, possibly due to the unknown role of gas accumulation at the interfaces. Here, during advanced atomic force microscopy of the initial evolution…

Mesoscale and Nanoscale Physics · Physics 2015-12-29 Ing-Shouh Hwang , Chung-Kai Fang , Hsien-Chen Ko , Chih-Wen Yang , Yi-Hsien Lu

Graphene serves as an ideal platform to investigate the microscopic structure and reaction kinetics at the graphitic electrode interfaces. However, graphene is susceptible to various extrinsic factors, e.g. substrate, causing much confusion…

Chemical Physics · Physics 2022-07-19 Ying Xu , You-Bo Ma , Feng Gu , Shan-Shan Yang , Chuan-Shan Tian