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The Bochkov-Kuzovlev nonlinear fluctuation-dissipation theorem is used to derive Narayanaswamy's phenomenological theory of physical aging, in which this highly nonlinear phenomenon is described by a linear material-time convolution…

Statistical Mechanics · Physics 2017-01-04 Jeppe C. Dyre

Physical aging deals with slow property changes over time caused by molecular rearrangements. This is relevant for non-crystalline materials like polymers and inorganic glasses, both in production and during subsequent use. The…

Soft Condensed Matter · Physics 2024-01-05 Saeed Mehri , Lorenzo Costigliola , Jeppe C. Dyre

The noncrystalline glassy state of matter plays a role in virtually all fields of materials science and offers complementary properties to those of the crystalline counterpart. The caveat of the glassy state is that it is out of equilibrium…

Physical ageing is the generic term for irreversible processes in glassy materials resulting from molecular rearrangements. One formalism for describing such ageing processes involves the concept of material time, which may be thought of as…

The relaxation dynamics of many disordered systems, such as structural glasses, proteins, granular materials or spin glasses, is not completely frozen even at very low temperatures. This residual motion leads to a change of the properties…

Soft Condensed Matter · Physics 2009-10-31 Walter Kob , Francesco Sciortino , Piero Tartaglia

4-dim intrinsic (material) Riemannian metric $G$ of the material 4-D space-time continuum $P$ is utilized as the characteristic of the aging processes developing in the material. Manifested through variation of basic material…

Mathematical Physics · Physics 2016-09-07 A. Chudnovsky , S. Preston

Understanding and controlling physical aging, i.e. the spontaneous temporal evolution of out-of-equilibrium systems, represents one of the greatest tasks in material science. Recent studies have revealed the existence of a complex atomic…

Materials Science · Physics 2016-02-17 V. M. Giordano , B. Ruta

Aging to the equilibrium liquid state of organic glasses is studied. The glasses were prepared by cooling the liquid to temperatures just below the glass transition. Aging following a temperature jump was studied by measuring the dielectric…

Soft Condensed Matter · Physics 2013-01-29 Tina Hecksher , Niels Boye Olsen , Kristine Niss , Jeppe C. Dyre

We consider a simple model of a structural glass, represented by a lattice gas with kinetic constraints in contact with a particle reservoir. Quench below the glass transition is represented by the jump of the chemical potential above a…

Statistical Mechanics · Physics 2007-05-23 Luca Peliti , Mauro Sellitto

The random first order transition theory of the dynamics of supercooled liquids is extended to treat aging phenomena in nonequilibrium structural glasses. A reformulation of the idea of ``entropic droplets'' in terms of libraries of local…

Soft Condensed Matter · Physics 2009-11-10 Vassiliy Lubchenko , Peter G. Wolynes

A model is proposed that considers aging and rejuvenation in a soft glassy material as respectively a decrease and an increase in free energy. The aging term is weighted by inverse of characteristic relaxation time suggesting greater…

Soft Condensed Matter · Physics 2015-02-25 Yogesh M. Joshi

This paper presents simulations of the physical aging of a binary Kob-Andersen-type Lennard-Jones liquid following large temperature up-jumps from equilibrated states of high relaxation time. The purpose is to investigate how well the…

Soft Condensed Matter · Physics 2026-04-14 Aude Y. Amari , Lorenzo Costigliola , Jeppe C. Dyre

We use confocal microscopy to directly visualize the dynamics of aging colloidal glasses. We prepare a colloidal suspension at high density, a simple model system which shares many properties with other glasses, and initiate experiments by…

Disordered Systems and Neural Networks · Physics 2009-11-07 Rachel E. Courtland , Eric R. Weeks

Physical aging in polymers is a fundamental yet poorly understood phenomenon, as diverse macromolecular systems exhibit remarkably similar slow dynamics. Through molecular dynamics simulations of physically crosslinked networks composed of…

Soft Condensed Matter · Physics 2025-10-16 Patrick Ilg , Clarisse Luap , Martin Kröger

Many measurements on soft condensed matter (e.g., biological and materials) systems track low-dimensional observables projected from the full system phase space as a function of time. Examples are dynamic structure factors, spectroscopic…

Statistical Mechanics · Physics 2021-02-03 Alessio Lapolla , Jeremy C. Smith , Aljaž Godec

It is well established that glassy materials can undergo aging, i.e., their properties gradually change over time. There is rapidly growing evidence that dense active and living systems also exhibit many features of glassy behavior, but it…

Statistical Mechanics · Physics 2022-03-29 Giulia Janzen , Liesbeth M. C. Janssen

The far-from-equilibrium dynamics of glassy systems share important phenomenological traits. A transition is generally observed from a time-homogeneous dynamical regime to an aging regime where physical changes occur intermittently and, on…

Soft Condensed Matter · Physics 2015-03-13 S. Boettcher , P. Sibani

Aging refers to the property of two-time correlation functions to decay very slowly on (at least) two time scales. This phenomenon has gained recent attention due to experimental observations of the history dependent relaxation behavior in…

Popular Physics · Physics 2008-02-03 Stefan Boettcher

In this paper, we review the general features of the out-of-equilibrium dynamics of spin glasses. We use this example as a guideline for a brief description of glassy dynamics in other disordered systems like structural and polymer glasses,…

Disordered Systems and Neural Networks · Physics 2009-11-03 Eric Vincent

Ageing of organic glasses to the equilibrium liquid state is studied by measuring the dielectric loss utilizing a microregulator where temperature is controlled by means of a Peltier element. Compared to conventional equipment the new…

Soft Condensed Matter · Physics 2011-07-18 Niels Boye Olsen , Tina Hecksher , Kristine Niss , Jeppe C. Dyre
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