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Thermodynamic relations are derived from first principles of mechanics for non-equilibrium processes. Since the key role herein is played by the law of increase of entropy, the latter is analyzed at first. It is shown that its derivation…

chao-dyn · Physics 2008-02-03 J. Kumicak , X. de Hemptinne

We show that systems with negative specific heat can violate the zeroth law of thermodynamics. By both numerical simulations and by using exact expressions for free energy and microcanonical entropy it is shown that if two systems with the…

Statistical Mechanics · Physics 2009-11-13 A. Ramirez-Hernandez , H. Larralde , F. Leyvraz

Thermodynamics plays an important role both in the foundations of physics and in technological applications. An operational perspective adopted in recent years is to formulate it as a quantum resource theory. At the core of this theory is…

Quantum Physics · Physics 2023-12-13 Thomas Theurer , Elia Zanoni , Carlo Maria Scandolo , Gilad Gour

In traditional thermodynamical and statistical-mechanical approaches one has (some) detailed knowledge of the principles governing the microdynamics of a system. However in many instances we may not have a Hamiltonian or good information…

Statistical Mechanics · Physics 2007-05-23 David Ford

For the system with inhomogeneous distribution of macroscopic parameters we obtain thermodynamic relation which depends on the spatial point (coordinate). In our approach, to obtain such a relation we use the basic ideas of the method of…

Statistical Mechanics · Physics 2025-09-24 A. P. Rebesh , B. I. Lev , A. G. Zagorodny

We propose a relationship between thermodynamic phase transitions and ground-state quantum phase transitions in systems with variable Hamiltonian parameters. It is based on a link between zeros of the canonical partition function at complex…

Nuclear Theory · Physics 2009-11-10 Pavel Cejnar , Stefan Heinze , Jan Dobes

Classical thermodynamics is built with the concept of equilibrium states. However, it is less clear how equilibrium thermodynamics emerges through the dynamics that follows the principle of quantum mechanics. In this paper, we develop a…

Quantum Physics · Physics 2018-12-18 Md. Manirul Ali , Wei-Ming Huang , Wei-Min Zhang

We resolve the long standing question of temperature dependence of uniformly moving bodies by means of a quantum statistical treatment centred on the zeroth law of thermodynamics. The key to our treatment is the result, established by…

Mathematical Physics · Physics 2015-05-13 Geoffrey L. Sewell

This paper starts from a toy model for inflation in a class of modified theories of gravity in the metric formalism. Instead of the standard procedure -- assuming a non-linear Lagrangian $f(R)$ in the Jordan frame -- we start from a simple…

General Relativity and Quantum Cosmology · Physics 2020-07-01 C. D. Peralta , S. E. Jorás

Thermodynamics is based on the notions of energy and entropy. While energy is the elementary quantity governing physical dynamics, entropy is the fundamental concept in information theory. In this work, starting from first principles, we…

Statistical Mechanics · Physics 2017-10-25 Bernhard Altaner

We solve a set of selected exercises on rotational motion requiring a mechanical and thermodynamical analysis. When non-conservative forces or thermal effects are present, a complete study must use the first law of thermodynamics together…

Classical Physics · Physics 2014-04-08 Julio Güémez , Manuel Fiolhais

A major part of the many thermally driven processes in our natural environment as well as in engineering solutions of Carnot-type machinery is based on the second law of thermodynamics (or principle of entropy increase). An interesting link…

General Physics · Physics 2010-09-29 Hans R. Moser

Thermodynamics is traditionally concerned with systems comprised of a large number of particles. Here we present a framework for extending thermodynamics to individual quantum systems, including explicitly a thermal bath and work-storage…

Quantum Physics · Physics 2014-09-29 Paul Skrzypczyk , Anthony J. Short , Sandu Popescu

Understanding thermodynamics and statistical mechanics in the full general relativistic context is an open problem. I give tentative definitions of equilibrium state, mean values, mean geometry, entropy and temperature, which reduce to the…

General Relativity and Quantum Cosmology · Physics 2013-05-01 Carlo Rovelli

Heat exchanges are the essence of Thermodynamics. In order to investigate non-equilibrium effects like quantum coherence and correlations in heat flows we introduce the concept of apparent temperature. Its definition is based on the…

Quantum Physics · Physics 2020-01-10 Camille L. Latune , Ilya Sinayskiy , Franceso Petruccione

The method of positive commutators, developed for zero temperature problems over the last twenty years, has been an essential tool in the spectral analysis of Hamiltonians in quantum mechanics. We extend this method to positive…

Mathematical Physics · Physics 2009-11-10 Marco Merkli

In this paper we study the first law of thermodynamics for the (2+1) dimensional rotating charged BTZ black hole considering a pair of thermodinamical systems constructed with the two horizons of this solution. We show that these two…

General Relativity and Quantum Cosmology · Physics 2009-01-14 Alexis Larranaga

On the basis of Bethe ansatz solution of one dimensional Kondo model with electronic interaction, the thermodynamics equilibrium of the system in finite temperature is studied in terms of the strategy of Yang and Yang. The string hypothesis…

Strongly Correlated Electrons · Physics 2009-10-31 Shi-Jian Gu , You-Quan Li , Hai-Qing Lin

The zeroth law of thermodynamics involves a transitivity relation (pairwise between three objects) expressed either in terms of `equal temperature' (ET), or `in equilibrium' (EQ) conditions. In conventional thermodynamics conditional on…

Statistical Mechanics · Physics 2021-04-21 Jen-Tsung Hsiang , Bei-Lok Hu

Quantum Thermodynamics is a continuous dialogue between two independent theories: Thermodynamics and Quantum Mechanics. Whenever the two theories addressed the same phenomena new insight has emerged. We follow the dialogue from equilibrium…

Quantum Physics · Physics 2018-06-04 Robert Alicki , Ronnie Kosloff
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