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We study low-energy dynamics generated by a two-dimensional two-state Jahn-Teller Hamiltonian in the vicinity of a conical intersection using quantum wavepacket and trajectories dynamics. Recently, these dynamics were studied by comparing…

Chemical Physics · Physics 2024-02-06 Lea M. Ibele , Federica Agostini

Quantum--Mechanical methods that are both computationally fast and accurate are not yet available for electronic excitations having charge transfer character. In this work, we present a significant step forward towards this goal for those…

Chemical Physics · Physics 2015-06-12 Michele Pavanello , Troy Van Voorhis , Lucas Visscher , Johannes Neugebauer

We study the occurrence of factorization in polarized and unpolarized observables in coincidence quasi-elastic electron scattering. Starting with the relativistic distorted wave impulse approximation, we reformulate the effective momentum…

Nuclear Theory · Physics 2009-11-10 Javier R. Vignote , M. C. Martinez , J. A. Caballero , E. Moya de Guerra , J. M. Udias

The time-dependent exchange-correlation potential has an unusual task in directing fictitious non-interacting electrons to move with exactly the same probability density as true interacting electrons. This has intriguing implications for…

Chemical Physics · Physics 2024-06-19 Davood Dar , Lionel Lacombe , Neepa T. Maitra

The enormous structural and chemical diversity of metal-organic frameworks (MOFs) forces researchers to actively use simulation techniques on an equal footing with experiments. MOFs are widely known for outstanding adsorption properties, so…

Materials Science · Physics 2021-11-22 Vadim V. Korolev , Yurii M. Nevolin , Thomas A. Manz , Pavel V. Protsenko

In nuclear fusion and fission, fluctuation and dissipation arise due to the coupling of collective degrees of freedom with internal excitations. Close to the barrier, both quantum, statistical and non-Markovian effects are expected to be…

Nuclear Theory · Physics 2010-04-06 G. Hupin , D. Lacroix

We use effective field theory to compute the influence of nuclear structure on precision calculations of atomic energy levels. As usual, the EFT's effective couplings correspond to the various nuclear properties (such as the charge radius,…

High Energy Physics - Phenomenology · Physics 2021-05-19 L. Zalavari , C. P. Burgess , P. Hayman , M. Rummel

Theory of non-equilibrium Green's function (NGF) provides a practical framework for studying quantum many-body systems out of equilibrium. Extending the previous mean field approach developed for nuclear systems in one dimension with NGF,…

Nuclear Theory · Physics 2020-08-26 Hao Lin , Hossein Mahzoon , Arnau Rios , Pawel Danielewicz

The theoretical and computational description of materials properties is a task of utmost scientific and technological importance. A first-principles description of electron-electron interactions poses an immense challenge that is usually…

Chemical Physics · Physics 2022-04-06 Jakub Kocák , Eli Kraisler , Axel Schild

This paper analyzes two eXtended finite element methods (XFEMs) for linear quadratic optimal control problems governed by Poisson equation in non-convex domains. We follow the variational discretization concept to discretize the continuous…

Numerical Analysis · Mathematics 2018-08-06 Tao Wang , Chao Chao Yang , Xiaoping Xie

We study the exact nuclear time-dependent potential energy surface (TDPES) for laser-induced electron localization with a view to eventually developing a mixed quantum-classical dynamics method for strong-field processes. The TDPES is…

Chemical Physics · Physics 2015-06-15 Yasumitsu Suzuki , Ali Abedi , Neepa T. Maitra , E. K. U. Gross

The quantum dynamics of electron-nuclear systems is analyzed from the perspective of the exact factorization of the wavefunction, with the aim of defining gauge invariant equations of motion for both the nuclei and the electrons. For pure…

Chemical Physics · Physics 2023-10-16 Rocco Martinazzo , Irene Burghardt

Ground-state Kohn-Sham density functional theory provides, in principle, the exact ground-state energy and electronic spin-densities of real interacting electrons in a static external potential. In practice, the exact density functional for…

Chemical Physics · Physics 2022-07-11 Aaron D. Kaplan , Mel Levy , John P. Perdew

The manipulation of the motion of neutral molecules with electric or magnetic fields has seen tremendous progress over the last decade. Recently, these techniques have been extended to the manipulation of large and complex molecules. In…

Chemical Physics · Physics 2011-04-07 Frank Filsinger , Gerard Meijer , Henrik Stapelfeldt , Henry N. Chapman , Jochen Küpper

We investigate the existence and the properties of fully separable (fully factorized) ground states in quantum spin systems. Exploiting techniques of quantum information and entanglement theory we extend a recently introduced method and…

Statistical Mechanics · Physics 2009-07-01 S. M. Giampaolo , G. Adesso , F. Illuminati

Simulating photon dynamics in strong light-matter coupling situations via classical trajectories is proving to be powerful and practical. Here we analyze the performance of the approach through the lens of the exact factorization approach.…

Quantum Physics · Physics 2024-06-19 Bart Rosenzweig , Norah M. Hoffmann , Lionel Lacombe , Neepa T. Maitra

We propose a procedure to analyze the relation between the exact factorization of the electron-nuclear wave function and the Born-Oppenheimer approximation. We define the adiabatic limit as the limit of infinite nuclear mass. To this end,…

Chemical Physics · Physics 2016-08-24 F. G. Eich , Federica Agostini

We present a novel mixed quantum-classical approach to the coupled electron-nuclear dynamics based on the exact factorization of the electron-nuclear wave function, recently proposed in [A. Abedi, N. T. Maitra, and E. K. U. Gross, Phys.…

Chemical Physics · Physics 2015-06-18 Ali Abedi , Federica Agostini , E. K. U. Gross

We consider the integrable family of symmetric boundary-driven interacting particle systems that arise from the non-compact XXX Heisenberg model in one dimension with open boundaries. In contrast to the well-known symmetric exclusion…

Mathematical Physics · Physics 2024-05-27 Rouven Frassek , Cristian Giardinà

Entanglement is one of the most fascinating features arising from quantum-mechanics and of great importance for quantum information science. Of particular interest are so-called hybrid-entangled states which have the intriguing property…